Cleaning Solution G317 [G31704]

Hazard statements (CLP)

H319

Code

Statements

H319

Causes serious eye irritation

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Signal word

WARNING.

Hazard pictograms

GHS07 (Exclamation mark) |

Hazard statements

H319 Causes serious eye irritation.

Precautionary statements

General: P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children.

Response

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. For containers not exceeding 125 ml the following Hazard and Precautionary statements may be used

Supplemental label elements

EUH208 Contains reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500- 7]and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1). May produce an allergic reaction. Information required per Regulation (EU) No 528/2012 on Biocidal Products: Contains a biocidal product (preservative) C(M)IT/MIT (3 1) Notes on labelling Updated per Regulation (EC) No. 648/2004 on detergents. Ingredients required per 648/2004 <5% Anionic surfactant, amphoteric surfactant, Non-ionic surfactants. Contains Perfumes, Colorant, Mixture of Methylchloroisothiazolinone and Methylisothiazolinone (3:1) Eye classification based on test data.

2.3 Other hazards

None known. This material does not contain any substances that are assessed to be a PBT or vPvB

2.1 Classification of the substance or mixture

CLP REGULATION (EC) No 1272/2008 Test data on the raw material is reflected in the skin and eye hazard classification for the product. The health and environmental classifications of this material have been derived using the calculation method, except in cases where test data are available or the physical form impacts classification. Classification(s) based on test data or physical form are noted below, if applicable. CLASSIFICATION: Serious Eye Damage/Eye Irritation, Category 2 - Eye Irrit. 2; H319 For full text of H phrases, see Section 16. 2.2. Label elements CLP REGULATION (EC) No 1272/2008 SIGNAL WORD WARNING. Symbols GHS07 (Exclamation mark) | Pictograms HAZARD STATEMENTS: H319 Causes serious eye irritation. PRECAUTIONARY STATEMENTS General: P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. Response: P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. For containers not exceeding 125 ml the following Hazard and Precautionary statements may be used: SUPPLEMENTAL INFORMATION: Supplemental Hazard Statements: EUH208 Contains reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500- 7]and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1). May produce an allergic reaction. Information required per Regulation (EU) No 528/2012 on Biocidal Products: Contains a biocidal product (preservative): C(M)IT/MIT (3:1). Notes on labelling Updated per Regulation (EC) No. 648/2004 on detergents. Ingredients required per 648/2004: <5%: Anionic surfactant, amphoteric surfactant, Non-ionic surfactants. Contains: Perfumes, Colorant, Mixture of Methylchloroisothiazolinone and Methylisothiazolinone (3:1) Eye classification based on test data. 2.3. Other hazards None known. This material does not contain any substances that are assessed to be a PBT or vPvB SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Ingredient Identifier(s) % Classification according to Regulation (EC) No. 1272/2008 [CLP] Non-Hazardous Ingredients Mixture 60 - 80 Substance not classified as hazardous Aluminium Oxide (non-fibrous) (CAS-No.) 1344-28-1 10 - 30 Substance with a national occupational (EC-No.) 215-691-6 exposure limit (REACH-No.) 01- 2119529248-35 Sulfuric acid, mono-C12-14-alkyl esters, (CAS-No.) 85586-07-8 1 - 5 Acute Tox. 4, H302 sodium salts (EC-No.) 287-809-4 Skin Irrit. 2, H315 Eye Dam. 1, H318 Aquatic Chronic 3, H412 Amines, C12-14-alkyldimethyl, N-oxides (CAS-No.) 308062-28-4 < 0.5 Acute Tox. 4, H302 (EC-No.) 931-292-6 Skin Irrit. 2, H315 Eye Dam. 1, H318 Aquatic Acute 1, H400,M=1 Aquatic Chronic 2, H411 reaction mass of: 5-chloro-2-methyl-4- (CAS-No.) 55965-84-9 < 0.0015 EUH071 isothiazolin-3-one [EC no. 247-500- (EC-No.) 911-418-6 Acute Tox. 3, H301 7]and 2-methyl-2H-isothiazol-3-one [EC Skin Corr. 1C, H314 no. 220-239-6] (3:1) Eye Dam. 1, H318 Skin Sens. 1A, H317 Aquatic Acute 1, H400,M=100 Aquatic Chronic 1, H410,M=100 Nota B Acute Tox. 2, H330 Acute Tox. 2, H310 Any entry in the Identifier(s) column that begins with the numbers 6, 7, 8, or 9 are a Provisional List Number provided by ECHA pending publication of the official EC Inventory Number for the substance. Please see section 16 for the full text of any H statements referred to in this section Specific Concentration Limits Ingredient Identifier(s) Specific Concentration Limits reaction mass of: 5-chloro-2-methyl-4- (CAS-No.) 55965-84-9 (C >= 0.6%) Skin Corr. 1C, H314 isothiazolin-3-one [EC no. 247-500-7]and 2- (EC-No.) 911-418-6 (0.06% =< C < 0.6%) Skin Irrit. 2, H315 methyl-2H-isothiazol-3-one [EC no. 220- (C >= 0.6%) Eye Dam. 1, H318 239-6] (3:1) (0.06% =< C < 0.6%) Eye Irrit. 2, H319 (C >= 0.0015%) Skin Sens. 1A, H317 Sulfuric acid, mono-C12-14-alkyl esters, (CAS-No.) 85586-07-8 (C >= 20%) Eye Dam. 1, H318 sodium salts (EC-No.) 287-809-4 (10% =< C < 20%) Eye Irrit. 2, H319 For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Remove person to fresh air. If you feel unwell, get medical attention. Skin contact Wash with soap and water. If signs/symptoms develop, get medical attention. Eye contact Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. If swallowed Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed The most important symptoms and effects based on the CLP classification include: Serious irritation to the eyes (significant redness, swelling, pain, tearing, and impaired vision). 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Extinguishing media Material will not burn. 5.2. Special hazards arising from the substance or mixture None inherent in this product. 5.3. Advice for fire-fighters No special protective actions for fire-fighters are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapours, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dykes to prevent entry into sewer systems or bodies of water.