I. I. Product identifier

3M

Revision date : 2014-08-14

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GHS07
Health risk rating 4
Safety risk rating 4
Environmental risk rating 5

Note: Ingredients listed on restricted chemical lists

EC/CAS

8050-15-5

Name of the chemical

Resin acids and Rosin acids, hydrogenated, methyl esters

Concentration

10 - 30

EC/CAS

25068-38-6

Name of the chemical

4,4'-Isopropylidenediphenol, oligomeric reaction products with 1-chloro-2,3-epoxypropane

Concentration

N/A

Listed in

EC/CAS

7732-18-5

Name of the chemical

Water, distilled, conductivity or of similar purity H2O

Concentration

N/A

EC/CAS

8050-09-7

Name of the chemical

Rosin

Concentration

N/A

General Information

Revision date

2014-08-14

Product name

I. I. Product identifier

1.2.1 Relevant identified uses

Passive fire protection in industrial applications

Manufacturer Name

3M

Emergency telephone

1-800-364-3577 or (65l) 737-6501 (24 hours

Icons in SDS

GHS07

Company Information

company name

3M

GHS Information

Signal word

Warning

Section 2

2.2 Label elements

Slgnnl word Warning Symhols Exclnmntion markI

Hazard pictograms

Page l of 10 ( !JMTM Cubie Prcpurntlon Kit CC-2 (Cun) 04/24/IS Hazord Stotements Combusti bleliquid. Causes skin irritation. May cause an allergic skin reaction. May cause drowsinessor dizziness. Precoutionury Statements

Prevention

Keep nwny from heal/sparks/open names/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/ mist/vapors/spray. Use only outdoorsor in a well-ventilated area. Wear protective gloves. Wash thoroughly uftcr handling. Contuminutcd work clothing must not be allowed out of the workplace.

Response

IF INHALED: Remove person to fresh air und keep comfortable for breat hing. IF ON SKIN: Wash wiU1 plenty ofsonp and water. If skin irritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. Call a POISON CENTER or doctor/physicinn if you feel unwell. In cuse of fire: Use u fire fighting ugcnt s uitablefor flummublc liquids such as dry chcmicul or carbon dioxide to extinguish. Storoge: Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up.

Disposal

Dispose of contcn1s/con1aincr in uccorduncc with 11pplicublc locul/rogionul/nulional/intcmu tional regulations. 2.3.Hazards not otherwsie classUled None. ISECTION 3: Composition/information on ingredients ! 11gredlent - C.A.S.No. %byWJ. 1S02.l!f, llffinic Hydrocarbon . 64742-48-9 --- 50- 70 - Cotton oads --- None -·25-4"6 D-LIMONENE -- 5989-27-5 5 - 20 ISECTION 4: First aid measures 4.1. Description of first aid measures Page 2 of 10 !J Cn blc Prcpnrntlon Kit cc. 2 (C un) MTM 04/24/15 Inhal ation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Im mediately wash with soap and waler. Remove contam inatedclothing nnd wosh before reuse. IJ's igns/sympto ms develo p, get medical attention. Eye Contact: No need for first aid is anticipated. If Swallowed: Rinse mouth. If you feel unwell, get medical attentio n. 4.2. Most important symptoms nod effects, both acuteand delayed See Section I I. I. ln fonnation on toxicological effects. 4.3. Indication of any Immediate medical attention and special treatment required Not opplicable ISECTION 5: Fire-fightingmeasures 5.l.Sult11blc extinguishing mcdi11 In case of fire Use o lire fighting agent suitable for ilmn mable liquids suc h os dry chemic tl or carbon dioxide to ex tinguish S.2. Special hazards arising from the substanceor mixture Closedcontainers exposed to hcut from fire muy build pressure und explode. 5.3. Special protective nctions for fire-fighters Water may not etleclively e:ittinguish fire; however, it shoul d be used lo kee p fire-exposed containersand surl'nces cool and prevent explosive rupt ure. ISECTION 6: Accidental release measures 6.1. rcrsonal prccnutions, protective equipment und emergency procedures Evncuate aren. Keep away from beat/sparks/open flames/hot surfaces. - No smoking. Use only non-s parking tools. Ventilute the ai·cu with fresh air. For large spill, or spills in co nfinedspuccs, provide mechunicul ventilation to dispe rseor exhaust vupors, in nccordance with good ind us trial hygiene practice. Warning! A motor could be an ig nitionsourceand could cousc flammable gases or vupors in the spill urea to bum or explode. Refer to other sections of this SDS for info1mat ion regarding physical and health hazards, respiratory protection, ventilatio n, and pcrsonol protec tive equipment. 6.2. Environmentulprccuutions Avoid release to the environment. 6.3. Methods and mutcrlnl for containment nnd cleaning up Contain spill. Cover spill area with a fire-extinguish ing foam. An appropriate aqueous film forming foam (AFFF) is recommended. Remem ber, adding an absorbent material docs not remove n physical, health,or environmental ha1,ard. Collect as much of the sp illed material as possible using non-spurkingtools. Pince in a metal contuincr approved for trans portation by appropria te authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read nnd followsafety precautions on the solvent lnbel and SDS. Seal the contuiner. Dispose of collecte d material as soon ns possible. ISECTION Handling and storage 7: 7.1. Precautions for safe hnndllng Pngc 3 of 10 ! J M TM C11blc Prcpurution Kit CC-2(Can) 04/24/15 For industrial or professio nal use only. Kee p away from heat/sparks/ open flames/hot surfaces.· No smoking. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on cloth ing. Do not eat, drink or smoke when using this product. Wash thoroughly aflcr handling, Contaminated work clot hing should not be allowe d out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse . Avoid contact with ox idizing agenls (eg. chlorine, chromic acid etc.) 7.2. Conditions for safe storage including nny lnconipatib llltles Store in a well-ventilated place. Keep container lightly closed. Keep cool. Protect from sunlig ht. Store away from heat. Store away from acids. Store away from oxidizing agents. ISECTION 8: Exposure controls/personal protection 8.1. Control pnrnmcters Occupational exposure limlls I f u component is disclosed in sectio n 3 but docs not appear in tlic table below, un occ upntionul exposure limit is not available tior thc component. ln11.redlent C.A.S. No. A2cncv Limit tvoe Additional Comments lsoparuflinic Hydrocarbon 64742-48-9 Manufacturer TWA: IOO ppm determined ACGIH Amcncnn Confcn ncc of Govcnnncnlul lnc.lu51rml l lyg1cnts lli AIHA : Amcria111!111.lu.triul Hygiene Associuiion CMRO : Chcmlcol Monulhc1urcr's Recommended Guidelines OSI-Ii\ : United Siotcs Dcpnnmc111ol'lnbor- Occupational Sal'cly nnd Ilculth Adminislrnlion TWA: Timc•Wcigh1cd-Avcnigc STUL Short Tenn cXJ10 Un L1111i1 CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineeringcontrols Use ge ne ral dilution ventilatio n and/or local exhaust ventilation to control airborne exposures to below releva nt Exposure Limits and/or control dust/fume /gas/mist/vapors/spray. lf vcntilotion is not adcquute, use respirotory protection equipment, 8.2.2. Personal protective equipment (PPE) Eye / face