Scotch(tm) Contact Cement 6015A, 6014A

SECTION 2: Hazards identification

3.1 EMERGENCY OVERVIEW Odor, Color, Grade: Amber gel with an ether-like odor. General Physical Form: Liquid Immediate health, physical, and environmental hazards: Flammable liquid and vapor. Closed containers exposed to heat from fire may build pressure and explode. Contact with aluminum or zinc in a pressurized system may generate hydrogen gas which could create an explosion hazard. Vapors may travel long distances along the ground or floor to an ignition source and flash back. May cause target organ effects. Contains a chemical or chemicals which can cause birth defects or other reproductive harm.

Potential health effects

Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin Contact: Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. May be absorbed through skin and cause target organ effects. Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May be harmful if inhaled. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be harmful if swallowed. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Prolonged or repeated exposure may cause: Central Neuropathy: Signs/symptoms may include irritability, memory impairment, personality changes, sleep disorders, and decreased ability to concentrate. Peripheral Neuropathy: Signs/symptoms may include tingling or numbness of the extremities, incoordination, weakness of the hands and feet, tremors and muscle atrophy. Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and jaundice. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point -10 ºF [Test Method: Tagliabue Closed Cup] Flammable Limits - LEL 1 % Flammable Limits - UEL 7.5 % 5.2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: Flammable liquid and vapor. Closed containers exposed to heat from fire may build pressure and explode. Contact with aluminum or zinc in a pressurized system may generate hydrogen gas which could create an explosion hazard. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non- sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Cover spill area with a fire-extinguishing foam. An aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible using non-sparking tools. Collect the resulting residue containing solution. Place in a closed container approved for transportation by appropriate authorities. Seal the container. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Keep away from aluminum and zinc. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Ground containers securely when transferring contents. Wear low static or properly grounded shoes. Avoid static discharge. Avoid eye contact with vapors, mists, or spray. Keep out of the reach of children. Avoid contact with oxidizing agents.

Storage

Store away from acids. Store away from heat. Store out of direct sunlight. Keep container in well-ventilated area. Keep container tightly closed. Store away from oxidizing agents. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Provide local exhaust ventilation at transfer points. Provide appropriate local exhaust ventilation on open containers. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Safety Glasses with side shields, Indirect Vented Goggles. 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Butyl Rubber, Natural Rubber. 8.2.3 Respiratory Protection Avoid breathing of vapors. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit Additional Information ACETONE ACGIH TWA 500 ppm Table A4 ACETONE ACGIH STEL 750 ppm Table A4 ACETONE OSHA TWA, Vacated 750 ppm ACETONE OSHA TWA 1000 ppm Table Z-1 ACETONE OSHA STEL, Vacated 1000 ppm HEXANE ACGIH TWA 50 ppm Skin Notation* HEXANE OSHA TWA, Vacated 50 ppm Table Z-1A HEXANE OSHA TWA 500 ppm Table Z-1A TOLUENE ACGIH TWA 20 ppm Table A4 TOLUENE CMRG STEL 75 ppm Skin Notation* TOLUENE OSHA TWA, Vacated 100 ppm TOLUENE OSHA STEL, Vacated 150 ppm TOLUENE OSHA TWA 200 ppm Table Z-2 TOLUENE OSHA CEIL 300 ppm Table Z-2 * Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. VAC Vacated PEL:Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your local regulatory agency. SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Odor, Color, Grade: Amber gel with an ether-like odor. General Physical Form: Liquid Autoignition temperature No Data Available Flash Point -10 ºF [Test Method: Tagliabue Closed Cup] Flammable Limits - LEL 1 % Flammable Limits - UEL 7.5 % Boiling point 151 ºF Density No Data Available Vapor Density 3 Vapor Pressure 125 mmHg Specific Gravity .88 [@ 77 ºF] pH Not Applicable Melting point No Data Available Solubility in Water Nil SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: Strong acids; Strong oxidizing agents; Strong bases; Aluminum Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products