3M Scotch-Weld Epoxy Adhesive DP405 Black, Part A

Hazard statements (CLP)

H312, H314, H317, H318

Code

Statements

H312

Harmful in contact with skin

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Hazard pictograms

GHS05 (Corrosion) |GHS07 (Exclamation mark) | Ingredients: Ingredient CAS Nbr EC No. % by Wt 3,3'-Oxybis(ethyleneoxy)bis(propylamine) 4246-51-9 224-207-2 10 - 30 N,N'-Bis(3-aminopropyl)ethylenediamine 10563-26-5 234-147-9 <= 15 2,4,6-tris(dimethylaminomethyl)phenol 90-72-2 202-013-9 < 5

Hazard statements

H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction.

Prevention

P260A Do not breathe vapours. P280D Wear protective gloves, protective clothing, and eye/face protection. P260A Do not breathe vapours. P280D Wear protective gloves, protective clothing, and eye/face protection.

Response

P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. For containers not exceeding 125 ml the following Hazard and Precautionary statements may be used: <=125 ml Hazard statements H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. <=125 ml Precautionary statements P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.

Contains

60% of components with unknown hazards to the aquatic environment

2.3 Other hazards

Persons previously sensitised to amines may develop a cross-sensitisation reaction to certain other amines. This material does not contain any substances that are assessed to be a PBT or vPvB

2.1 Classification of the substance or mixture

CLP REGULATION (EC) No 1272/2008 The health and environmental classifications of this material have been derived using the calculation method, except in cases where test data are available or the physical form impacts classification. Classification(s) based on test data or physical form are noted below, if applicable. CLASSIFICATION: Acute Toxicity, Category 4 - Acute Tox. 4; H312 Skin Corrosion/Irritation, Category 1B - Skin Corr. 1B; H314 Serious Eye Damage/Eye Irritation, Category 1 - Eye Dam. 1; H318 Skin Sensitization, Category 1 - Skin Sens. 1; H317 For full text of H phrases, see Section 16. 2.2. Label elements CLP REGULATION (EC) No 1272/2008 SIGNAL WORD DANGER. Symbols GHS05 (Corrosion) |GHS07 (Exclamation mark) | Pictograms Ingredients: Ingredient CAS Nbr EC No. % by Wt 3,3'-Oxybis(ethyleneoxy)bis(propylamine) 4246-51-9 224-207-2 10 - 30 N,N'-Bis(3-aminopropyl)ethylenediamine 10563-26-5 234-147-9 <= 15 2,4,6-tris(dimethylaminomethyl)phenol 90-72-2 202-013-9 < 5 HAZARD STATEMENTS: H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. PRECAUTIONARY STATEMENTS Prevention: P260A Do not breathe vapours. P280D Wear protective gloves, protective clothing, and eye/face protection. Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. For containers not exceeding 125 ml the following Hazard and Precautionary statements may be used: <=125 ml Hazard statements H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. <=125 ml Precautionary statements Prevention: P260A Do not breathe vapours. P280D Wear protective gloves, protective clothing, and eye/face protection. Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. Contains 60% of components with unknown hazards to the aquatic environment. 2.3. Other hazards Persons previously sensitised to amines may develop a cross-sensitisation reaction to certain other amines. This material does not contain any substances that are assessed to be a PBT or vPvB SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Ingredient Identifier(s) % Classification according to Regulation (EC) No. 1272/2008 [CLP] Modified Epoxy Resin Trade Secret 40 - 60 Substance not classified as hazardous 3,3'- (CAS-No.) 4246-51-9 10 - 30 Skin Corr. 1B, H314 Oxybis(ethyleneoxy)bis(propylamine) (EC-No.) 224-207-2 Eye Dam. 1, H318 (REACH-No.) 01- Skin Sens. 1, H317 2119963377-26 N,N'-Bis(3-aminopropyl)ethylenediamine (CAS-No.) 10563-26-5 <= 15 Acute Tox. 3, H311 (EC-No.) 234-147-9 Acute Tox. 4, H302 Skin Corr. 1B, H314 Eye Dam. 1, H318 Skin Sens. 1A, H317 Nepheline syenite (CAS-No.) 37244-96-5 1 - 10 Substance not classified as hazardous Silane, trimethoxyoctyl-, hydrolysis (CAS-No.) 92797-60-9 0.5 - 5 Substance not classified as hazardous products with silica (EC-No.) 296-597-2 2,4,6-tris(dimethylaminomethyl)phenol (CAS-No.) 90-72-2