3M Ultrapro MSP Sprayable Seam Sealer (Gray) PN 08374

SECTION 2: Hazards identification

29 CFR 1910.1200) 3.1 EMERGENCY OVERVIEW Specific Physical Form: Paste Odor, Color, Grade: Grey, creamy paste General Physical Form: Liquid Immediate health, physical, and environmental hazards: Combustible liquid and vapor. Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. May cause allergic skin reaction. May cause target organ effects. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Contains a chemical or chemicals which can cause cancer.

Potential health effects

Eye Contact: Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing. Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. May be absorbed through skin and cause target organ effects. Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Prolonged or repeated exposure may cause: Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate, bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Prolonged or repeated exposure may cause: Bone Marrow Effects: Signs/symptoms may include generalized weakness, pallor of the skin, fatty infiltration of the bone marrow, decreases in the numbers of circulating blood cells, increased susceptibility to infection. Immunological Effects: Signs/symptoms may include alterations in the number of circulating immune cells, allergic skin and /or respiratory reaction, and changes in immune function. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient C.A.S. No. Class Description Regulation QUARTZ SILICA 14808-60-7 Grp. 1: Carcinogenic to International Agency for Research on Cancer humans SILICA, CRYSTALLINE (AIRBORNE SEQ677 Grp. 1: Carcinogenic to International Agency for Research on Cancer PARTICLES OF RESPIRABLE SIZE) humans SILICA, CRYSTALLINE (AIRBORNE SEQ677 Known human carcinogen National Toxicology Program Carcinogens PARTICLES OF RESPIRABLE SIZE) SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point 144 ºF [Test Method: Pensky-Martens Closed Cup] Details SPECIFIC METHOD ASTM D93] Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available 5.2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). Foam, carbon dioxide, dry chemical. 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Water may be used to blanket the fire. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: Combustible liquid and vapor. Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. 6.2. Environmental precautions For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. Clean-up methods Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more information on handling and managing the spill. Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Do not spray near flames or sources of ignition. Avoid breathing of vapors, mists or spray. Avoid eye contact with vapors, mists, or spray. For industrial or professional use only. Avoid contact with oxidizing agents. Keep out of the reach of children. Avoid skin contact. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits. If ventilation is not adequate, use respiratory protection equipment.

Storage

Store away from acids. Store away from heat. Store out of direct sunlight. Keep container tightly closed. Store away from areas where product may come into contact with food or pharmaceuticals. Store away from oxidizing agents. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use with appropriate local exhaust ventilation. Use in an enclosed process area is recommended. Use with functioning spray booth or local exhaust. If exhaust ventilation is not available, use appropriate respiratory protection. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Safety Glasses with side shields Indirect Vented Goggles . 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Butyl Rubber Neoprene . 8.2.3 Respiratory Protection Avoid breathing of vapors, mists or spray. Consult the current 3M Respirator Selection Guide for additional information or call 1- 800-243-4630 for 3M technical assistance. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit

Additional information

N-ME 2-PYRROLIDONE AIHA TWA 40 mg/m3 Skin Notation* CALCIUM CARBONATE CMRG TWA 10 mg/m3 CALCIUM CARBONATE CMRG STEL 20 mg/m3 DIBUTYL PHTHALATE ACGIH TWA 5 mg/m3 DIBUTYL PHTHALATE OSHA TWA 5 mg/m3 HYDROTREATED HEAVY NAPHTHA Manufacturer TWA 100 ppm (PETROLEUM) determined LIMESTONE OSHA TWA, respirable 5 mg/m3 fraction LIMESTONE OSHA TWA, as total dust 15 mg/m3 METHYL ALCOHOL ACGIH TWA 200 ppm Skin Notation* METHYL ALCOHOL ACGIH STEL 250 ppm Skin Notation* METHYL ALCOHOL OSHA TWA 260 mg/m3 QUARTZ SILICA ACGIH TWA, respirable 0.025 mg/m3 fraction QUARTZ SILICA OSHA TWA concentration, 0.1 mg/m3 respirable QUARTZ SILICA OSHA TWA concentration, 0.3 mg/m3 as total dust STEARATES ACGIH TWA 10 mg/m3 * Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Specific Physical Form: Paste Odor, Color, Grade: Grey, creamy paste General Physical Form: Liquid Autoignition temperature No Data Available Flash Point 144 ºF [Test Method: Pensky-Martens Closed Cup] [Details: SPECIFIC METHOD: ASTM D93] Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Boiling Point Not Applicable Density 1.4 - 1.6 g/cm3 Vapor Density Not Applicable Vapor Pressure Not Applicable Specific Gravity 1.4 - 1.6 [Ref Std: WATER=1] pH Not Applicable Melting point Not Applicable Solubility in Water Negligible Evaporation rate Nil Hazardous Air Pollutants 3.6285 % weight [Test Method: Calculated] Volatile Organic Compounds 0.56 lb/gal [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 4.4 % weight [Test Method: calculated per CARB title 2] Volatile Organic Compounds 66 g/l [Test Method: calculated SCAQMD rule 443.1] Kow - Oct/Water partition coef No Data Available Percent volatile 4.4 % VOC Less H2O & Exempt Solvents 66 g/l [Test Method: calculated SCAQMD rule 443.1] Viscosity 300000 - 600000 poise [Test Method: Brookfield] [Details: CONDITIONS: Spindle #7, 2 rpm] SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: 10.1 Conditions to avoid Heat Sparks and/or flames 10.2 Materials to avoid Strong acids Strong oxidizing agents Strong bases Open flame, heat Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide Not Specified Carbon dioxide Not Specified Hazardous Decomposition: Carbon monoxide, carbon dioxide, oxides of nitrogen.

TOXICOLOGICAL INFORMATION

Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Incinerate in an industrial or commercial facility. As a disposal alternative, dispose of waste product in a facility permitted to accept chemical waste. EPA Hazardous Waste Number (RCRA): Not regulated Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number(s): 60-9800-2115-2, 60-9800-2116-0, 60-9800-3128-4 For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt DIBUTYL PHTHALATE 84-74-2 1 - 5 N-ME 2-PYRROLIDONE 872-50-4 0.5 - 1.5 STATE REGULATIONS Contact 3M for more information. CALIFORNIA PROPOSITION 65 Ingredient C.A.S. No.

2.1 Classification of the substance or mixture

SILICA, CRYSTALLINE (AIRBORNE None **Carcinogen PARTICLES OF RESPIRABLE SIZE) DIBUTYL PHTHALATE 84-74-2 *Female reproductive toxin DIBUTYL PHTHALATE 84-74-2 *Male reproductive toxin DIBUTYL PHTHALATE 84-74-2 *Developmental Toxin METHYL ALCOHOL 67-56-1 *Developmental Toxin N-ME 2-PYRROLIDONE 872-50-4 *Developmental Toxin * WARNING: contains a chemical or chemicals which can cause birth defects or other reproductive harm. ** WARNING: contains a chemical which can cause cancer. CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information. This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

Further information

NFPA Hazard Classification Health 2 Flammability 2 Reactivity 0 Special None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Revision Changes: Section 1: Product name was modified. Section 1: Product use information was modified. Section 16: Disclaimer (second paragraph) was modified. Section 3: Potential effects from eye contact was modified. Section 3: Potential effects from inhalation information was modified. Section 7: Handling information was modified. Section 7: Storage information was modified. Section 8: Engineering controls information was modified. Section 8: Respiratory protection information was modified. Section 8: Prevention of swallowing information was modified. Section 10: Hazardous decomposition or by-products table was modified. Section 13: Waste disposal method information was modified. Section 8: Eye/face protection information was modified. Section 8: Skin protection - recommended gloves information was modified. Section 8: Respiratory protection - recommended respirators information was modified. Section 8: Respiratory protection - recommended respirators was modified. Section 3: Immediate other hazard(s) was modified. Section 14: Transportation legal text was modified. Section 3: Other health effects information was modified. Page Heading: Product name was modified. Section 15: Inventories information was modified. Section 9: Density information was modified. Section 9: Vapor density value was modified. Section 9: Vapor pressure value was modified. Section 9: Boiling point information was modified. Section 5: Flammable limits (UE) information was modified. Section 5: Flammable limits (LEL) information was modified. Section 5: Autoignition temperature information was modified. Section 5: Flash point information was modified. Section 9: Property description for optional properties was modified. Section 9: Specific gravity information was modified. Section 9: pH information was modified. Section 9: Melting point information was modified. Section 9: Solubility in water text was modified. Section 8: Respiratory protection - recommended respirators guide was modified. Section 9: Flash point information was modified. Section 9: Flammable limits (LEL) information was modified. Section 9: Flammable limits (UEL) information was modified. Section 9: Autoignition temperature information was modified. Section 2: Ingredient table was modified. Section 15: EPCRA 313 information was modified. Section 8: Exposure guidelines ingredient information was modified. Section 15: California proposition 65 ingredient information was modified. Section 3: Carcinogenicity phrase was added. Section 3: Carcinogenicity table was added. Section 3: Carcinogenicity heading was added. Section 15: California proposition 65 cancer warning was added. Section 6: 6.2. Environmental precautions heading was added. Section 6: 6.1. Personal precautions, protective equipment and emergency procedures heading was added. Section 10.1 Conditions to avoid heading was added. Section 10.2 Materials to avoid heading was added. Section 16: Web address was added. Section 6: Personal precautions information was added. Section 6: Environmental procedures information was added. Section 6: Methods for cleaning up information was added. Section 10: Materials to avoid physical property was added. Section 10: Conditions to avoid physical property was added. Section 1: Address was added. Copyright was added. Company logo was added. Section 6: Clean-up methods heading was added. Telephone header was added. Company Telephone was added. Section 1: Emergency phone information was added. Section 1: Emergency phone information was deleted. Section 5: Unusual fire and explosion hazard comment was deleted. Company Logo was deleted. Copyright was deleted. Section 16: Web address heading was deleted. Section 6: Release measures information was deleted. Section 6: Release measures heading was deleted. Section 10: Materials and conditions to avoid physical property was deleted. Section 1: Address line 1 was deleted. Section 1: Address line 2 was deleted.