3MMarine Vinyl Cleaner, Conditioner and Protector, 09023

SECTION 2: Hazards identification

OSHA 3.1 EMERGENCY OVERVIEW Specific Physical Form: Viscous Odor, Color, Grade: Off-white viscous liquid with a slight odor General Physical Form: Liquid Immediate health, physical, and environmental hazards: May cause allergic skin reaction. May cause target organ effects. Contains a chemical or chemicals which can cause birth defects or other reproductive harm.

Potential health effects

Eye Contact: Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing. Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Prolonged or repeated exposure may cause: Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and jaundice. Kidney/Bladder Effects: Signs/symptoms may include changes in urine production, abdominal or lower back pain, increased protein in urine, increased blood urea nitrogen (BUN), blood in urine, and painful urination. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: If signs/symptoms develop, remove person to fresh air. If signs/symptoms persist, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point No flash point Flammable Limits(LEL) Not Applicable Flammable Limits(UEL) Not Applicable OSHA Flammability Classification: Not Applicable 5.2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: No unusual fire or explosion hazards are anticipated. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. 6.2. Environmental precautions For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Place in a metal container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. Clean-up methods Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill. Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Clean up residue with water. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Avoid eye contact. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Avoid breathing of vapors, mists or spray. Avoid prolonged or repeated skin contact. Keep out of the reach of children. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits. If ventilation is not adequate, use respiratory protection equipment. Do not ingest.

Storage

Keep from freezing. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use with appropriate local exhaust ventilation. Use in an enclosed process area is recommended. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact. The following eye protection(s) are recommended: Safety Glasses with side shields Indirect Vented Goggles . 8.2.2 Skin Protection Avoid prolonged or repeated skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Nitrile Rubber Polyvinyl Chloride . 8.2.3 Respiratory Protection Consult the current 3M Respirator Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance. During application: Avoid breathing of vapors, mists or spray. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece supplied-air respirator For questions about suitability for a specific application, consult with your respirator manufacturer. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit Additional Information 1-METHOXY-2-PROPANOL ACGIH TWA 50 ppm 1-METHOXY-2-PROPANOL ACGIH STEL 100 ppm OCTAMETHYLCYCLOTETRASILOXANE CMRG TWA 10 ppm TRIETHANOLAMINE ACGIH TWA 5 mg/m3 SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Specific Physical Form: Viscous Odor, Color, Grade: Off-white viscous liquid with a slight odor General Physical Form: Liquid Autoignition temperature No Data Available Flash Point No flash point Flammable Limits(LEL) Not Applicable Flammable Limits(UEL) Not Applicable Boiling Point 212 ºF Density 1 g/ml Vapor Density No Data Available Vapor Pressure No Data Available Specific Gravity Approximately 1 [Ref Std: WATER=1] pH 7.5 - 8.5 Melting point No Data Available Solubility in Water Complete Evaporation rate No Data Available Hazardous Air Pollutants 0.003 % weight [Test Method: Calculated] Volatile Organic Compounds 3.6 % weight [Test Method: calculated per CARB title 2] Volatile Organic Compounds 36 g/l [Test Method: calculated SCAQMD rule 443.1] Kow - Oct/Water partition coef Not Applicable Percent volatile 84.2 VOC Less H2O & Exempt Solvents 185 g/l [Test Method: calculated SCAQMD rule 443.1] Viscosity >=40,000 centipoise [Test Method: Brookfield] SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: 10.1 Conditions to avoid None known 10.2 Materials to avoid None known Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products