3M Valux Plus Restorative (5540)

Hazard statements (CLP)

H317, H360

Code

Statements

H317

May cause an allergic skin reaction

SECTION 2: Hazards identification

Hazard pictograms

Exclamation mark | Health Hazard |

Hazard statements

May cause an allergic skin reaction. May damage fertility or the unborn child.

Prevention

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid breathing dust/fume/gas/mist/vapors/spray. Wear protective gloves. Contaminated work clothing must not be allowed out of the workplace.

Response

IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. IF exposed or concerned: Get medical advice/attention.

Disposal

Dispose of contents/container in accordance with applicable local/regional/national/international regulations.

2.1 Classification of the substance or mixture

Skin Sensitizer: Category 1. Reproductive Toxicity: Category 1B. 2.2. Label elements Signal word Danger Symbols Exclamation mark | Health Hazard | Pictograms Hazard Statements May cause an allergic skin reaction. May damage fertility or the unborn child. Precautionary Statements Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid breathing dust/fume/gas/mist/vapors/spray. Wear protective gloves. Contaminated work clothing must not be allowed out of the workplace. Response: IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. IF exposed or concerned: Get medical advice/attention. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Silane Treated Ceramic 444758-98-9 80 - 90 Trade Secret * Bisphenol A Diglycidyl Ether Dimethacrylate 1565-94-2 5 - 10 Trade Secret * (BISGMA) Triethylene Glycol Dimethacrylate (TEGDMA) 109-16-0 < 10 Trade Secret * 2-Benzotriazolyl-4-Methylphenol 2440-22-4 < 0.3 Trade Secret * N,N-DIMETHYLBENZOCAINE 10287-53-3 < 0.3 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed Allergic skin reaction (redness, swelling, blistering, and itching). 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion 5.3. Special protective actions for fire-fighters Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue. Seal the container. Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations. SECTION 7: Handling and storage 7.1. Precautions for safe handling A no-touch technique is recommended. If skin contact occurs, wash skin with soap and water. Acrylates may penetrate commonly-used gloves. If product contacts glove, remove and discard glove, wash hands immediately with soap and water and then re-glove. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapors/spray. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Do not get in eyes. Use personal protective equipment (gloves, respirators, etc.) as required. 7.2. Conditions for safe storage including any incompatibilities