3M Scotchkote Urethane Elastomer Primer 075

3m company

Revision date : 2014-04-11

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GHS02 GHS07 GHS08
Health risk rating 5
Safety risk rating 3
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

101-68-8

Name of the chemical

4,4’-Methylenediphenyl diisocyanate

Concentration

N/A

EC/CAS

5873-54-1

Name of the chemical

2,4’-Methylenediphenyl diisocyanate

Concentration

N/A

General Information

Revision date

2014-04-11

Product name

3M Scotchkote Urethane Elastomer Primer 075

Emergency telephone

+44 (0)1344 858 000

Icons in SDS

Company Information

company name

3m company

e-mail address of the competent person responsible for the Safety Data Sheet

tox.uk@mmm.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H225, H315, H317, H319, H334, H335, H336, H351

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

2.1 Classification of the substance or mixture

CLP REGULATION (EC) No 1272/2008 Flammable Liquid, Category 2 - Flam. Liq. 2; H225 Serious Eye Damage/Eye Irritation, Category 2 - Eye Irrit. 2; H319 Skin Corrosion/Irritation, Category 2 - Skin Irrit. 2; H315 Respiratory Sensitization, Category 1 - Resp. Sens. 1; H334 Skin Sensitization, Category 1 - Skin Sens. 1; H317 Carcinogenicity, Category 2 - Carc. 2; H351 Specific Target Organ Toxicity-Single Exposure, Category 3 - STOT SE 3; H335 Specific Target Organ Toxicity-Single Exposure, Category 3 - STOT SE 3; H336 For full text of H phrases, see Section 16. Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive

Hazard statements

Highly flammable; F; R11 Carcinogenic; Carc. Cat. 3; R40 Irritant; Xi; R36/37/38 Sensitizing; R42/43 R67 For full text of R phrases, see Section 16. H225 Highly flammable liquid and vapour. H319 Causes serious eye irritation. H315 Causes skin irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. R11 Highly flammable. R36/37/38 Irritating to eyes, respiratory system and skin. R42/43 May cause sensitisation by inhalation and skin contact. R67 Vapours may cause drowsiness and dizziness. R40 Limited evidence of a carcinogenic effect.

2.2 Label elements

CLP REGULATION (EC) No 1272/2008

Hazard pictograms

GHS02 (Flame) |GHS07 (Exclamation mark) | GHS08 (Health Hazard) | Ingredient CAS Nbr % by Wt Butanone 78-93-3 70 - 80 4,4'-methylenediphenyl diisocyanate 101-68-8 1 - 5 Diphenylmethane-2,4'-diisocyanate 5873-54-1 1 - 5 Highly Harmful Flammable

Prevention

P210A Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P284A In case of inadequate ventilation wear respiratory protection. P280E Wear protective gloves.

Response

P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTRE or doctor/physician. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. P370 + P378G In case of fire: Use a fire fighting agent suitable for flammable liquids and solids such as dry chemical or carbon dioxide to extinguish. 25% of the mixture consists of components of unknown acute inhalation toxicity. Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive

Contains

Diphenylmethane-2,4'-diisocyanate; 4,4'-methylenediphenyl diisocyanate

Precautionary statements

S16 Keep away from sources of ignition - No Smoking. S23A Do not breathe vapour. S36/37 Wear suitable protective clothing and gloves. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Special provisions concerning the labelling of certain substances Contains isocyanates. See information supplied by manufacturer.

2.3 Other hazards

Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates.

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