3M(TM) 51004 - Filler

Hazard statements (CLP)

H226, H315, H317, H319, H335, H361d, H372, H412

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Hazard pictograms

GHS02 (Flame) |GHS07 (Exclamation mark) |GHS08 (Health Hazard) | Ingredients: Ingredient CAS Nbr EC No. % by Wt styrene 100-42-5 202-851-5 < 20 (1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1- 42978-66-5 256-032-2 < 3 ethanediyl)] diacrylate M-TOLYLDIETHANOLAMINE 91-99-6 202-114-8 < 1.5 N-ethyl-2-pyrrolidone 2687-91-4 220-250-6 0.05 - < 0.5 maleic anhydride 108-31-6 203-571-6 < 0.1

Hazard statements

H226 Flammable liquid and vapour. H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H361d Suspected of damaging the unborn child. H335 May cause respiratory irritation. H372 Causes damage to organs through prolonged or repeated exposure: sensory organs. H412 Harmful to aquatic life with long lasting effects.

Prevention

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260A Do not breathe vapours. P280K Wear protective gloves and respiratory protection.

Response

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. P370 + P378 In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish.

Additional information

Supplemental Precautionary Statements: Provide ventilation adequate to maintain vapour concentration below lower explosive concentration. 14% of the mixture consists of components of unknown acute oral toxicity. 44% of the mixture consists of components of unknown acute inhalation toxicity.

Contains

14% of components with unknown hazards to the aquatic environment EU VOC Directive (2004/42/EC) labelling: 2004/42/EC IIB(b)(250) 100 g/l

2.3 Other hazards

None known. This material does not contain any substances that are assessed to be a PBT or vPvB

2.1 Classification of the substance or mixture

CLP REGULATION (EC) No 1272/2008 The health and environmental classifications of this material have been derived using the calculation method, except in cases where test data are available or the physical form impacts classification. Classification(s) based on test data or physical form are noted below, if applicable. The aspiration hazard classification is not required due to the product's physical form. CLASSIFICATION: Flammable Liquid, Category 3 - Flam. Liq. 3; H226 Skin Corrosion/Irritation, Category 2 - Skin Irrit. 2; H315 Serious Eye Damage/Eye Irritation, Category 2 - Eye Irrit. 2; H319 Skin Sensitization, Category 1 - Skin Sens. 1; H317 Reproductive Toxicity, Category 2 - Repr. 2; H361d Specific Target Organ Toxicity-Repeated Exposure, Category 1 - STOT RE 1; H372 Specific Target Organ Toxicity-Single Exposure, Category 3 - STOT SE 3; H335 Hazardous to the Aquatic Environment (Chronic), Category 3 - Aquatic Chronic 3; H412 For full text of H phrases, see Section 16. 2.2. Label elements CLP REGULATION (EC) No 1272/2008 SIGNAL WORD DANGER. Symbols GHS02 (Flame) |GHS07 (Exclamation mark) |GHS08 (Health Hazard) | Pictograms Ingredients: Ingredient CAS Nbr EC No. % by Wt styrene 100-42-5 202-851-5 < 20 (1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1- 42978-66-5 256-032-2 < 3 ethanediyl)] diacrylate M-TOLYLDIETHANOLAMINE 91-99-6 202-114-8 < 1.5 N-ethyl-2-pyrrolidone 2687-91-4 220-250-6 0.05 - < 0.5 maleic anhydride 108-31-6 203-571-6 < 0.1 HAZARD STATEMENTS: H226 Flammable liquid and vapour. H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H361d Suspected of damaging the unborn child. H335 May cause respiratory irritation. H372 Causes damage to organs through prolonged or repeated exposure: sensory organs. H412 Harmful to aquatic life with long lasting effects. PRECAUTIONARY STATEMENTS Prevention: P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260A Do not breathe vapours. P280K Wear protective gloves and respiratory protection. Response: P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. P370 + P378 In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. SUPPLEMENTAL INFORMATION: Supplemental Precautionary Statements: Provide ventilation adequate to maintain vapour concentration below lower explosive concentration. 14% of the mixture consists of components of unknown acute oral toxicity. 44% of the mixture consists of components of unknown acute inhalation toxicity. Contains 14% of components with unknown hazards to the aquatic environment. EU VOC Directive (2004/42/EC) labelling: 2004/42/EC IIB(b)(250) 100 g/l 2.3. Other hazards None known. This material does not contain any substances that are assessed to be a PBT or vPvB SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Ingredient Identifier(s) % Classification according to Regulation (EC) No. 1272/2008 [CLP] Unsaturated Polyester Resin None 15 - 40 Aquatic Chronic 4, H413 Talc (CAS-No.) 14807-96-6 10 - 30 Substance with a national occupational (EC-No.) 238-877-9 exposure limit Dolomite (CAS-No.) 16389-88-1 5 - 20 Substance with a national occupational (EC-No.) 240-440-2 exposure limit styrene (CAS-No.) 100-42-5 < 20 Flam. Liq. 3, H226 (EC-No.) 202-851-5 Acute Tox. 4, H332 (REACH-No.) 01- Skin Irrit. 2, H315 2119457861-32 Eye Irrit. 2, H319 Repr. 2, H361d STOT RE 1, H372 Nota D Asp. Tox. 1, H304 STOT SE 3, H335 Aquatic Chronic 3, H412 Unsatured Polyester Resin 2 Trade Secret 1 - 10 Substance not classified as hazardous