3M High Strength Color Changing Spackling

Hazard statements (CLP)

H315, H318, H335

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

Hazard classification Skin Corrosion/Irritation: Category 2 Serious Eye Damage/Irritation: Category 1 Specific Target Organ Toxicity (single exposure): Category 3

Hazard pictograms

Corrosion |Exclamation mark |

Hazard statements

Causes skin irritation. Causes serious eye damage. May cause respiratory irritation.

Precautionary statements

General: Keep out of reach of children.

Prevention

Avoid breathing vapors. Wash exposed skin thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective gloves, eye protection, and face protection.

Response

IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Immediately call a POISON CENTER or doctor. If skin irritation occurs: Get medical advice. Take off contaminated clothing and wash it before reuse.

Storage

Store in a well-ventilated place. Keep container tightly closed. Store locked up.

Disposal

Dispose of contents and container in accordance with applicable local, regional, national, and international regulations. 20% of the mixture consists of ingredients of unknown acute oral toxicity.

2.1 Classification of the substance or mixture

Skin Corrosion/Irritation: Category 2. Serious Eye Damage/Irritation: Category 1. Specific Target Organ Toxicity (single exposure): Category 3. 2.2. Label elements Signal word Danger Symbols Corrosion |Exclamation mark | Pictograms Hazard Statements Causes skin irritation. Causes serious eye damage. May cause respiratory irritation. Precautionary statements General: Keep out of reach of children. Prevention: Avoid breathing vapors. Wash exposed skin thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective gloves, eye protection, and face protection. Response: IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Immediately call a POISON CENTER or doctor. If skin irritation occurs: Get medical advice. Take off contaminated clothing and wash it before reuse. Storage: Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal: Dispose of contents and container in accordance with applicable local, regional, national, and international regulations. 20% of the mixture consists of ingredients of unknown acute oral toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt pH Adjuster Trade Secret* 0.5 - 5 Trade Secret * Potassium Hydroxide 1310-58-3 < 0.5 *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue rinsing. Immediately get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed Irritating to the respiratory tract (coughing, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain). Serious damage to the eyes (corneal cloudiness, severe pain, tearing, ulcerations, and significantly impaired or loss of vision). 4.3. Indication of any immediate medical attention and special treatment required Not applicable. SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion Oxides of Nitrogen During Combustion 5.3. Special protective actions for fire-fighters Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Use personal protective equipment based on the results of an exposure assessment. Refer to Section 8 for PPE recommendations. If anticipated exposure resulting from an accidental release exceeds the protective capabilities of the PPE listed in Section 8, or are unknown, select PPE that offers an appropriate level of protection. Consider the physical and chemical hazards of the material when doing so. Examples of PPE ensembles for emergency response could include wearing bunker gear for a release of flammable material; wearing chemical protective clothing if the spilled material is a corrosive, a sensitizer, a significant dermal irritant, or can be absorbed through the skin; or donning a positive pressure supplied-air respirator for chemicals with inhalation hazards. For information regarding physical and health hazards, refer to sections 2 and 11 of the SDS. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Contain spill. For large spills, if necessary, get assistance from professional spill clean up team. For small spills, carefully neutralize spill by adding appropriate dilute acid such as vinegar. Work slowly to avoid boiling or spattering. Continue to add neutralizing agent until reaction stops. Let cool before collecting. Or use a commercially available caustic (alkaline or basic) spill clean-up kit. Follow kit directions exactly. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry.