COMPUBLEND (TM) II SPOT/STAIN REMOVER (Ready-to-Use)

SECTION 2: Hazards identification

29 CFR 1910.1200) 3.1 EMERGENCY OVERVIEW Specific Physical Form: Liquid Odor, Color, Grade: Clear dark turquoise, citrus floral fragrance General Physical Form: Liquid Immediate health, physical, and environmental hazards: May cause allergic skin reaction. May cause target organ effects. Contains a chemical or chemicals which can cause birth defects or other reproductive harm.

Potential health effects

Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin Contact: Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. May be absorbed through skin and cause target organ effects. Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Prolonged or repeated exposure may cause: Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and jaundice. Kidney/Bladder Effects: Signs/symptoms may include changes in urine production, abdominal or lower back pain, increased protein in urine, increased blood urea nitrogen (BUN), blood in urine, and painful urination. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Flash Point > 200 ºF OSHA Flammability Classification: Class IIIB Combustible Liquid 5.2 EXTINGUISHING MEDIA Ordinary combustible material. Use fire extinguishers with class A extinguishing agents (e.g., water, foam). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards Non-flammable ordinary combustible material Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more information on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible. Clean up residue with water. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Keep out of the reach of children. Avoid breathing of vapors, mists or spray. Avoid skin contact. Avoid eye contact with vapors, mists, or spray. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.

Storage

Store under normal warehouse conditions. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use in a well-ventilated area. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Safety Glasses with side shields, Indirect Vented Goggles. 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Butyl Rubber, Neoprene, Nitrile Rubber. 8.2.3 Respiratory Protection Avoid breathing of vapors, mists or spray. Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit

Additional information

1-METHOXY-2-PROPANOL ACGIH TWA 100 ppm 1-METHOXY-2-PROPANOL ACGIH STEL 150 ppm 1-METHOXY-2-PROPANOL OSHA TWA 100 ppm Table Z-1A 1-METHOXY-2-PROPANOL OSHA STEL 150 ppm Table Z-1A 2-BUTOXYETHANOL ACGIH TWA 20 ppm Table A3 2-BUTOXYETHANOL OSHA TWA, Vacated 25 ppm Skin Notation* 2-BUTOXYETHANOL OSHA TWA 50 ppm Skin Notation*; Table Z-1 POLYETHYLENE GLYCOLS AIHA TWA, as aerosol 10 mg/m3 * Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. VAC Vacated PEL:Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your local regulatory agency. SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Specific Physical Form: Liquid Odor, Color, Grade: Clear dark turquoise, citrus floral fragrance General Physical Form: Liquid Flash Point > 200 ºF Boiling point Approximately 200 ºF Specific Gravity Approximately 0.9 [Ref Std: WATER=1] pH 7.5 Solubility in Water Complete Volatile Organic Compounds 10 - 20 % [Test Method: calculated per CARB title 2] VOC Less H2O & Exempt Solvents 700 - 1300 g/l [Test Method: calculated per CARB title 2] Viscosity < 100 centipoise SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: None known Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion

TOXICOLOGICAL INFORMATION

Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. A 3M Product Environmental Data Sheet (PED) is available. CHEMICAL FATE INFORMATION A 3M Product Environmental Data Sheet (PED) is available. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Discharge spent solutions and small quantities (less than 5 gal.(19 L)) to a wastewater treatment system. Reduce discharge rate if foaming occurs. As a disposal alternative, dispose of waste product in a facility permitted to accept chemical waste. EPA Hazardous Waste Number (RCRA): Not regulated Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt 2-BUTOXYETHANOL (GLYCOL ETHERS) 111-76-2 7 - 13 STATE REGULATIONS CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. All the components of this product are listed on China's Inventory of Chemical Substances. The components of this product are listed on the Canadian Domestic Substances List. INTERNATIONAL REGULATIONS This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

Further information

NFPA Hazard Classification Health 2 Flammability 1 Reactivity 0 Special None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

HMIS® ratings

Health 2 Flammability 1 Reactivity 0 Protection X - See PPE section Hazardous Material Identification System (HMIS®) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint and Coatings Association (NPCA). Revision Changes: Section 1: Product name was modified. Section 1: Product use information was modified. Section 16: NFPA hazard classification heading was modified. Section 16: HMIS hazard classification heading was modified. Section 3: Other potential health effects heading was modified. Copyright was modified. Section 8: Exposure guidelines data source legend was modified. Section 4: First aid for eye contact - decontamination - was modified. Section 4: First aid for eye contact - medical assistance - was modified. Section 3: Potential effects from skin contact information was modified. Section 3: Potential effects from inhalation information was modified. Section 3: Potential effects from ingestion information was modified. Section 7: Handling information was modified. Section 8: Respiratory protection information was modified. Section 8: Eye/face protection information was modified. Section 15: 311/312 hazard categories heading was modified. Section 4: First aid for skin contact - medical assistance - was modified. Section 4: First aid for inhalation - termination of exposure - was modified. Section 4: First aid for inhalation - medical assistance - was modified. Section 4: First aid for ingestion (swallowing) - medical assistance - was modified. Section 10: Hazardous polymerization heading was modified. Section 3: Immediate other hazard(s) was modified. Section 2: Ingredient table was modified. Section 3: Other health effects information was modified. Section 16: HMIS explanation was modified. Section 16: NFPA explanation was modified. Page Heading: Product name was modified. Section 15: Inventories information was modified. Section 15: EPCRA 313 information was modified. Section 15: EPCRA 313 text was modified. Section 12: Ecotoxicological information heading was modified. Section 12: Chemical fate information heading was modified. Section 8: Exposure guidelines ingredient information was modified. Section 8: Exposure guidelines legend was modified. Section 8: Exposure guideline note was modified. Section 9: Property description for optional properties was modified. Section 1: Initial issue message was modified. Section 16: NFPA hazard classification for special hazards was modified. Section 12: Ecotoxicological phrase was modified. Section 12: Chemical Fate phrase was modified. Section 3: Immediate skin hazard(s) was added. Section 4: First aid for skin contact - termination of exposure - was added. Section 4: First aid for skin contact - handling - was added. Sections 3 and 9: Specific physical form information was added. Sections 3 and 9: Specific physical form heading was added. Section 2: Ingredient phrase was added. Section 3: Other health effects information (reproductive hazards) was added. Section 9: Density information was deleted. Section 9: Vapor density value was deleted. Section 9: Vapor pressure value was deleted.