3M Perfect-It EX Rubbing Compound, 36060, 36061, 36062, 36063, 36064

SECTION 2: Hazards identification

3.1 EMERGENCY OVERVIEW Odor, Color, Grade: Tan liquid slight pine oil odor General Physical Form: Liquid Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and explode. May cause allergic skin reaction. May cause target organ effects.

Potential health effects

Eye Contact: Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing. Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Prolonged or repeated exposure may cause: Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and changes in lung function tests. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point >=200 ºF [Test Method: Closed Cup] Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available 5.2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: Closed containers exposed to heat from fire may build pressure and explode. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. 6.2. Environmental precautions For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. Clean-up methods Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more information on handling and managing the spill. Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Avoid skin contact. Avoid eye contact with vapors, mists, or spray. Keep out of the reach of children. Avoid breathing of dust created by cutting, sanding, grinding or machining. Do not breathe vapors. Do not breathe dust. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits. If ventilation is not adequate, use respiratory protection equipment.

Storage

Keep from freezing. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use in an enclosed process area is recommended. Provide appropriate local exhaust for cutting, grinding, sanding or machining. Do not use in a confined area or areas with little or no air movement. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control dust, fume, or airborne particles. If ventilation is not adequate, use respiratory protection equipment. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Safety Glasses with side shields Indirect Vented Goggles . 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Neoprene Nitrile Rubber . 8.2.3 Respiratory Protection Avoid breathing of dust created by cutting, sanding, grinding or machining. Do not breathe vapors. Do not breathe dust. Consult the current 3M Respirator Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for particulates For questions about suitability for a specific application, consult with your respirator manufacturer. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit Additional Information ALUMINUM OXIDE CMRG TWA 1 fiber/cc ALUMINUM OXIDE OSHA TWA, respirable 5 mg/m3 fraction ALUMINUM OXIDE OSHA TWA, as total dust 15 mg/m3 Aluminum, insoluble compounds ACGIH TWA, respirable 1 mg/m3 fraction GLYCERIN ACGIH TWA, as mist 10 mg/m3 GLYCERIN OSHA TWA, respirable 5 mg/m3 fraction GLYCERIN OSHA TWA, as total dust 15 mg/m3 HYDROTREATED LIGHT PETROLEUM CMRG TWA 165 ppm DISTILLATES Kerosine (petroleum) ACGIH TWA, as total 200 mg/m3 Skin Notation* hydrocarbon vapor, non-aerosol MINERAL OILS, HIGHLY-REFINED OILS ACGIH TWA, inhalable 5 mg/m3 fraction Paraffin oil OSHA TWA, as mist 5 mg/m3 WHITE MINERAL OIL (PETROLEUM) CMRG TWA 5 mg/m3 WHITE MINERAL OIL (PETROLEUM) CMRG STEL 10 mg/m3 SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Odor, Color, Grade: Tan liquid slight pine oil odor General Physical Form: Liquid Autoignition temperature No Data Available Flash Point >=200 ºF [Test Method: Closed Cup] Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Boiling Point No Data Available Density 1.05 - 1.1 g/ml Vapor Density No Data Available Vapor Pressure No Data Available Specific Gravity 1.05 - 1.1 [Ref Std: WATER=1] pH 7.5 - 9 Melting point No Data Available Solubility In Water No Data Available Evaporation rate No Data Available Hazardous Air Pollutants 0.0001 lb HAPS/lb solids [Test Method: Calculated] Volatile Organic Compounds 178 g/l [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 16.2 % weight [Test Method: calculated per CARB title 2] Kow - Oct/Water partition coef No Data Available Percent volatile 78.6 % weight VOC Less H2O & Exempt Solvents 561 g/l [Test Method: calculated SCAQMD rule 443.1] Viscosity 30,000 - 35,000 centipoise SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: 10.1 Conditions to avoid None known 10.2 Materials to avoid None known Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products