3M Mar-Hyde Paintable Rubberized Undercoating Aerosol, 4211

SECTION 2: Hazards identification

(29 CFR 1910.1200) 3.1 EMERGENCY OVERVIEW Specific Physical Form: Aerosol Odor, Color, Grade: Asphalt oder / Black General Physical Form: Liquid Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and explode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Aerosol container contains flammable material under pressure. Contains a chemical or chemicals which can cause cancer. May cause target organ effects. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. May cause genotoxic or mutagenic effects.

Potential health effects

Eye Contact: Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing. Skin Contact: Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. May be absorbed through skin and cause target organ effects. Inhalation: Intentional concentration and inhalation may be harmful or fatal. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Single exposure, above recommended guidelines, may cause: Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be fatal. Prolonged or repeated exposure may cause: Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and changes in lung function tests. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. May cause blindness. Genotoxicity and Mutagenicity: May interact with genetic material and possibly alter gene expression. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient C.A.S. No. Class Description Regulation ASPHALT 8052-42-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer Carbon Black 1333-86-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. Get immediate medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. 4.2 NOTE TO PHYSICIANS Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point -18 ºC [Test Method: Closed Cup] Flammable Limits(LEL) 0.6 % Flammable Limits(UEL) 9.5 %

Storage

Store away from acids. Store away from heat. Store out of direct sunlight. Keep container tightly closed. Do not store containers on their sides. Store away from oxidizing agents. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use in an enclosed process area is recommended. Use with functioning spray booth or local exhaust. Provide appropriate local exhaust for cutting, grinding, sanding or machining. Do not use in a confined area or areas with little or no air movement. Local exhaust ventilation with a minimum capture velocity of 100 linear feet per minute should be provided for applications at or above the boiling temperature. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Indirect Vented Goggles . 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Fluoroelastomer Polymer laminate . 8.2.3 Respiratory Protection Avoid breathing of vapors, mists or spray. Avoid breathing of dust created by cutting, sanding, grinding or machining. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with

Additional information

ASPHALT ACGIH TWA, as benzene 0.5 mg/m3 solubles, inhalable fraction Carbon Black ACGIH TWA 3.5 mg/m3 Carbon Black CMRG TWA 0.5 mg/m3 Carbon Black

TOXICOLOGICAL INFORMATION

Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Dispose of waste product in a permitted hazardous waste facility. Facility must be capable of handling aerosol cans. Dispose of empty product containers in a sanitary landfill. EPA Hazardous Waste Number (RCRA): D001 (Ignitable) Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number(s): 70-0080-0424-7 For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes

2.1 Classification of the substance or mixture

BITUMENS, EXTRACTS OF STEAM- SEQ653 **Carcinogen REFINED AND AIR-REFINED Carbon Black 1333-86-4 **Carcinogen ** WARNING: contains a chemical which can cause cancer. CHEMICAL INVENTORIES Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information.

Further information

NFPA Hazard Classification Health 2 Flammability 4 Reactivity 0 Special None Aerosol Storage Code: 3 National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Revision Changes Section 16: Disclaimer (second paragraph) was modified. Section 8: Eye/face protection information was modified. Section 8: Skin protection - recommended gloves information was modified. Section 8: Respiratory protection - recommended respirators information was modified. Section 3: Immediate other hazard(s) was modified. Section 14: Transportation legal text was modified. Section 9: Boiling point information was modified. Section 5: Flammable limits (UE) information was modified. Section 5: Flammable limits (LEL) information was modified. Section 9: Property description for optional properties was modified. Section 8: Respiratory protection - recommended respirators guide was modified. Section 9: Flammable limits (LEL) information was modified. Section 9: Flammable limits (UEL) information was modified. Section 2: Ingredient table was modified. Section 8: Exposure guidelines ingredient information was modified. Section 3: Carcinogenicity table was modified. Section 15: California proposition 65 ingredient information was modified. Section 10: Materials to avoid physical property was modified. Section 10: Conditions to avoid physical property was modified. Section 6: 6.2. Environmental precautions heading was added. Section 6: 6.1. Personal precautions, protective equipment and emergency procedures heading was added. Section 16: Web address was added. Section 1: Address was added. Copyright was added. Company logo was added. Section 6: Clean-up methods heading was added. Telephone header was added. Company Telephone was added. Section 1: Emergency phone information was added. Section 1: Emergency phone information was deleted. Company Logo was deleted. Copyright was deleted. Section 16: Web address heading was deleted. Section 6: Release measures heading was deleted. Section 1: Address line 1 was deleted. Section 1: Address line 2 was deleted. Section 8: Exposure guidelines legend was deleted. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M