3M(TM) Paint Buster(TM) Hand Cleaner, P.N. 05975

SECTION 2: Hazards identification

3.1 EMERGENCY OVERVIEW Specific Physical Form: Paste Odor, Color, Grade: sweet odor, light tan paste General Physical Form: Liquid Paste Immediate health, physical, and environmental hazards: May cause allergic skin reaction.

Potential health effects

Eye Contact: Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing. Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point 201 ºF [Test Method: Closed Cup] Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available 5.2 EXTINGUISHING MEDIA Ordinary combustible material. Use fire extinguishers with class A extinguishing agents (e.g., water, foam). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: No unusual fire or explosion hazards are anticipated. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. 6.2. Environmental precautions Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. Clean-up methods Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more information on handling and managing the spill. Collect as much of the spilled material as possible. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Avoid breathing of vapors, mists or spray. Keep out of the reach of children. Avoid contact with oxidizing agents. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits. If ventilation is not adequate, use respiratory protection equipment.

Storage

Store away from oxidizing agents. Keep from freezing. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact. The following eye protection(s) are recommended: Safety Glasses with side shields . 8.2.2 Skin Protection Avoid prolonged or repeated skin contact. 8.2.3 Respiratory Protection Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. Avoid breathing of vapors, mists or spray. Consult the current 3M Respirator Selection Guide for additional information or call 1-800-243- 4630 for 3M technical assistance. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit Additional Information CELLULOSE ACGIH TWA 10 mg/m3 CELLULOSE OSHA TWA, respirable 5 mg/m3 fraction CELLULOSE OSHA TWA, as total dust 15 mg/m3 D-LIMONENE AIHA TWA 165.5 mg/m3 DIMETHYL ADIPATE CMRG TWA, as Dimethyl 1.5 ppm Esters DIMETHYL GLUTARATE CMRG TWA, as Dimethyl 1.5 ppm Esters POLYETHYLENE GLYCOL AIHA TWA, as particulate 10 mg/m3 TALC ACGIH TWA, respirable 2 mg/m3 fraction TALC CMRG TWA, as respirable 0.5 mg/m3 dust TALC OSHA TWA concentration, 0.1 mg/m3 respirable TALC OSHA TWA concentration, 0.3 mg/m3 as total dust TALC OSHA TWA 20 millions of particles/cu. ft. TRIETHANOLAMINE ACGIH TWA 5 mg/m3 SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Specific Physical Form: Paste Odor, Color, Grade: sweet odor, light tan paste General Physical Form: Liquid Paste Autoignition temperature No Data Available Flash Point 201 ºF [Test Method: Closed Cup] Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Boiling Point >=215 ºF Density 9.25 - 9.75 lb/gal Vapor Density No Data Available Vapor Pressure mmHg [Test Method Estimated] [Details CONDITIONS @ 20 C] Specific Gravity 9.25 - 9.75 lb/gal [Ref Std: WATER=1] pH 8.1 - 8.7 Melting point No Data Available Solubility in Water Slight (less than 10%) Evaporation rate No Data Available Hazardous Air Pollutants 0.013067 % weight [Test Method: Calculated] Volatile Organic Compounds 1.0 % weight [Test Method: calculated per CARB title 2] Kow - Oct/Water partition coef No Data Available Percent volatile 1.10 % [Details: (excluding exempt compounds)] VOC Less H2O & Exempt Solvents 686 g/l [Test Method: calculated SCAQMD rule 443.1] Viscosity >= 40000 centipoise SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: 10.1 Conditions to avoid None known 10.2 Materials to avoid Strong oxidizing agents Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products