3M FRITTED GLASS PRIMER P590, BLACK

Hazard statements (CLP)

H225, H315, H317, H319, H334, H335, H336, H351, H412

Code

Statements

H225

Highly Flammable liquid and vapour

2.1 Classification of the substance or mixture

CLP REGULATION (EC) No 1272/2008 Flammable Liquid, Category 2 - Flam. Liq. 2; H225 Serious Eye Damage/Eye Irritation, Category 2 - Eye Irrit. 2; H319 Skin Corrosion/Irritation, Category 2 - Skin Irrit. 2; H315 Respiratory Sensitization, Category 1A - Resp. Sens. 1A; H334 Skin Sensitization, Category 1A - Skin Sens. 1A; H317 Carcinogenicity, Category 2 - Carc. 2; H351 Specific Target Organ Toxicity-Single Exposure, Category 3 - STOT SE 3; H335 Specific Target Organ Toxicity-Single Exposure, Category 3 - STOT SE 3; H336 Hazardous to the Aquatic Environment (Chronic), Category 3 - Aquatic Chronic 3; H412 For full text of H phrases, see Section 16.

2.2 Label elements

CLP REGULATION (EC) No 1272/2008

Hazard pictograms

GHS02 (Flame) |GHS07 (Exclamation mark) | GHS08 (Health Hazard) | Ingredients: Ingredient CAS Nbr % by Wt Butanone 78-93-3 40 - 70 1,6-Hexamethylene diisocyanate - toluene diisocyanate copolymer 63368-95-6 5 - 10 4,4'-methylenediphenyl diisocyanate 101-68-8 3 - 7 Polymethylene polyphenylene isocyanate 9016-87-9 0.5 - 2 Diphenylmethane-2,4'-diisocyanate 5873-54-1 0.5 - 2 Hexamethylene diisocyanate polymer 28182-81-2 1 - 5 p-toluenesulphonyl isocyanate 4083-64-1 < 1 Hexamethylene diisocyanate 822-06-0 < 0.5 4-methyl-m-phenylene diisocyanate 584-84-9 < 0.1

Hazard statements

H225 Highly flammable liquid and vapour. H319 Causes serious eye irritation. H315 Causes skin irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. H412 Harmful to aquatic life with long lasting effects.

Prevention

P261A Avoid breathing vapours. P284A In case of inadequate ventilation wear respiratory protection. P280E Wear protective gloves. P261A Avoid breathing vapours. P284A In case of inadequate ventilation wear respiratory protection. P280E Wear protective gloves.

Response

P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTRE or doctor/physician. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTRE or doctor/physician. 3% of the mixture consists of components of unknown acute oral toxicity. 22% of the mixture consists of components of unknown acute inhalation toxicity.

Disposal

P501 Dispose of contents/container in accordance with applicable local/regional/national/international regulations. For containers not exceeding 125 ml the following Hazard and Precautionary statements may be used: <=125 ml Hazard statements H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H351 Suspected of causing cancer. H412 Harmful to aquatic life with long lasting effects. <=125 ml Precautionary statements

Contains

14% of components with unknown hazards to the aquatic environment

2.3 Other hazards

Persons previously sensitised to isocyanates may develop a cross-sensitisation reaction to other isocyanates.