Filler bulk material for 3M 51002

Hazard statements (CLP)

H226, H304, H315, H319, H361d, H372

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Hazard pictograms

GHS02 (Flame) |GHS07 (Exclamation mark) |GHS08 (Health Hazard) | Ingredients: Ingredient CAS Nbr EC No. % by Wt styrene 100-42-5 202-851-5 10 - 30

Hazard statements

H226 Flammable liquid and vapour. H315 Causes skin irritation. H319 Causes serious eye irritation. H361d Suspected of damaging the unborn child. H304 May be fatal if swallowed and enters airways. H372 Causes damage to organs through prolonged or repeated exposure: sensory organs.

Prevention

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260A Do not breathe vapours. P280E Wear protective gloves. P260A Do not breathe vapours. P280E Wear protective gloves.

Response

P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P331 Do NOT induce vomiting. For containers not exceeding 125 ml the following Hazard and Precautionary statements may be used: <=125 ml Hazard statements H361d Suspected of damaging the unborn child. H304 May be fatal if swallowed and enters airways. H372 Causes damage to organs through prolonged or repeated exposure: sensory organs. <=125 ml Precautionary statements P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor. P331 Do NOT induce vomiting.

Supplemental label elements

EUH208

Contains

N,N'-ethylenebis-12-hydroxystearamide. May produce an allergic reaction 51% of the mixture consists of components of unknown acute oral toxicity. 51% of the mixture consists of components of unknown acute inhalation toxicity. 51% of components with unknown hazards to the aquatic environment

2.3 Other hazards

None known. This material does not contain any substances that are assessed to be a PBT or vPvB

2.1 Classification of the substance or mixture

CLP REGULATION (EC) No 1272/2008 The health and environmental classifications of this material have been derived using the calculation method, except in cases where test data are available or the physical form impacts classification. Classification(s) based on test data or physical form are noted below, if applicable. CLASSIFICATION: Flammable Liquid, Category 3 - Flam. Liq. 3; H226 Skin Corrosion/Irritation, Category 2 - Skin Irrit. 2; H315 Serious Eye Damage/Eye Irritation, Category 2 - Eye Irrit. 2; H319 Reproductive Toxicity, Category 2 - Repr. 2; H361d Specific Target Organ Toxicity-Repeated Exposure, Category 1 - STOT RE 1; H372 Aspiration Hazard, Category 1 - Asp. Tox. 1; H304 For full text of H phrases, see Section 16. 2.2. Label elements CLP REGULATION (EC) No 1272/2008 SIGNAL WORD DANGER. Symbols GHS02 (Flame) |GHS07 (Exclamation mark) |GHS08 (Health Hazard) | Pictograms Ingredients: Ingredient CAS Nbr EC No. % by Wt styrene 100-42-5 202-851-5 10 - 30 HAZARD STATEMENTS: H226 Flammable liquid and vapour. H315 Causes skin irritation. H319 Causes serious eye irritation. H361d Suspected of damaging the unborn child. H304 May be fatal if swallowed and enters airways. H372 Causes damage to organs through prolonged or repeated exposure: sensory organs. PRECAUTIONARY STATEMENTS Prevention: P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260A Do not breathe vapours. P280E Wear protective gloves. Response: P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P331 Do NOT induce vomiting. For containers not exceeding 125 ml the following Hazard and Precautionary statements may be used: <=125 ml Hazard statements H361d Suspected of damaging the unborn child. H304 May be fatal if swallowed and enters airways. H372 Causes damage to organs through prolonged or repeated exposure: sensory organs. <=125 ml Precautionary statements Prevention: P260A Do not breathe vapours. P280E Wear protective gloves. Response: P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor. P331 Do NOT induce vomiting. SUPPLEMENTAL INFORMATION: Supplemental Hazard Statements: EUH208 Contains N,N'-ethylenebis-12-hydroxystearamide. May produce an allergic reaction. 51% of the mixture consists of components of unknown acute oral toxicity. 51% of the mixture consists of components of unknown acute inhalation toxicity. Contains 51% of components with unknown hazards to the aquatic environment. 2.3. Other hazards None known. This material does not contain any substances that are assessed to be a PBT or vPvB SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Ingredient Identifier(s) % Classification according to Regulation (EC) No. 1272/2008 [CLP] Talc (CAS-No.) 14807-96-6 30 - 60 Substance with a national occupational (EC-No.) 238-877-9 exposure limit styrene (CAS-No.) 100-42-5 10 - 30 Flam. Liq. 3, H226 (EC-No.) 202-851-5 Acute Tox. 4, H332 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Repr. 2, H361d STOT RE 1, H372 Nota D Asp. Tox. 1, H304 STOT SE 3, H335 Aquatic Chronic 3, H412 Titanium dioxide (CAS-No.) 13463-67-7 5 - 10 Substance with a national occupational (EC-No.) 236-675-5 exposure limit Oxide glass chemicals (CAS-No.) 65997-17-3 1 - 5 Substance with a national occupational (EC-No.) 266-046-0 exposure limit Magnesite (CAS-No.) 13717-00-5 < 3 Substance not classified as hazardous Dolomite (CAS-No.) 16389-88-1 < 3 Substance with a national occupational (EC-No.) 240-440-2 exposure limit N,N'-ethylenebis-12-hydroxystearamide (CAS-No.) 123-26-2 < 0.5 Skin Sens. 1, H317 (EC-No.) 204-613-6 Please see section 16 for the full text of any H statements referred to in this section