3M Scotchkote Urethane Coating 165HB (Part B)

Hazard statements (CLP)

H315, H317, H319, H332, H334, H335, H351, H373, H410

Code

Statements

H315

Causes skin irritation

2.1 Classification of the substance or mixture

CLP REGULATION (EC) No 1272/2008 Acute Toxicity, Category 4 - Acute Tox. 4; H332 Serious Eye Damage/Eye Irritation, Category 2 - Eye Irrit. 2; H319 Skin Corrosion/Irritation, Category 2 - Skin Irrit. 2; H315 Respiratory Sensitization, Category 1 - Resp. Sens. 1; H334 Skin Sensitization, Category 1 - Skin Sens. 1; H317 Carcinogenicity, Category 2 - Carc. 2; H351 Specific Target Organ Toxicity-Single Exposure, Category 3 - STOT SE 3; H335 Specific Target Organ Toxicity-Repeated Exposure, Category 2 - STOT RE 2; H373 Hazardous to the Aquatic Environment (Chronic), Category 1 - Aquatic Chronic 1; H410 For full text of H phrases, see Section 16. Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive

Hazard statements

Carcinogenic; Carc. Cat. 3; R40 Harmful; Xn; R20 Irritant; Xi; R36/37/38 Sensitizing; R42/43 Harmful; Xn; R48/20 Dangerous for the environment; N; R51/53 For full text of R phrases, see Section 16. H332 Harmful if inhaled. H319 Causes serious eye irritation. H315 Causes skin irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure: respiratory system H410 Very toxic to aquatic life with long lasting effects. R20 Harmful by inhalation. R36/37/38 Irritating to eyes, respiratory system and skin. R42/43 May cause sensitisation by inhalation and skin contact. R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. R40 Limited evidence of a carcinogenic effect. R51/53 Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.

2.2 Label elements

CLP REGULATION (EC) No 1272/2008

Hazard pictograms

GHS07 (Exclamation mark) | GHS08 (Health Hazard) |GHS09 (Environment) | Ingredient CAS Nbr % by Wt Polymethylene polyphenylene isocyanate 9016-87-9 30 - 60 4,4'-methylenediphenyl diisocyanate 101-68-8 35 - 45 Diphenylmethane-2,4'-diisocyanate 5873-54-1 10 - 20 2,2'-methylenediphenyl diisocyanate 2536-05-2 1 - 5 Harmful Dangerous for the

Prevention

P260E Do not breathe vapour or spray. P284A In case of inadequate ventilation wear respiratory protection. P280E Wear protective gloves. P273 Avoid release to the environment.

Response

P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTRE or doctor/physician. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.

Disposal

P501 Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 1% of the mixture consists of components of unknown acute inhalation toxicity. Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive

Contains

2,2'-methylenediphenyl diisocyanate; Diphenylmethane-2,4'-diisocyanate; 4,4'-methylenediphenyl diisocyanate; Polymethylene polyphenylene isocyanate

Precautionary statements

S23C Do not breathe vapour or spray. S51 Use only in well ventilated areas. S36/37 Wear suitable protective clothing and gloves. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S61 Avoid release to the environment. Refer to special instructions/safety data sheets. Special provisions concerning the labelling of certain substances Contains isocyanates. See information supplied by manufacturer.

2.3 Other hazards

Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates.