3M Rocker Protector Pouch, PN08733, 08734

SECTION 2: Hazards identification

29 CFR 1910.1200) 3.1 EMERGENCY OVERVIEW Odor, Color, Grade: Off-White Liquid, Solvent Odor General Physical Form: Liquid Immediate health, physical, and environmental hazards: Flammable liquid and vapor. Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. May cause severe skin irritation. Contains a chemical or chemicals which can cause cancer. May cause target organ effects. Contains a chemical or chemicals which can cause birth defects or other reproductive harm.

Potential health effects

Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin Contact: Severe Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Prolonged or repeated exposure may cause: Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate, bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Prolonged or repeated exposure may cause: Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and jaundice. Kidney/Bladder Effects: Signs/symptoms may include changes in urine production, abdominal or lower back pain, increased protein in urine, increased blood urea nitrogen (BUN), blood in urine, and painful urination. Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Ocular Effects: Signs/symptoms may include blurred or significantly impaired vision. Olfactory Effects: Signs/symptoms may include decreased ability to detect odors and/or complete loss of smell. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient C.A.S. No. Class Description Regulation Benzene 71432 Grp. 1: Carcinogenic to International Agency for Research on Cancer humans Benzene 71432 Known human carcinogen National Toxicology Program Carcinogens Benzene 71432 Cancer hazard OSHA Carcinogens CHROMIUM (HEXAVALENT S~CR6~C Grp. 1: Carcinogenic to International Agency for Research on Cancer COMPOUNDS) humans CHROMIUM (HEXAVALENT S~CR6~C Known human carcinogen National Toxicology Program Carcinogens COMPOUNDS) CHROMIUM (HEXAVALENT S~CR6~C Cancer hazard OSHA Carcinogens COMPOUNDS) ETHYLBENZENE 100-41-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer Lead 7439921 Grp. 2B: Possible human carc. International Agency for Research on Cancer Lead 7439921 Anticipated human carcinogen National Toxicology Program Carcinogens LEAD COMPOUNDS S~PB~C Anticipated human carcinogen National Toxicology Program Carcinogens SILICA, CRYSTALLINE (AIRBORNE SEQ677 Grp. 1: Carcinogenic to International Agency for Research on Cancer PARTICLES OF RESPIRABLE SIZE) humans SILICA, CRYSTALLINE (AIRBORNE SEQ677 Known human carcinogen National Toxicology Program Carcinogens PARTICLES OF RESPIRABLE SIZE) Titanium oxide (TiO2) 13463677 Grp. 2B: Possible human carc. International Agency for Research on Cancer SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point 36 ºF [Test Method: Pensky-Martens Closed Cup] Flammable Limits(LEL) 1.0 % [Details: email from Ray D] Flammable Limits(UEL) 7.1 % [Details: email from Ray D] 5.2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: Flammable liquid and vapor. Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. 6.2. Environmental precautions For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Collect the resulting residue containing solution. Place in a metal container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. Clean-up methods Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill. Contain spill. Cover spill area with a fire-extinguishing foam designed for use on solvents, such as alcohols and acetone, that can dissolve in water. An AR - AFFF type foam is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Seal the container. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Contents may be under pressure, open carefully. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Ground containers securely when transferring contents. Wear low static or properly grounded shoes. Do not spray near flames or sources of ignition. Avoid skin contact. Do not ingest. Avoid static discharge. Avoid eye contact with vapors, mists, or spray. Keep out of the reach of children. For industrial or professional use only. Do not breathe vapors. Avoid contact with oxidizing agents. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits. If ventilation is not adequate, use respiratory protection equipment.

Storage

Store away from acids. Store away from heat. Store out of direct sunlight. Keep container in well-ventilated area. Keep container tightly closed. Do not store containers on their sides. Store away from areas where product may come into contact with food or pharmaceuticals. Store away from oxidizing agents. Store in a cool, dry place. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Provide appropriate local exhaust ventilation on open containers. Use in an enclosed process area is recommended. Use in a well- ventilated area. Do not use in a confined area or areas with little or no air movement. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. Select and use approved eyewear to prevent eye contact with liquid splashes. The following eye protection(s) are recommended: Safety Glasses with side shields Indirect Vented Goggles . 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Fluoroelastomer Polyvinyl Alcohol (PVA) Polymer laminate . 8.2.3 Respiratory Protection Do not breathe vapors. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Do not ingest. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit

Additional information

ALUMINUM OXIDE (FIBROUS FORMS OSHA TWA, respirable 5 mg/m3 ONLY) fraction ALUMINUM OXIDE (FIBROUS FORMS OSHA TWA, as total dust 15 mg/m3 ONLY) Aluminum, insoluble compounds ACGIH TWA, respirable 1 mg/m3 fraction Benzene ACGIH TWA 0.5 ppm Skin Notation* Benzene ACGIH STEL 2.5 ppm Skin Notation* Benzene OSHA TWA 1 ppm 29 CFR 1910.1028 Benzene OSHA STEL 5 ppm 29 CFR 1910.1028 Benzene OSHA TWA 10 ppm Benzene OSHA CEIL 25 ppm Benzene, 1,3-dimethyl- ACGIH TWA 100 ppm Benzene, 1,3-dimethyl- ACGIH STEL 150 ppm Benzene, 1,4-dimethyl- ACGIH TWA 100 ppm Benzene, 1,4-dimethyl- ACGIH STEL 150 ppm Benzene, dimethyl- ACGIH TWA 100 ppm Benzene, dimethyl- ACGIH STEL 150 ppm Benzene, dimethyl- OSHA TWA 435 mg/m3 Benzene, trimethyl- ACGIH TWA 25 ppm CHROMATES OSHA CEIL 0.1 mg/m3 CHROMIUM (HEXAVALENT OSHA TWA 0.005 mg/m3 Skin Notation*; 29 CFR 1910.1026 COMPOUNDS) Chromium(6+), insoluble inorganic compounds ACGIH TWA, as Cr 0.01 mg/m3 Chromium, insoluble salts OSHA TWA, as Cr 1 mg/m3 ETHYLBENZENE ACGIH TWA 20 ppm ETHYLBENZENE CMRG TWA 25 ppm ETHYLBENZENE CMRG STEL 75 ppm ETHYLBENZENE OSHA TWA 435 mg/m3 KAOLIN ACGIH TWA, respirable 2 mg/m3 fraction KAOLIN, TOTAL DUST OSHA TWA, respirable 5 mg/m3 fraction KAOLIN, TOTAL DUST OSHA TWA, as total dust 15 mg/m3 Lead ACGIH TWA, as Pb 0.05 mg/m3 Lead OSHA TWA 0.05 mg/m3 29 CFR 1910.1025 Limestone OSHA TWA, respirable 5 mg/m3 fraction Limestone OSHA TWA, as total dust 15 mg/m3 LIMESTONE OSHA TWA, respirable 5 mg/m3 fraction LIMESTONE OSHA TWA, as total dust 15 mg/m3 SILICA, AMORPHOUS OSHA TWA concentration 0.8 mg/m3 SILICA, AMORPHOUS OSHA TWA 20 millions of particles/cu. ft. Titanium oxide (TiO2) ACGIH TWA 10 mg/m3 Titanium oxide (TiO2) OSHA TWA, as total dust 15 mg/m3 TOLUENE ACGIH TWA 20 ppm TOLUENE CMRG STEL 75 ppm Skin Notation* TOLUENE OSHA TWA 200 ppm TOLUENE OSHA CEIL 300 ppm Water-soluble inorganic Cr(6+) compounds ACGIH TWA, as Cr 0.05 mg/m3 XYLENE ACGIH TWA 100 ppm XYLENE ACGIH STEL 150 ppm XYLENE CMRG TWA 50 ppm XYLENE CMRG STEL 75 ppm XYLENE OSHA TWA 435 mg/m3 * Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Odor, Color, Grade: Off-White Liquid, Solvent Odor General Physical Form: Liquid Autoignition temperature No Data Available Flash Point 36 ºF [Test Method: Pensky-Martens Closed Cup] Flammable Limits(LEL) 1.0 % [Details: email from Ray D] Flammable Limits(UEL) 7.1 % [Details: email from Ray D] Boiling Point >=234 ºF [Details: From Boiling Points of Toluene and Xylene.] Density 0.98 - 1.02 g/ml Vapor Density No Data Available Vapor Pressure <=22 mmHg [@ 68 ºF] Specific Gravity 0.98 - 1.02 [Ref Std: WATER=1] pH Not Applicable Melting point Not Applicable Solubility In Water Not Applicable Evaporation rate No Data Available Hazardous Air Pollutants 63.4 % weight [Test Method: Calculated] Volatile Organic Compounds 548 g/l [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 4.58 lb/gal [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 60.6 % weight [Test Method: calculated per CARB title 2] Kow - Oct/Water partition coef No Data Available Percent volatile 60.9 % weight VOC Less H2O & Exempt Solvents 548 g/l [Test Method: calculated SCAQMD rule 443.1] Viscosity 3000 - 3500 centipoise SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: 10.1 Conditions to avoid Heat Sparks and/or flames 10.2 Materials to avoid Strong acids Strong oxidizing agents Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide Not Specified Carbon dioxide Not Specified Toxic Vapor, Gas, Particulate Not Specified

