3M Super Fast Repair Adhesive PN 04248, 04748 (Accelerator) Part A

Hazard statements (CLP)

H315, H317, H319, H334, H335, H351, H373

Code

Statements

H315

Causes skin irritation

2.1 Classification of the substance or mixture

CLP REGULATION (EC) No 1272/2008 Serious Eye Damage/Eye Irritation, Category 2 - Eye Irrit. 2; H319 Skin Corrosion/Irritation, Category 2 - Skin Irrit. 2; H315 Respiratory Sensitization, Category 1 - Resp. Sens. 1; H334 Skin Sensitization, Category 1 - Skin Sens. 1; H317 Carcinogenicity, Category 2 - Carc. 2; H351 Specific Target Organ Toxicity-Single Exposure, Category 3 - STOT SE 3; H335 Specific Target Organ Toxicity-Repeated Exposure, Category 2 - STOT RE 2; H373 For full text of H phrases, see Section 16.

2.2 Label elements

CLP REGULATION (EC) No 1272/2008

Hazard pictograms

GHS07 (Exclamation mark) | GHS08 (Health Hazard) | Ingredients: Ingredient CAS Nbr EC No. % by Wt 4,4’-Methylenediphenyl diisocyanate, oligomers 500-040-3 45 - 70

Hazard statements

H319 Causes serious eye irritation. H315 Causes skin irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure: respiratory system |

Prevention

P260G Do not breathe vapours or dust. P280E Wear protective gloves. P260G Do not breathe vapours or dust. P280E Wear protective gloves.

Response

P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTRE or doctor/physician. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. For containers not exceeding 125 ml the following Hazard and Precautionary statements may be used: <=125 ml Hazard statements H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. H351 Suspected of causing cancer. <=125 ml Precautionary statements P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTRE or doctor/physician. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. 36% of the mixture consists of components of unknown acute oral toxicity. 36% of the mixture consists of components of unknown acute inhalation toxicity.

Contains

36% of components with unknown hazards to the aquatic environment Notes on labelling Isocyanates are not available for inhalation exposure.

2.3 Other hazards

Persons previously sensitised to isocyanates may develop a cross-sensitisation reaction to other isocyanates.