3M Impact Resistant Structural Adhesive, PN 07444 - Part A

Hazard statements (CLP)

H302, H302+H312, H312, H314, H318, H412

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Hazard pictograms

GHS05 (Corrosion) |GHS07 (Exclamation mark) | Ingredients: Ingredient CAS Nbr EC No. % by Wt Reaction products of di-, tri- and tetra- 9046-10-0 618-561-0 10 - 30 propoxylated propane-1,2-diol with ammonia 2,2'-dimethyl-4,4'- 6864-37-5 229-962-1 3 - 7 methylenebis(cyclohexylamine) Nitric acid, calcium salt, tetrahydrate 13477-34-4 233-332-1 < 2 2,4,6-tris(dimethylaminomethyl)phenol 90-72-2 202-013-9 0.5 - 1.5

Hazard statements

H302 + H312 Harmful if swallowed or in contact with skin. H314 Causes severe skin burns and eye damage. H412 Harmful to aquatic life with long lasting effects.

Prevention

P260A Do not breathe vapours. P280D Wear protective gloves, protective clothing, and eye/face protection.

Response

P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. 50% of the mixture consists of components of unknown acute oral toxicity. 50% of the mixture consists of components of unknown acute dermal toxicity.

Contains

53% of components with unknown hazards to the aquatic environment

2.3 Other hazards

None known. This material does not contain any substances that are assessed to be a PBT or vPvB

2.1 Classification of the substance or mixture

CLP REGULATION (EC) No 1272/2008 The health and environmental classifications of this material have been derived using the calculation method, except in cases where test data are available or the physical form impacts classification. Classification(s) based on test data or physical form are noted below, if applicable. CLASSIFICATION: Acute Toxicity, Category 4 - Acute Tox. 4; H302 Acute Toxicity, Category 4 - Acute Tox. 4; H312 Skin Corrosion/ Irritation, Category 1A - Skin Corr. 1A; H314 Serious Eye Damage/Eye Irritation, Category 1 - Eye Dam. 1; H318 Hazardous to the Aquatic Environment (Chronic), Category 3 - Aquatic Chronic 3; H412 For full text of H phrases, see Section 16. 2.2. Label elements CLP REGULATION (EC) No 1272/2008 SIGNAL WORD DANGER. Symbols GHS05 (Corrosion) |GHS07 (Exclamation mark) | Pictograms Ingredients: Ingredient CAS Nbr EC No. % by Wt Reaction products of di-, tri- and tetra- 9046-10-0 618-561-0 10 - 30 propoxylated propane-1,2-diol with ammonia 2,2'-dimethyl-4,4'- 6864-37-5 229-962-1 3 - 7 methylenebis(cyclohexylamine) Nitric acid, calcium salt, tetrahydrate 13477-34-4 233-332-1 < 2 2,4,6-tris(dimethylaminomethyl)phenol 90-72-2 202-013-9 0.5 - 1.5 HAZARD STATEMENTS: H302 + H312 Harmful if swallowed or in contact with skin. H314 Causes severe skin burns and eye damage. H412 Harmful to aquatic life with long lasting effects. PRECAUTIONARY STATEMENTS Prevention: P260A Do not breathe vapours. P280D Wear protective gloves, protective clothing, and eye/face protection. Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. 50% of the mixture consists of components of unknown acute oral toxicity. 50% of the mixture consists of components of unknown acute dermal toxicity. Contains 53% of components with unknown hazards to the aquatic environment. 2.3. Other hazards None known. This material does not contain any substances that are assessed to be a PBT or vPvB SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Ingredient Identifier(s) % Classification according to Regulation (EC) No. 1272/2008 [CLP] Phenol, 4,4'-(1-methylethylidene)bis-, (CAS-No.) 68318- 15 - 40 Substance not classified as hazardous polymer with .alpha.-(2- 44-5 aminomethylethyl)-.omega.-(2- aminomethylethoxy)poly[oxy(methyl-1,2- ethanediyl)] and (chloromethyl)oxirane Reaction products of di-, tri- and tetra- (CAS-No.) 9046-10- 10 - 30 Skin Corr. 1C, H314 propoxylated propane-1,2-diol with 0 Eye Dam. 1, H318 ammonia (EC-No.) 618-561-0 Aquatic Chronic 3, H412 Methyl methacrylate - butadiene - styrene None 5 - 10 Substance not classified as hazardous polymer Aluminium (CAS-No.) 7429-90- 5 - 10 Flam. Sol. 1, H228 5 Water-react. 2, H261 (EC-No.) 231-072-3 Nota T (REACH-No.) 01- 2119529243-45 2,2'-dimethyl-4,4'- (CAS-No.) 6864-37- 3 - 7 Acute Tox. 2, H330 methylenebis(cyclohexylamine) 5