3M SCOTCH-WELD EC-7210 (Part A)

Hazard statements (CLP)

H314, H317, H318, H411

Code

Statements

H314

Causes severe skin burns and eye damage

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Hazard pictograms

GHS05 (Corrosion) |GHS07 (Exclamation mark) |GHS09 (Environment) | Ingredients: Ingredient Identifier(s) EC No. % by Wt Hydrogenated terphenyl 61788-32-7 262-967-7 < 10 2,4,6-tris(dimethylaminomethyl)phenol 90-72-2 202-013-9 < 5 3,6-diazaoctanethylenediamin 112-24-3 203-950-6 < 2

Hazard statements

H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H411 Toxic to aquatic life with long lasting effects. EUH441 Strongly accumulates in the environment and living organisms including in humans.

Prevention

P201 Obtain special instructions before use. P260A Do not breathe vapours. P273 Avoid release to the environment. P280D Wear protective gloves, protective clothing, and eye/face protection. P201 Obtain special instructions before use. P260A Do not breathe vapours. P273 Avoid release to the environment. P280D Wear protective gloves, protective clothing, and eye/face protection.

Response

P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. P391 Collect spillage. For containers not exceeding 125 ml the following Hazard and Precautionary statements may be used: <=125 ml Hazard statements H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. EUH441 Strongly accumulates in the environment and living organisms including in humans. <=125 ml Precautionary statements P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. 42% of the mixture consists of components of unknown acute oral toxicity. 42% of the mixture consists of components of unknown acute dermal toxicity.

Contains

49% of components with unknown hazards to the aquatic environment

2.3 Other hazards

Persons previously sensitised to amines may develop a cross-sensitisation reaction to certain other amines. Contains a

2.1 Classification of the substance or mixture

CLP REGULATION (EC) No 1272/2008 The health and environmental classifications of this material have been derived using the calculation method, except in cases where test data are available or the physical form impacts classification. Classification(s) based on test data or physical form are noted below, if applicable. CLASSIFICATION: Skin Corrosion/ Irritation, Category 1C - Skin Corr. 1C; H314 Serious Eye Damage/Eye Irritation, Category 1 - Eye Dam. 1; H318 Skin Sensitization, Category 1 - Skin Sens. 1; H317 Hazardous to the Aquatic Environment (Chronic), Category 2 - Aquatic Chronic 2; H411 Very Persistent, Very Bioaccumulative – vPvB; EUH441 For full text of H phrases, see Section 16. 2.2. Label elements CLP REGULATION (EC) No 1272/2008 SIGNAL WORD DANGER. Symbols GHS05 (Corrosion) |GHS07 (Exclamation mark) |GHS09 (Environment) | Pictograms Ingredients: Ingredient Identifier(s) EC No. % by Wt Hydrogenated terphenyl 61788-32-7 262-967-7 < 10 2,4,6-tris(dimethylaminomethyl)phenol 90-72-2 202-013-9 < 5 3,6-diazaoctanethylenediamin 112-24-3 203-950-6 < 2 HAZARD STATEMENTS: H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H411 Toxic to aquatic life with long lasting effects. EUH441 Strongly accumulates in the environment and living organisms including in humans. PRECAUTIONARY STATEMENTS Prevention: P201 Obtain special instructions before use. P260A Do not breathe vapours. P273 Avoid release to the environment. P280D Wear protective gloves, protective clothing, and eye/face protection. Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. P391 Collect spillage. For containers not exceeding 125 ml the following Hazard and Precautionary statements may be used: <=125 ml Hazard statements H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. EUH441 Strongly accumulates in the environment and living organisms including in humans. <=125 ml Precautionary statements Prevention: P201 Obtain special instructions before use. P260A Do not breathe vapours. P273 Avoid release to the environment. P280D Wear protective gloves, protective clothing, and eye/face protection. Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. 42% of the mixture consists of components of unknown acute oral toxicity. 42% of the mixture consists of components of unknown acute dermal toxicity. Contains 49% of components with unknown hazards to the aquatic environment. 2.3. Other hazards Persons previously sensitised to amines may develop a cross-sensitisation reaction to certain other amines. Contains a substance that meets the criteria for vPvB according to Regulation (EC) No 1907/2006, Annex XIII SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Ingredient Identifier(s) % Classification according to Regulation (EC) No. 1272/2008 [CLP] Reaction products of pentaerythritol, (CAS-No.) 72244- 30 - 60 Skin Sens. 1B, H317 propoxylated and 1-chloro-2,3- 98-5 Aquatic Chronic 3, H412 epoxypropane with hydrogen sulphide (EC-No.) 701-196-7 (REACH-No.) 01- 2120118957-46 Modified Epoxy Resin Trade Secret 10 - 30 Substance not classified as hazardous Hydrogenated terphenyl (CAS-No.) 61788- < 10 vPvB , EUH441 32-7 Aquatic Chronic 2, H411 (EC-No.) 262-967-7 (REACH-No.) 01- 2119488183-33 2,4,6-tris(dimethylaminomethyl)phenol (CAS-No.) 90-72-2 < 5 Acute Tox. 4, H302 (EC-No.) 202-013-9 Skin Corr. 1C, H314 (REACH-No.) 01- Eye Dam. 1, H318 2119560597-27