Note: Ingredients listed on restricted chemical lists
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
N/A
EC/CAS
5873-54-1
Name of the chemical
2,4’-Methylenediphenyl diisocyanate
Concentration
N/A
General Information
Revision date
2014-04-11
Product name
3M Scotchkote Urethane Elastomer Primer 075
Emergency telephone
+44 (0)1344 858 000
Icons in SDS
Company Information
company name
3m company
e-mail address of the competent person responsible for the Safety Data Sheet
tox.uk@mmm.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H225, H315, H317, H319, H334, H335, H336, H351
Hazard statements
Code
Statements
H225
Highly Flammable liquid and vapour
Section 2
2.1 Classification of the substance or mixture
CLP REGULATION (EC) No 1272/2008 Flammable Liquid, Category 2 - Flam. Liq. 2; H225 Serious Eye Damage/Eye Irritation, Category 2 - Eye Irrit. 2; H319 Skin Corrosion/Irritation, Category 2 - Skin Irrit. 2; H315 Respiratory Sensitization, Category 1 - Resp. Sens. 1; H334 Skin Sensitization, Category 1 - Skin Sens. 1; H317 Carcinogenicity, Category 2 - Carc. 2; H351 Specific Target Organ Toxicity-Single Exposure, Category 3 - STOT SE 3; H335 Specific Target Organ Toxicity-Single Exposure, Category 3 - STOT SE 3; H336 For full text of H phrases, see Section 16. Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Hazard statements
Highly flammable; F; R11 Carcinogenic; Carc. Cat. 3; R40 Irritant; Xi; R36/37/38 Sensitizing; R42/43 R67 For full text of R phrases, see Section 16. H225 Highly flammable liquid and vapour. H319 Causes serious eye irritation. H315 Causes skin irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. R11 Highly flammable. R36/37/38 Irritating to eyes, respiratory system and skin. R42/43 May cause sensitisation by inhalation and skin contact. R67 Vapours may cause drowsiness and dizziness. R40 Limited evidence of a carcinogenic effect.
2.2 Label elements
CLP REGULATION (EC) No 1272/2008
Hazard pictograms
GHS02 (Flame) |GHS07 (Exclamation mark) | GHS08 (Health Hazard) | Ingredient CAS Nbr % by Wt Butanone 78-93-3 70 - 80 4,4'-methylenediphenyl diisocyanate 101-68-8 1 - 5 Diphenylmethane-2,4'-diisocyanate 5873-54-1 1 - 5 Highly Harmful Flammable
Prevention
P210A Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P284A In case of inadequate ventilation wear respiratory protection. P280E Wear protective gloves.
Response
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTRE or doctor/physician. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. P370 + P378G In case of fire: Use a fire fighting agent suitable for flammable liquids and solids such as dry chemical or carbon dioxide to extinguish. 25% of the mixture consists of components of unknown acute inhalation toxicity. Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Contains
Diphenylmethane-2,4'-diisocyanate; 4,4'-methylenediphenyl diisocyanate
Precautionary statements
S16 Keep away from sources of ignition - No Smoking. S23A Do not breathe vapour. S36/37 Wear suitable protective clothing and gloves. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Special provisions concerning the labelling of certain substances Contains isocyanates. See information supplied by manufacturer.
2.3 Other hazards
Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates.