Note: Ingredients listed on restricted chemical lists
EC/CAS
202-966-0/101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
>97 <=3
General Information
Revision date
2019-11-04
Product name
3M Scotch-Weld PUR Adhesive TS230 Black
CAS No.
101-68-8
Icons in SDS
Company Information
company name
3m company
e-mail address of the competent person responsible for the Safety Data Sheet
tox.uk@mmm.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H317, H334, H351
Hazard statements
Code
Statements
H317
May cause an allergic skin reaction
Section 2
2.1 Classification of the substance or mixture
CLP REGULATION (EC) No 1272/2008 Respiratory Sensitization, Category 1 - Resp. Sens. 1; H334 Skin Sensitization, Category 1 - Skin Sens. 1; H317 Carcinogenicity, Category 2 - Carc. 2; H351 For full text of H phrases, see Section 16.
2.2 Label elements
CLP REGULATION (EC) No 1272/2008
Hazard pictograms
GHS08 (Health Hazard) | Ingredients: Ingredient CAS Nbr EC No. % by Wt 4,4'-methylenediphenyl diisocyanate 101-68-8 202-966-0 <= 3
Hazard statements
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H351 Suspected of causing cancer.
Prevention
P261A Avoid breathing vapours. P280E Wear protective gloves.
Response
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTRE or doctor/physician. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.
Supplemental label elements
Avoid contact with hot extruded molten material or applicator tip. Avoid direct eye exposure to vapours. In case of eye/skin contact with molten material, immediately flush with cold water and cover with a clean dressing. Do not attempt to remove molten material. Have burn treated by a physician.
Contains
99% of components with unknown hazards to the aquatic environment
2.3 Other hazards
Persons previously sensitised to isocyanates may develop a cross-sensitisation reaction to other isocyanates. May cause thermal burns.