Cream Hardener (Red, White & Blue)

SECTION 2: Hazards identification

29 CFR 1910.1200) 3.1 EMERGENCY OVERVIEW Specific Physical Form: Viscous Odor, Color, Grade: Red paste with slight ester odor General Physical Form: Solid Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and explode. Dust clouds of this material in combination with an ignition source may be explosive. May cause severe eye irritation. May cause allergic skin reaction.

Potential health effects

Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Prolonged or repeated exposure may cause: Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and changes in lung function tests. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Prolonged or repeated exposure may cause: Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and jaundice. Kidney/Bladder Effects: Signs/symptoms may include changes in urine production, abdominal or lower back pain, increased protein in urine, increased blood urea nitrogen (BUN), blood in urine, and painful urination. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point 111 ºC [Test Method: Estimated] Flammable Limits(LEL) Not Applicable Flammable Limits(UEL) Not Applicable 5.2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: Closed containers exposed to heat from fire may build pressure and explode. Dust clouds of this material in combination with an ignition source may be explosive. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. 6.2. Environmental precautions For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Place in a metal container approved for use in transportation by appropriate authorities. The container must be lined with polyethylene plastic or contain a plastic drum liner made of polyethylene. Dispose of collected material as soon as possible. Clean-up methods Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Contain spill. Cover spill area with a fire-extinguishing foam. An aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Seal the container. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Avoid static discharge. Avoid eye contact with vapors, mists, or spray. Keep out of the reach of children. Avoid breathing of dust created by cutting, sanding, grinding or machining. Avoid eye contact with dust or airborne particles.

Storage

Store away from heat. Store out of direct sunlight. Keep container tightly closed. Do not heat under confinement to avoid risk of explosion SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Provide appropriate local exhaust for cutting, grinding, sanding or machining. Do not use in a confined area or areas with little or no air movement. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control dust, fume, or airborne particles. If ventilation is not adequate, use respiratory protection equipment. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Safety Glasses with side shields Indirect Vented Goggles . 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Polymer laminate . 8.2.3 Respiratory Protection Avoid breathing of vapors, mists or spray. Avoid breathing of dust created by cutting, sanding, grinding or machining. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit

Additional information

BENZOYL PEROXIDE ACGIH TWA 5 mg/m3 BENZOYL PEROXIDE OSHA TWA 5 mg/m3 CALCIUM SULFATE ACGIH TWA, inhalable 10 mg/m3 fraction CALCIUM SULFATE OSHA TWA, respirable 5 mg/m3 fraction CALCIUM SULFATE OSHA TWA, as total dust 15 mg/m3 CYANIDES OSHA TWA, as CN 5 mg/m3 Skin Notation* IRON OXIDE (FE2O3) ACGIH TWA, respirable 5 mg/m3 fraction IRON OXIDE (FE2O3) OSHA TWA, as fume 10 mg/m3 ZINC STEARATE OSHA TWA, respirable 5 mg/m3 fraction ZINC STEARATE OSHA TWA, as total dust 15 mg/m3 SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Specific Physical Form: Viscous Odor, Color, Grade: Red paste with slight ester odor General Physical Form: Solid Autoignition temperature No Data Available Flash Point 111 ºC [Test Method: Estimated] Flammable Limits(LEL) Not Applicable Flammable Limits(UEL) Not Applicable Boiling Point No Data Available Density 1.2 g/cm3 Vapor Density Not Applicable Vapor Pressure Not Applicable Specific Gravity 1.2 [@ 25 ºC] [Ref Std: WATER=1] pH No Data Available Melting point No Data Available Solubility in Water Negligible Evaporation rate No Data Available Hazardous Air Pollutants 0 % weight [Test Method: Calculated] Volatile Organic Compounds 0 lb/gal [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 0 g/l [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 0 % weight [Test Method: calculated per CARB title 2] Kow - Oct/Water partition coef No Data Available Percent volatile 20 % [Details: Water is the volatile component] VOC Less H2O & Exempt Solvents 0 g/l [Test Method: calculated SCAQMD rule 443.1] Viscosity No Data Available SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Stable unless exposed to heat, flames and drying conditions. Materials and Conditions to Avoid: 10.1 Conditions to avoid Heat 10.2 Materials to avoid Accelerators Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide Not Specified Carbon dioxide Not Specified Toxic Vapor, Gas, Particulate Not Specified

TOXICOLOGICAL INFORMATION

Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility. This product has been classified on the basis that it is stable as sold. Material may become unstable if allowed to dry out. Classify appropriately before disposal. EPA Hazardous Waste Number (RCRA): D001 (Ignitable) Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number(s): LB-K100-0965-7, LB-K100-0965-8, LB-K100-0965-9, LB-K100-0966-0, LB-K100-0966-1, LB-K100-0966-2, LB-K100-0966-3, LB-K100-1035-6, LB-K100-1045-4, LB-K100-1286-7, 41-0003-7987-9, 60-4550-6614-6, 60-4550-6617-9, 60-4550-6830-8, 60- 4550-6981-9, 60-4550-6982-7 For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - Yes Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt ZINC STEARATE (ZINC COMPOUNDS) 557-05-1 3 - 7 BENZOYL PEROXIDE 94-36-0 30 - 60 FERRIC FERROCYANIDE (CYANIDES) 14038-43-8 0 - 1 STATE REGULATIONS Contact 3M for more information. CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information. WHMIS: Hazardous This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

Further information

NFPA Hazard Classification Health 2 Flammability 1 Reactivity 1 Special Oxidizer National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

HMIS® ratings

Health 2 Flammability 1 Reactivity 1 Protection X - See PPE section Hazardous Material Identification System (HMIS®) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint and Coatings Association (NPCA). Revision Changes: Section 14: ID Number(s) Template 1 was modified. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 3M™ Contractor Grade All-Purpose Filler PN 31133 MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours) Issue date 05/31/12 Supercedes Date: 03/01/12 Document Group: 29-6688-5 Product Use: Specific Use: Designed for Concrete, Metal, Plaster, Sheet Rock, Stucco, Wood & Brick Repairs Intended Use: Industrial use SECTION 2: INGREDIENTS Ingredient C.A.S. No. % by Wt 1,3-ISOBENZOFURANDIONE, POLYMER WITH 2,5-FURANDIONE AND 26123-45-5 30 - 60 2,2'-OXYBIS[ETHANOL] TALC 14807-96-6 10 - 30 STYRENE MONOMER 100-42-5 10 - 30 MAGNESIUM CARBONATE 546-93-0 10 - 30 CHLORITE (MINERAL) 1318-59-8 1 - 5 FIBERGLASS Mixture 1 - 5 FIBER None 0.5 - 1.5 OXIDE GLASS CHEMICALS 65997-17-3 0.1 - 1.0 SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW Specific Physical Form: Paste Odor, Color, Grade: Pungent Styrene odor Green paste General Physical Form: Liquid MATERIAL SAFETY DATA SHEET 3M™ Contractor Grade All-Purpose Filler PN 31133 05/31/12 Immediate health, physical, and environmental hazards: Flammable liquid and vapor. Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Contains a chemical or chemicals which can cause cancer. May cause target organ effects. 3.2 POTENTIAL HEALTH EFFECTS Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin Contact: Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Inhalation: May be harmful if inhaled. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Prolonged or repeated exposure may cause: Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and changes in lung function tests. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and jaundice. Prolonged or repeated exposure may cause: Immunological Effects: Signs/symptoms may include alterations in the number of circulating immune cells, allergic skin and /or respiratory reaction, and changes in immune function. Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Ocular Effects: Signs/symptoms may include blurred or significantly impaired vision. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient C.A.S. No. Class Description Regulation STYRENE MONOMER 100-42-5 Grp. 2B: Possible human carc. International Agency for Research on Cancer STYRENE MONOMER 100-42-5 Anticipated human carcinogen National Toxicology Program Carcinogens