3M Scotchkote Urethane Aluminium Primer MCU 125

Hazard statements (CLP)

H226, H304, H315, H317, H319, H334, H335, H336, H351, H373, H412

Code

Statements

H226

Flammable liquid and vapour

2.1 Classification of the substance or mixture

CLP REGULATION (EC) No 1272/2008 Flammable Liquid, Category 3 - Flam. Liq. 3; H226 Serious Eye Damage/Eye Irritation, Category 2 - Eye Irrit. 2; H319 Skin Corrosion/Irritation, Category 2 - Skin Irrit. 2; H315 Respiratory Sensitization, Category 1 - Resp. Sens. 1; H334 Skin Sensitization, Category 1 - Skin Sens. 1; H317 Carcinogenicity, Category 2 - Carc. 2; H351 Specific Target Organ Toxicity-Single Exposure, Category 3 - STOT SE 3; H335 Specific Target Organ Toxicity-Single Exposure, Category 3 - STOT SE 3; H336 Specific Target Organ Toxicity-Repeated Exposure, Category 2 - STOT RE 2; H373 Hazardous to the Aquatic Environment (Chronic), Category 3 - Aquatic Chronic 3; H412 For full text of H phrases, see Section 16. Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive

Hazard statements

Flammable; R10 Carcinogenic; Carc. Cat. 3; R40 Harmful; Xn; R20 Irritant; Xi; R36/37/38 Sensitizing; R42/43 Harmful; Xn; R48/20 Dangerous for the environment; R52/53 For full text of R phrases, see Section 16. H226 Flammable liquid and vapour. H319 Causes serious eye irritation. H315 Causes skin irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure: respiratory system H412 Harmful to aquatic life with long lasting effects. R10 Flammable. R20 Harmful by inhalation. R36/37/38 Irritating to eyes, respiratory system and skin. R42/43 May cause sensitisation by inhalation and skin contact. R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. R40 Limited evidence of a carcinogenic effect. R52/53 Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment.

2.2 Label elements

CLP REGULATION (EC) No 1272/2008

Hazard pictograms

GHS02 (Flame) |GHS07 (Exclamation mark) | GHS08 (Health Hazard) | Ingredient CAS Nbr % by Wt Solvent naphtha (petroleum), light aromatic 64742-95-6 10 - 20 P,P'-Methylenebis(phenyl isocyanate) 101-68-8 7 - 13 Formaldehyde, oligomeric reaction products with aniline and phosgene 32055-14-4 5 - 10 Naphtha (petroleum), hydrotreated heavy 64742-48-9 5 - 10 Diphenylmethane-2,4'-diisocyanate 5873-54-1 1 - 5 p-toluenesulphonyl isocyanate 4083-64-1 0.5 - 1.0 2,2'-methylenediphenyl diisocyanate 2536-05-2 < 0.1 Harmful

Prevention

P210A Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P262 Do not get in eyes, on skin, or on clothing. P284A In case of inadequate ventilation wear respiratory protection. P280E Wear protective gloves.

Response

P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTRE or doctor/physician. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. P331 Do NOT induce vomiting. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTRE or doctor/physician. P370 + P378G In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish.

Disposal

P501 Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 31% of the mixture consists of components of unknown acute oral toxicity. 46% of the mixture consists of components of unknown acute inhalation toxicity.

Contains

52% of components with unknown hazards to the aquatic environment Notes on labelling H304 is not required on the label due to the product's viscosity Nota P applied to CASRN 64742-95-6 and CASRN 64742-48-9. Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive 1,2,4-Trimethylbenzene; Diphenylmethane-2,4'-diisocyanate; Formaldehyde, oligomeric reaction products with aniline and phosgene; P,P'-Methylenebis(phenyl isocyanate)

Precautionary statements

S23C Do not breathe vapour or spray. S51 Use only in well ventilated areas. S36/37 Wear suitable protective clothing and gloves. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S61 Avoid release to the environment. Refer to special instructions/safety data sheets. Special provisions concerning the labelling of certain substances Contains isocyanates. See information supplied by manufacturer. Notes on labelling R65 is not required on the label due to the product's viscosity. Nota P applied to CASRNs 64742-95-6 and 64742-48-9.

2.3 Other hazards

Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates.