3M(TM) Foam Fast 74 Classic Spray Adhesive

SECTION 2: Hazards identification

29 CFR 1910.1200) 3.1 EMERGENCY OVERVIEW Odor, Color, Grade: orange, sweet/fruity odor. General Physical Form: Gas Aerosol Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and explode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Aerosol container contains flammable material under pressure. May cause allergic skin reaction. May cause target organ effects.

Potential health effects

Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Intentional concentration and inhalation may be harmful or fatal. Single exposure, above recommended guidelines, may cause: Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be fatal. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. Get immediate medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. 4.2 NOTE TO PHYSICIANS Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point -50.00 ºF [Test Method: Tagliabue Closed Cup] [Details: CONDITIONS: (Propellant)] Flammable Limits(LEL) 1.00 % volume 5.2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: Closed containers exposed to heat from fire may build pressure and explode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Aerosol container contains flammable material under pressure. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. 6.2. Environmental precautions For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Collect the resulting residue containing solution. Place in a metal container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. Clean-up methods Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill. Contain spill. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Seal the container. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. No smoking while handling this material. Avoid eye contact with vapors, mists, or spray. Avoid contact with oxidizing agents.

Storage

Store away from acids. Store away from heat. Store out of direct sunlight. Store away from oxidizing agents. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use with appropriate local exhaust ventilation. Use in an enclosed process area is recommended. Do not use in a confined area or areas with little or no air movement. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. Do not use in a confined area or areas with little or no air movement. If exhaust ventilation is not adequate, use appropriate respiratory protection. Provide ventilation adequate to control vapor concentrations below recommended exposure limits and/or control spray or mist. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Safety Glasses with side shields . 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Nitrile Rubber Polyvinyl Alcohol (PVA) . 8.2.3 Respiratory Protection Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges . Select and use respiratory protection to prevent an inhalation exposure based on the results of an exposure assessment. Consult with your respirator manufacturer for selection of appropriate types of respirators. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Not applicable. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit

Additional information

Acetone ACGIH TWA 500 ppm Acetone ACGIH STEL 750 ppm Acetone OSHA TWA 2400 mg/m3 Dimethyl ether AIHA TWA 1880 mg/m3 Dimethyl ether CMRG TWA 1000 ppm Napththol spirits Manufacturer TWA 100 ppm determined Isopentane ACGIH TWA 600 ppm Pentane ACGIH TWA 600 ppm Pentane OSHA TWA 2950 mg/m3 SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Odor, Color, Grade: orange, sweet/fruity odor. General Physical Form: Gas Aerosol Autoignition temperature No Data Available Flash Point -50.00 ºF [Test Method: Tagliabue Closed Cup] [Details: CONDITIONS: (Propellant)] Flammable Limits(LEL) 1.00 % volume Boiling Point Not Applicable Density 0.725 g/ml Vapor Density >=2.00 [Ref Std: AIR=1] Specific Gravity 0.725 [Ref Std: WATER=1] pH No Data Available Melting point No Data Available Solubility in Water Nil Evaporation rate 2.00 [Ref Std: ETHER=1] Hazardous Air Pollutants 0 % weight [Test Method: Calculated] Volatile Organic Compounds Approximately 66 % weight [Test Method: calculated per CARB title 2] Kow - Oct/Water partition coef No Data Available Percent volatile Approximately 78 % weight VOC Less H2O & Exempt Solvents Approximately 563 g/l [Test Method: calculated SCAQMD rule 443.1] Viscosity Not Applicable SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: 10.1 Conditions to avoid Heat 10.2 Materials to avoid Strong oxidizing agents Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Condition Aldehydes During Combustion Hydrocarbons During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion Ketones During Combustion ++ synthetic polymers, resins, filler, antioxidant, rosin and u.v. absorber. Not hazardous according to Canadian WHMIS criteria. Non-WHMIS controlling. INTERNATIONAL REGULATIONS Contact 3M for more information. This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

TOXICOLOGICAL INFORMATION

Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility. Facility must be capable of handling aerosol cans. Dispose of empty product containers in a sanitary landfill. EPA Hazardous Waste Number (RCRA): D001 (Ignitable) Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number UPC ID Number UPC 62-4991-0930-4 00-21200-31320-2 62-4991-0931-2 62-4991-4921-9 62-4991-4930-0 00-21200-65055-0 62-4991-4935-9 00-00000-00000-0 62-4991-4936-7 00-21200-82242-1 62-4991-4950-8 62-4991-4955-7 CS-0406-2031-5 CS-0406-6932-0 For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No This material contains a chemical which requires export notification under TSCA Section 12[b]: Ingredient (Category if applicable) C.A.S. No Regulation Status Pentane (Pentane) 109-66-0 Toxic Substances Control Act (TSCA) 4 Test Applicable Rule Chemicals Pentane 109-66-0 Toxic Substances Control Act (TSCA) 4 Test Applicable Rule Chemicals STATE REGULATIONS Contact 3M for more information. CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. Contact 3M for more information.

Further information

NFPA Hazard Classification Health 2 Flammability 4 Reactivity 1 Special None Aerosol Storage Code: 3 National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Revision Changes: Section 1: Product name was modified. Section 1: Product use information was modified. Section 16: Disclaimer (second paragraph) was modified. Section 3: Potential effects from skin contact information was modified. Section 3: Potential effects from inhalation information was modified. Section 10: Hazardous decomposition or by-products table was modified. Section 4: First aid for skin contact - decontamination - was modified. Section 4: First aid for skin contact - medical assistance - was modified. Section 4: First aid for inhalation - medical assistance - was modified. Page Heading: Product name was modified. Section 9: Density information was modified. Section 9: Vapor density value was modified. Section 9: Boiling point information was modified. Section 5: Flammable limits (LEL) information was modified. Section 5: Autoignition temperature information was modified. Section 5: Flash point information was modified. Section 9: Property description for optional properties was modified. Section 9: Specific gravity information was modified. Section 9: pH information was modified. Section 9: Melting point information was modified. Section 9: Solubility in water text was modified. Section 1: Initial issue message was modified. Section 8: Respiratory protection - recommended respirators guide was modified. Section 9: Flash point information was modified. Section 9: Flammable limits (LEL) information was modified. Section 9: Autoignition temperature information was modified. Section 14: ID Number(s) and/or UPC(s) Template 1 was modified. Section 2: Ingredient table was modified. Section 8: Exposure guidelines ingredient information was modified. Section 15: TSCA section 12[b] information was modified. Section 4: Note to physicians heading was added. Section 3: Immediate skin hazard(s) was added. Section 4: First aid for skin contact - termination of exposure - was added. Section 4: First aid for skin contact - handling - was added. Section 4: Note to physicians was added. Section 16: Web address was added. Section 1: Address was added. Copyright was added. Company logo was added. Telephone header was added. Company Telephone was added. Section 1: Emergency phone information was added. Section 1: Emergency phone information was deleted. Company Logo was deleted. Copyright was deleted. Section 16: Web address heading was deleted. Section 1: Address line 1 was deleted. Section 1: Address line 2 was deleted. Section 3: Carcinogenicity table was deleted. Section 3: Carcinogenicity heading was deleted. Section 15: California proposition 65 ingredient information was deleted. Section 15: California proposition 65 heading was deleted. Section 15: California proposition 65 cancer warning was deleted. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may