3M Scotch-Weld DP-490 Black Structural Adhesive Part B

Hazard statements (CLP)

H315, H317, H319, H411

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Signal word

WARNING.

Hazard pictograms

GHS07 (Exclamation mark) |GHS09 (Environment) | Ingredients: Ingredient CAS Nbr EC No. % by Wt bis-[4-(2,3-epoxipropoxi)phenyl]propane 1675-54-3 216-823-5 50 - 60 1,4-Bis[(2,3-epoxypropoxy)methyl]cyclohexane 14228-73-0 238-098-4 5 - 15

Hazard statements

H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H411 Toxic to aquatic life with long lasting effects.

Prevention

P273 Avoid release to the environment. P280E Wear protective gloves. P280E Wear protective gloves.

Response

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. P391 Collect spillage. For containers not exceeding 125 ml the following Hazard and Precautionary statements may be used: <=125 ml Hazard statements H317 May cause an allergic skin reaction. <=125 ml Precautionary statements P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.

Supplemental label elements

EUH212 Warning! Hazardous respirable dust may be formed when used. Do not breathe dust. 16% of the mixture consists of components of unknown acute oral toxicity.

Contains

20% of components with unknown hazards to the aquatic environment

2.3 Other hazards

None known. This material does not contain any substances that are assessed to be a PBT or vPvB

2.1 Classification of the substance or mixture

CLP REGULATION (EC) No 1272/2008 The health and environmental classifications of this material have been derived using the calculation method, except in cases where test data are available or the physical form impacts classification. Classification(s) based on test data or physical form are noted below, if applicable. The carcinogenicity classification for titanium dioxide is not applicable based on physical form (material is not a powder). CLASSIFICATION: Skin Corrosion/Irritation, Category 2 - Skin Irrit. 2; H315 Serious Eye Damage/Eye Irritation, Category 2 - Eye Irrit. 2; H319 Skin Sensitization, Category 1 - Skin Sens. 1; H317 Hazardous to the Aquatic Environment (Chronic), Category 2 - Aquatic Chronic 2; H411 For full text of H phrases, see Section 16. 2.2. Label elements CLP REGULATION (EC) No 1272/2008 SIGNAL WORD WARNING. Symbols GHS07 (Exclamation mark) |GHS09 (Environment) | Pictograms Ingredients: Ingredient CAS Nbr EC No. % by Wt bis-[4-(2,3-epoxipropoxi)phenyl]propane 1675-54-3 216-823-5 50 - 60 1,4-Bis[(2,3-epoxypropoxy)methyl]cyclohexane 14228-73-0 238-098-4 5 - 15 HAZARD STATEMENTS: H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H411 Toxic to aquatic life with long lasting effects. PRECAUTIONARY STATEMENTS Prevention: P273 Avoid release to the environment. P280E Wear protective gloves. Response: P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. P391 Collect spillage. For containers not exceeding 125 ml the following Hazard and Precautionary statements may be used: <=125 ml Hazard statements H317 May cause an allergic skin reaction. <=125 ml Precautionary statements Prevention: P280E Wear protective gloves. Response: P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. SUPPLEMENTAL INFORMATION: Supplemental Hazard Statements: EUH212 Warning! Hazardous respirable dust may be formed when used. Do not breathe dust. 16% of the mixture consists of components of unknown acute oral toxicity. Contains 20% of components with unknown hazards to the aquatic environment. 2.3. Other hazards None known. This material does not contain any substances that are assessed to be a PBT or vPvB SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Ingredient Identifier(s) % Classification according to Regulation (EC) No. 1272/2008 [CLP] bis-[4-(2,3-epoxipropoxi)phenyl]propane (CAS-No.) 1675-54-3 50 - 60 Skin Irrit. 2, H315 (EC-No.) 216-823-5 Eye Irrit. 2, H319 (REACH-No.) 01- Skin Sens. 1, H317 2119456619-26 Aquatic Chronic 2, H411 MBS POLYMER (METHYL Trade Secret 10 - 20 Substance not classified as hazardous METHACRYLATE-BUTADIENE- STYRENE POLYMER) 1,4-Bis[(2,3- (CAS-No.) 14228-73-0 5 - 15 Aquatic Chronic 3, H412 epoxypropoxy)methyl]cyclohexane (EC-No.) 238-098-4 Acute Tox. 4, H302 Skin Irrit. 2, H315 Skin Sens. 1B, H317 Oxide glass chemicals (CAS-No.) 65997-17-3 1 - 5 Substance with a national occupational (EC-No.) 266-046-0 exposure limit Carbon black (CAS-No.) 1333-86-4 1 - 5 Substance with a national occupational (EC-No.) 215-609-9 exposure limit (REACH-No.) 01- 2119384822-32 Siloxanes and Silicones, di-Me, reaction (CAS-No.) 67762-90-7 1 - 5 Substance not classified as hazardous products with silica [3-(2,3- (CAS-No.) 2530-83-8 0.5 - 1.5 Eye Dam. 1, H318 epoxypropoxy)propyl]trimethoxysilane (EC-No.) 219-784-2 Aquatic Chronic 3, H412 (REACH-No.) 01- 2119513212-58 Titanium dioxide (CAS-No.) 13463-67-7 0.5 - 1.5 Carc. 2, H351 (inhalation) (EC-No.) 236-675-5 (REACH-No.) 01- 2119489379-17 2,6-Di-tert-butyl-p-cresol (CAS-No.) 128-37-0 < 1 Aquatic Chronic 1, H410,M=1 (EC-No.) 204-881-4 Aquatic Acute 1, H400,M=1 (REACH-No.) 01-