protection Under normal use condition s, eye exposure is not expected to be signifi cant enough to require eye protection. Skin/hand protection Select and use g loves and/or protective clothing approved to releva nt local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors s uch as exposure levels, concentration of the substnnce or mixture, frequency and duration, physical challenges such as te mperature extremes, and other use co nditions. Consult with your glove aml/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Glovesmade from the following mutcrial(s} arc recommended: Nitrilc Rubber Polymer laminate If this product is used in a manner that prese nts a higher potentai l for exposure (cg. sprnying, high splash potential e tc.), thon use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of' an exposure assessment. The following protective cloth ing materinl(s) a re recommended: Apron - Nilrile Apron • polymer laminate Respiratoryprotection An exposure asse smcnt may be needed to decide ifa respirator is required. lf u resp irator is needed, use respirators as part of Page 4 of 10 !JMTM Cable Prcpnrall11n Kit CC-2 (Can) 04/24/IS a full respiratory protection program. Bnscd on the results of the exposure assessment, select from the following respirator lype(s) to reduce inhalation exposure : Half focc piccc or full foccpiecc air-purifying respirator suitable for organic vapors Fo,· ques tions about suitability for a specific application, consult with your respirator manufa c turer. I SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Gcncrul Physical Form: Solid (Lint-free cloths soaked with liquid) Specific Physical Form: Cloth pads soaked in liquid in can or bag Odor, Colo r, Grade: citrus-like odor Odor threshold No Dara A11ai lab/e pH 7.0 Melting point No Dara Available Boiling Point 380 "F • 480 "F Flash Point 144 °F (Test Met/rod: Closed Cup] Evaporation rate No Dara Available Flammability (solid, gas) Not Classified Flammable Limits(LEL) No Data Available Fl11mmable Llmlts(UEL) No Dula Available Vapor Pressure < I mmHg (@ 2S "CJ Vapor Density > J [Ref Std: AIR=J] Specltlc Grnvlty 0.76 [ Re/ Std: WATER=!] Solubility In Water Nil Solubility- non-water No Duw Available Purtltion coernclent: n-octnnol/ wuter No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity I.S centipoise Volatile Orgunic Compounds Approximately 740 g/1 voe Less H20 & Exempt Solvents 760g/1 ISECTION IO: Stability and reactivity 10.1. Reuctivlty This motcriul moy be reactive with certain agents under ccrt11in conditions - sec the rcmuining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hnznrdous reactions 1-luzardous polymerization will not occur. 10.4. Cond11lons to avoid Spurks and/or flames 10.S. Incompatible materials Strong oxidi zing agents 10.6. Hazardous decomposition products Substunce Condition Carbon monoxide Not Specified Page 5 of 10 ! JMT" C11blc Prcpurulion KIi CC-2 (Cun) 04/24/15 Carbon dioxide Not Specified ISECTION 11: Toxicological information The lnformntlon below may not be consistent with the mnterlal cluss incation in Section 2 if specific ingredient classtncatlons are mandated by a competent authority. In addition , toxicological data on Ingredients muy not be reflected in the material classification and /or the signs and symptoms ofexposure, because an ingredient may be present below the threshold for labeling, 11n Ingredient may not be available for exposure, or the datn may not be relevant to the material as a whole. 11.1. Information on Toxlcologicnl effects Signs and Symptoms of Exposure Based on test data and/orinformation on the components, this mutcrh1l may produce the following health effects: Inhalation: Rcspirntory Tract irritation: Signs/symptoms may include cough, sneezing, nnsnl discharge, headache, hoarseness, and nose and throat pnin. May cause additional henlth effects (sec below). Skin Contnct: Skin Irritation: Signs/symptoms muy include localizedredness, swe lling, itching, dryness. cracking, blistering, and pain. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, nnd itching. Eye Contact: Contact with the eyes during product use is not expected to result in sig nificunt irritution. Ingestion: Physical Blockage: Signs/symptoms mny include cramping, abdominal pain, and constipation. Gnslroi.ntestlnul Irritation:Signs/symptoms may include obdominol puin, stomachupset,nnuseo, vomiting nnd diarrhea. Additional Health Effects: Single exposure m11y cause tnrget organ effects: Centrnl Nervous Sy tem (CNS) Deprc .sion Signs/symptoms may include he udache, dizz iness, drowsiness, incoordinotion, nausea, s lowed reaction time, s lurred speech, giddiness, and unco nscious ness. Toxicologlcnl Data Ira component is disc losed in section3 but does not appear in n tab le below, either no data are available for Lhat e ndpointor the data arc not sufficient for classification. Acute Toxicity Nome Route Species V11luc O vcrnll Drodoct fngcsaior, Nodaaa availab le; calc11la1cd ATE:,. 5,000 m lsopnruffinic Hydrocnrbml lnhalutlon- LC50 cs1i mm m cdm be 20 - 50 mg/I Vmi or l onunimn ic Hvdrocnrblm Demml Rabbit LOSO > 3,000 1111!.iko lsoDaraffinic Hvdrocnrbon lm!Cstio n RQI LD50 > 5 000 nw/k D-LIMON l;NE lnhu1l11ion- Mouse LCSO > 3. 14 mi;/1 Vupor (4 hours) D- LIMONENE Dcmml Rabbit LDSO> 5,000 mw'ki: D-L!MONENE lnAes aio n Rat LD50 4,400 ml!/ku Page 6 of 10 l JMTM Cubie Prcp11rnllnn Kil CC-2 (Cun) 04/24/15 ATE - ucutc toxicity estimate Skin Corrosion/Jrritntion Nuntc Spec ies V11luc lsooumffinic Hvdrocurbon Rubbit Irritant D·LIMONENE Rubbit Mild irritant ser ous E;ye DllmllJ!C/I rr tat1on Nome S peci es Volue lsu11umffinic Hvdrocurbo11 Rubbit No siiu1ificunt irritution D-LIMONENE Rnbbi1 Mild irritant Skln Sensitization Nnmt Species Value lsopammnic Hydrocnrbon Guincn Nol sensitizing pig D·LIMONENE Mouse Scnsitizinu Respiratory Scn ltizntion For the component/components, either no data are currently available or lhe data are not sufficient for classification. Germ Cell Mutaaeniclty N11mc Route V11luc lsooumllinic Hvdrocurbon In vivo Not m111ni:cnic lsopm'Uffinlc Hydro1:nrbon In Vitro Some (IOsi1ivc d,1111 exist, but the dnrn urc 1101 sufficient tor clnssilicntion D· LIMON l! NE In Vitro Not mutn11cnic D-LIMONENE In vivo Nut mutn11c11ic Carcmo cnI.c1tv N111uc Ruutc Soccios Vuluc lsopurull'inlc Hydrocurbon Donnul Mouse Some positivedntn exist. but thed01u urc not sufficient forcl.isslficution bopuruffinic Hydrocurbon lnhulotion Hum1111 Some positivedntu exist, hut theduti1 urc not nnd sunicicnl forclnssificntion nninml D-LIMONENE h111-:.1ion 1{111 So me ro itivc d11rn e xist. but the dniu arc ntn sullicicntrnrclnssil'icution Reproductive Toxicity Rcproduct ve nnd/orDeve opmentnI Effccts Nnmc Route Vnluc Sp1idc Tl'St Re! ult Exposure Duration lsopnrnffinic l.lydrocarbon lnlrnlnlion Nol toxic todevelo pment Rnt NOA.EL 2.4 during mw l or!!unogcncsi s D-LIMONENE Ingestion Not to ic to mule reproduction Rm NO/\EL ISO 103wc,cks 11111/Lrn/dav D-LIMONENE lni:c 1ion Some positive li:male rcprotluciivc dntu Rnl NO/\EL 750 prcmnting& exist, but thedutu urc not sufficient for msfkg/dny durin!! clussificution i:cstution D-LIMONENE lngcslion Some positive dcvclopmc,11111 clout c.xis1, Multiple NOAEL59 1 during but thedata urc not sufficicnr for unimul mg/kg/dny organogcnC8i clussitication so -cics s Turget Organ(s) Specific Target Organ Toxicity· single exposure Pnge 7 of JO ! JMTM Coble Prcpurution Kit CC-2 (C11n) 04 /24 /15 N11me Route '1'J1r11ct Orgnn(s) Vuluc Species Test ltcsult Exposure Duration lsopurallinic 1-lydrocorbon lnhnlu1oi11 ccn1ml ncrv ou May enuse drowsiness or llumon NOAEL Nol sys1cm depression dizziness nnd available nnimnl lsopo rnllinic Hydrocarbon lnhola1ion rcspiralOry irritulion Some poshive dntll cxisl, bul lhc NOAEL Nol durn ore1101sufficient for avniloblc clnssificution lsopanillinic Ilydr<X:urbon lnhohnion nervous sys11c11 Someposilivedutacxisl.bulthe Dos NOAE L 6.5 4 hours dutoore not sufficient for mg/I clussificution D-LIMONENE lnscs tion nervous syslcm Some posi1ivc do111 exist, bu1lhc NOAELNui dutn ore notsufficie nt for (1\/Ullnbk clussi ficution s;peeifiC T Qfl,!Ct 0 reun T ox1c1 ty - rcpeutcd exposure Numc Routll T,1r ctOrgun( , ) Vuluc Species Tc.,t Result Exposure Ourutlun lsopuroffinic Hydrucnrbon lnlrnlntion nervoussyslcm Somepositivedurnoxigt,butthe Rut LOAl:L4 .6 6 months dutn urc not sullicicnt for mg/I cht sificution lsopuroninicHydrueurbon lnlmlolion kidneyand/or Some posilivcduUi exist, but the Rat LOAEL 1.9 13 weeks bladder doto arc not sufficient for mg/I clnssificntion lsoparollinic llydrocnrbon lnlmlulion rcspirmorysylcm Some poshivc dutocxisl, but the Muhiplc NOAEL0.6 90dny dnlll arc not s ufficient for animul ml!il classlfic:ution 11cc ic hopumllinic Hydrocnrbon lnhnl111io11 bone, tee th, noils, All data arc ncg;1ti\·1: Ru1 NOAEL 5.6 12 weeks nnd/orhairI bloodI msJI liver I muscles lsoparullinic: Hydrocurbon lnlwlutlOII hcUl'l All dmu urc ncgu1ivc Multiple NOAEL 1.3 90 duys unimal mi:JI sn ccics D-LIMONENE Ingestion kidncy and/or Some posilivcdntu exist, hut the Rut LOAEL 75 103 weeks bluddcr datu ore 1101sullicicnl lbr mi;t'kg/doy clussific:ulion D-LIMONENE Ingestion liver Some: positive du1t1exist, but the Mouse NOAEL 103 weeks dntu nrc not sullicicnl for 1,000 cl11ssi f1cmio11 1 11/lu i/dnv D-LIMONENE lngcs1ion hcort I cn t.locrinc Alld111n nrc negative Rnt NOAEL600 103 weeks sys tem I bllm:. teeth. mg/kg/dny nails, unc.Vor huirI hcmutopoiclic syslcm I immune system I musclesI nervoussystem I rcsoimtorv svslcm As lratlon Hazard Vnlue As inuion hu1.urd As irnlion lmznrd Please contact the address or phone number listed on the first page of the SDS for additional toxkologlcnl information on this materialand/or its components. ISECTION

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