PM-8576 (Accelerator for 3M Panel Bonding Adhesive, P/N 08115) (Intermediate)

SECTION 2: Hazards identification

OSHA 3.1 EMERGENCY OVERVIEW Specific Physical Form: Viscous Odor, Color, Grade: Tan Liquid Minor Amine odor. General Physical Form: Liquid Immediate health, physical, and environmental hazards: May cause chemical eye burns. May cause chemical skin burns. May cause allergic skin reaction. May cause chemical gastrointestinal burns. May cause target organ effects. Contains a chemical or chemicals which can cause birth defects or other reproductive harm.

Potential health effects

Eye Contact: Corrosive (Eye Burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing, ulcerations, significantly impaired vision or complete loss of vision. Skin Contact: Corrosive (Skin Burns): Signs/symptoms may include localized redness, swelling, itching, intense pain, blistering, ulceration, and tissue destruction. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Corrosion: Signs/symptoms may include severe mouth, throat and abdominal pain; nausea; vomiting; and diarrhea; blood in the feces and/or vomitus may also be seen. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Methemoglobinemia: Signs/symptoms may include headache, dizziness, nausea, difficulty breathing, and generalized weakness. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Contains a chemical or chemicals which can cause cancer. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water for at least 15 minutes. Get immediate medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get immediate medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point >=110 ºC [Test Method: Closed Cup] Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available OSHA Flammability Classification: Class IIIB Combustible Liquid 5.2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: No unusual fire or explosion hazards are anticipated. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. 6.2. Environmental precautions For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. Clean-up methods Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more information on handling and managing the spill. Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Contents may be under pressure, open carefully. Avoid breathing of vapors, mists or spray. Avoid skin contact. Avoid eye contact with vapors, mists, or spray. Avoid contact with oxidizing agents.

Storage

Store away from acids. Keep container in well-ventilated area. Store away from areas where product may come into contact with food or pharmaceuticals. Store away from oxidizing agents. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Provide appropriate local exhaust ventilation on open containers. Use in an enclosed process area is recommended. Do not use in a confined area or areas with little or no air movement. For additional health and precautionary information, including air monitoring methodology, contact 3M. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Safety Glasses with side shields Indirect Vented Goggles . 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Neoprene Polymer laminate . 8.2.3 Respiratory Protection Avoid breathing of vapors, mists or spray. Avoid breathing of fumes. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece air-purifying respirator suitable for organic vapors/acid gases and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit Additional Information DIMETHYL SILOXANE, REACTION CMRG CEIL 5 mg/m3 PRODUCT WITH SILICA SILICA, AMORPHOUS OSHA TWA concentration 0.8 mg/m3 SILICA, AMORPHOUS OSHA TWA 20 millions of particles/cu. ft. TOLUENE ACGIH TWA 20 ppm TOLUENE CMRG STEL 75 ppm Skin Notation* TOLUENE OSHA TWA 200 ppm TOLUENE OSHA CEIL 300 ppm TRIS(2,4,6- CMRG TWA 5 ppm DIMETHYLAMINOMONOMETHYL)PHEN OL * Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Specific Physical Form: Viscous Odor, Color, Grade: Tan Liquid Minor Amine odor. General Physical Form: Liquid Autoignition temperature No Data Available Flash Point >=110 ºC [Test Method: Closed Cup] Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Boiling Point > 110 ºC Density 9.5 lb/gal Vapor Density No Data Available Vapor Pressure <=200 mmHg [@ 20 ºC] Specific Gravity 1.2 [Ref Std: WATER=1] pH No Data Available Melting point No Data Available Solubility In Water No Data Available Evaporation rate <=1 [Ref Std: BUOAC=1] Hazardous Air Pollutants 0.05 lb HAPS/gal [Test Method: Calculated] Volatile Organic Compounds 0.5 % weight [Test Method: calculated per CARB title 2] Volatile Organic Compounds 5 g/l [Test Method: calculated SCAQMD rule 443.1] Kow - Oct/Water partition coef No Data Available Percent volatile 0.5 % Percent volatile Negligible VOC Less H2O & Exempt Solvents 5 g/l [Test Method: calculated SCAQMD rule 443.1] Viscosity 100000 - 225000 centipoise [Test Method: Brookfield] SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: 10.1 Conditions to avoid Not determined 10.2 Materials to avoid Strong oxidizing agents Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products