TOXICOLOGICAL INFORMATION

Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Dispose of waste product in a permitted hazardous waste facility. EPA Hazardous Waste Number (RCRA): D001 (Ignitable), D018 (Benzene) Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number(s): LB-K100-1039-2, LB-K100-1168-3, 60-4550-6706-0, 60-4550-6975-1 For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt XYLENE 1330-20-7 7 - 13 XYLENE (Benzene, 1,2-dimethyl-) 1330-20-7 7 - 13 XYLENE (Benzene, 1,3-dimethyl-) 1330-20-7 7 - 13 XYLENE (Benzene, 1,4-dimethyl-) 1330-20-7 7 - 13 XYLENE (Benzene, dimethyl-) 1330-20-7 7 - 13 TOLUENE 108-88-3 40 - 60 ETHYLBENZENE 100-41-4 < 5 STATE REGULATIONS Contact 3M for more information. CALIFORNIA PROPOSITION 65 Ingredient C.A.S. No.

2.1 Classification of the substance or mixture

CHROMIUM (HEXAVALENT None *Female reproductive toxin COMPOUNDS) CHROMIUM (HEXAVALENT None *Male reproductive toxin COMPOUNDS) CHROMIUM (HEXAVALENT None **Carcinogen COMPOUNDS) CHROMIUM (HEXAVALENT None *Developmental Toxin COMPOUNDS) Benzene None *Male reproductive toxin Benzene None **Carcinogen Benzene None *Developmental Toxin Lead None *Female reproductive toxin Lead None *Male reproductive toxin Lead None **Carcinogen Lead None *Developmental Toxin Titanium oxide (TiO2) None **Carcinogen LEAD COMPOUNDS None *Female reproductive toxin LEAD COMPOUNDS None *Male reproductive toxin LEAD COMPOUNDS None **Carcinogen LEAD COMPOUNDS None *Developmental Toxin SILICA, CRYSTALLINE (AIRBORNE None **Carcinogen PARTICLES OF RESPIRABLE SIZE) ETHYLBENZENE 100-41-4 **Carcinogen TOLUENE 108-88-3 *Female reproductive toxin TOLUENE 108-88-3 *Developmental Toxin * WARNING: contains a chemical or chemicals which can cause birth defects or other reproductive harm. ** WARNING: contains a chemical which can cause cancer. CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information. This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

Further information

NFPA Hazard Classification Health 2 Flammability 3 Reactivity 0 Special None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Reason for Reissue: The MSDS has been revised because 3M has adopted the 16-section ANSI/ISO format. The potential hazards of the product have not changed. We encourage you to reread the MSDS and review the information. Revision Changes: Section 9: Density information was modified. Section 9: Vapor pressure value was modified. Section 9: Boiling point information was modified. Section 5: Flammable limits (UE) information was modified. Section 5: Flammable limits (LEL) information was modified. Section 9: Specific gravity information was modified. Section 9: pH information was modified. Section 9: Melting point information was modified. Section 9: Flammable limits (LEL) information was modified. Section 9: Flammable limits (UEL) information was modified. Section 2: Ingredient table was modified. Section 8: Exposure guidelines ingredient information was modified. Section 3: Carcinogenicity table was modified. Section 15: California proposition 65 ingredient information was modified. Copyright was modified. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M 3M USA MSDSs are available at www.3M.com