PN 37455FC Epoxy Metal Filler, Part A

Hazard statements (CLP)

H314, H317, H318, H336, H400, H410

Code

Statements

H314

Causes severe skin burns and eye damage.

H317

May cause an allergic skin reaction

H318

Causes serious eye damage.

H336

May cause drowsiness or dizziness

H400

Very toxic to aquatic life

H410

Very toxic to aquatic life with long lasting effects

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Hazard pictograms

GHS05 (Corrosion) |GHS07 (Exclamation mark) |GHS09 (Environment) | Ingredients: Ingredient CAS Nbr EC No. % by Wt Fatty acids, C18-unsaturated, dimers, polymers with 68911-25-1 15 - 40 3,3'-oxybis(ethyleneoxy)bis(propylamine) Nitric acid, calcium salt, tetrahydrate 13477-34-4 233-332-1 3 - 7 m-Xylene-.alpha.alpha'.-diamine 1477-55-0 216-032-5 2 - 6 3,3'-Oxybis(ethyleneoxy)bis(propylamine) 4246-51-9 224-207-2 < 5 Amines, polyethylenepoly-, triethylenetetramine 90640-67-8 292-588-2 0.5 - 1.5 fraction

Hazard statements

H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H336 May cause drowsiness or dizziness. H410 Very toxic to aquatic life with long lasting effects.

Prevention

P260A Do not breathe vapours. P273 Avoid release to the environment. P280D Wear protective gloves, protective clothing, and eye/face protection.

Response

P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician.

Supplemental label elements

EUH071 Corrosive to the respiratory tract. 30% of the mixture consists of components of unknown acute oral toxicity. 30% of the mixture consists of components of unknown acute dermal toxicity.

Contains

34% of components with unknown hazards to the aquatic environment

2.3 Other hazards

Persons previously sensitised to amines may develop a cross-sensitisation reaction to certain other amines. This material does not contain any substances that are assessed to be a PBT or vPvB

2.1 Classification of the substance or mixture

CLP REGULATION (EC) No 1272/2008 The health and environmental classifications of this material have been derived using the calculation method, except in cases where test data are available or the physical form impacts classification. Classification(s) based on test data or physical form are noted below, if applicable. CLASSIFICATION: Skin Corrosion/Irritation, Category 1B - Skin Corr. 1B; H314 Serious Eye Damage/Eye Irritation, Category 1 - Eye Dam. 1; H318 Skin Sensitization, Category 1 - Skin Sens. 1; H317 Specific Target Organ Toxicity-Single Exposure, Category 3 - STOT SE 3; H336 Hazardous to the Aquatic Environment (Acute), Category 1 - Aquatic Acute 1; H400 Hazardous to the Aquatic Environment (Chronic), Category 1 - Aquatic Chronic 1; H410 For full text of H phrases, see Section 16. 2.2. Label elements CLP REGULATION (EC) No 1272/2008 SIGNAL WORD DANGER. Symbols GHS05 (Corrosion) |GHS07 (Exclamation mark) |GHS09 (Environment) | Pictograms Ingredients: Ingredient CAS Nbr EC No. % by Wt Fatty acids, C18-unsaturated, dimers, polymers with 68911-25-1 15 - 40 3,3'-oxybis(ethyleneoxy)bis(propylamine) Nitric acid, calcium salt, tetrahydrate 13477-34-4 233-332-1 3 - 7 m-Xylene-.alpha.alpha'.-diamine 1477-55-0 216-032-5 2 - 6 3,3'-Oxybis(ethyleneoxy)bis(propylamine) 4246-51-9 224-207-2 < 5 Amines, polyethylenepoly-, triethylenetetramine 90640-67-8 292-588-2 0.5 - 1.5 fraction HAZARD STATEMENTS: H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H336 May cause drowsiness or dizziness. H410 Very toxic to aquatic life with long lasting effects. PRECAUTIONARY STATEMENTS Prevention: P260A Do not breathe vapours. P273 Avoid release to the environment. P280D Wear protective gloves, protective clothing, and eye/face protection. Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. SUPPLEMENTAL INFORMATION: Supplemental Hazard Statements: EUH071 Corrosive to the respiratory tract. 30% of the mixture consists of components of unknown acute oral toxicity. 30% of the mixture consists of components of unknown acute dermal toxicity. Contains 34% of components with unknown hazards to the aquatic environment. 2.3. Other hazards Persons previously sensitised to amines may develop a cross-sensitisation reaction to certain other amines. This material does not contain any substances that are assessed to be a PBT or vPvB SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Ingredient Identifier(s) % Classification according to Regulation (EC) No. 1272/2008 [CLP] Fatty acids, C18-unsaturated, dimers, (CAS-No.) 68911-25-1 15 - 40 Skin Irrit. 2, H315 polymers with 3,3'- Eye Irrit. 2, H319 oxybis(ethyleneoxy)bis(propylamine) Skin Sens. 1A, H317 STOT SE 3, H336 Aquatic Acute 1, H400,M=1 Aquatic Chronic 1, H410,M=1 Polymeric amine Trade Secret 20 - 30 Substance not classified as hazardous Silica, vitreous (CAS-No.) 60676-86-0 7 - 13 Substance with a national occupational (EC-No.) 262-373-8 exposure limit Nitric acid, calcium salt, tetrahydrate (CAS-No.) 13477-34-4 3 - 7 Acute Tox. 4, H302 (EC-No.) 233-332-1