Note: Ingredients listed on restricted chemical lists
EC/CAS
25068-38-6
Name of the chemical
4,4'-Isopropylidenediphenol, oligomeric reaction products with 1-chloro-2,3-epoxypropane
Concentration
N/A
General Information
Revision date
2007-01-16
Product name
Scotchcast Brand Electrical Resin 262
CAS No.
25068-38-6
Manufacturer Name
3M
Emergency telephone
1-800-364-3577 or (651) 737-6501 (24 hours
Icons in SDS
Company Information
company name
3M
Section 2
SECTION 2: Hazards identification
29 CFR 1910.1200) 3.1 EMERGENCY OVERVIEW Specific Physical Form: Powder Odor, Color, Grade: Red Powder General Physical Form: Solid Immediate health, physical, and environmental hazards: Dust clouds of this material in combination with an ignition source may be explosive. Contains a chemical or chemicals which can cause cancer. May cause target organ effects.
Potential health effects
Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Vapors released during curing may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Dust created by cutting, grinding, sanding, or machining may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin Contact: Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Inhalation: Vapors released during curing may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Dust from cutting, grinding, sanding or machining may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate, bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure. Prolonged or repeated exposure may cause: Silicosis: Signs/symptoms may include breathlessness, weakness, chest pain, persistent cough, increased amounts of sputum, and heart disease. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient C.A.S. No. Class Description Regulation QUARTZ SILICA 14808-60-7 Group 1 International Agency for Research on Cancer QUARTZ SILICA 14808-60-7 Known human carcinogen National Toxicology Program Carcinogens SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. If signs/symptoms develop, get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature 450 - 550 ºC [Details: For Dust Cloud Form; determined on a range of typical coating powders.] Autoignition temperature 325 - 375 ºC [Details: For Dust Layer Form; determined on a range of typical coating powders.] Flash Point Not Applicable Flammable Limits - LEL 35 - 55 g/m3 [Details: Minimum Explosive Concentration (MEC) for dust-air mixture; determined on a range of typical coating powders.] Flammable Limits - UEL No Data Available 5.2 EXTINGUISHING MEDIA Ordinary combustible material. Use fire extinguishers with class A extinguishing agents (e.g., water, foam). Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: Dust clouds of this material in combination with an ignition source may be explosive. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more information on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Collect as much of the spilled material as possible. Use wet sweeping compound or water to avoid dusting. Sweep up. Place in a closed container approved for transportation by appropriate authorities. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Do not spray near flames or sources of ignition. Avoid eye contact with dust or airborne particles. Avoid eye contact with vapors, mists, or spray. Avoid breathing of airborne material. Avoid breathing of fumes. Avoid breathing of vapors created during cure cycle. Avoid breathing of dust created by cutting, sanding, grinding or machining. Avoid skin contact. Avoid skin contact with hot material. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. For industrial or professional use only. Keep out of the reach of children.
Storage
Keep container in well-ventilated area. Store away from heat. Store away from flammable and combustible materials. Keep container tightly closed. Store at temperatures which are below 80 degrees F (27 degrees C). SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Provide local exhaust ventilation at transfer points. Provide ventilated enclosure for heat curing. Provide appropriate local exhaust for molten or extruded material. Curing enclosures must be exhausted to outdoors or to a suitable emission control device. Provide appropriate local exhaust when product is heated. Provide ventilation adequate to control dust concentrations below recommended exposure limits and/or control dust. Cool down area should be ventilated to prevent vapors from entering the work area. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Safety Glasses with side shields, Indirect Vented Goggles. 8.2.2 Skin Protection Wear appropriate gloves, such as Nomex, when handling this material to prevent thermal burns. Avoid skin contact. Avoid skin contact with hot material. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. 8.2.3 Respiratory Protection Avoid breathing of vapors created during cure cycle. Avoid breathing of fumes. Avoid breathing of dust created by cutting, sanding, grinding or machining. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges and P100 particulate prefilters. Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit
Additional information
MICA-GROUP MINERALS ACGIH TWA, respirable 3 mg/m3 MICA-GROUP MINERALS OSHA TWA, as less than 1% 3 mg/m3 Table Z-1A crystalline silica, respirable QUARTZ SILICA ACGIH TWA, respirable 0.025 mg/m3 Table A2 QUARTZ SILICA OSHA TWA, respirable 0.1 mg/m3 Table Z-1A SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Specific Physical Form: Powder Odor, Color, Grade: Red Powder General Physical Form: Solid Autoignition temperature 450 - 550 ºC [Details: For Dust Cloud Form; determined on a range of typical coating powders.] Autoignition temperature 325 - 375 ºC [Details: For Dust Layer Form; determined on a range of typical coating powders.] Flash Point Not Applicable Flammable Limits - LEL 35 - 55 g/m3 [Details: Minimum Explosive Concentration (MEC) for dust-air mixture; determined on a range of typical coating powders.] Flammable Limits - UEL No Data Available Boiling point Not Applicable Density 1.40 g/cm3 Vapor Density Not Applicable Vapor Pressure Not Applicable Specific Gravity 1.40 [Ref Std: WATER=1] pH Not Applicable Melting point No Data Available Solubility in Water Nil Evaporation rate Not Applicable Volatile Organic Compounds 0 % Percent volatile 0 % VOC Less H2O & Exempt Solvents 0 % Viscosity Not Applicable SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: Sparks and/or flames Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Condition Aldehydes Not Specified Carbon monoxide Not Specified Carbon dioxide Not Specified Ammonia Not Specified Oxides of Nitrogen Not Specified
TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Dispose of completely cured (or polymerized) wastes in a sanitary landfill. As a disposal alternative, dispose of waste product in a facility permitted to accept chemical waste. Be sure that container of waste is not compromised by landfill operation. Destruction of package may cause nuisance dust. EPA Hazardous Waste Number (RCRA): Not regulated Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number(s): 41-4800-0148-0, 80-1300-0542-6 Not regulated per U.S. DOT, IATA or IMO. These transportation classifications are provided as a customer service. As the shipper YOU remain responsible for complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M’s transportation classifications are based on product formulation, packaging, 3M policies and 3M’s understanding of applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information applies only to transportation classification and not the packaging, labeling, or marking requirements. The original 3M package is certified for U.S. ground shipment only. If you are shipping by air or ocean, the package may not meet applicable regulatory requirements. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes STATE REGULATIONS Contact 3M for more information. CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. The components of this product are listed on the Canadian Domestic Substances List. All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information. This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
Further information
NFPA Hazard Classification Health 2 Flammability 1 Reactivity 0 Special None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
HMIS® ratings
Health 2 Flammability 1 Reactivity 0 Protection X - See PPE section Hazardous Material Identification System (HMIS®) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint and Coatings Association (NPCA). Revision Changes: Section 1: Product name was modified. Section 1: Product use information was modified. Copyright was modified. Section 3: Potential effects from eye contact was modified. Section 3: Potential effects from inhalation information was modified. Section 7: Handling information was modified. Section 10: Hazardous decomposition or by-products table was modified. Section 14: Transportation legal text was modified. Section 2: Ingredient table was modified. Page Heading: Product name was modified. Section 15: Inventories information was modified. Section 3: Immediate physical hazard(s) was added. Section 2: Ingredients comment was added. Section 14: Transportation phrase was added. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. 3M MSDSs are available at www.3M.com