Note: Ingredients listed on restricted chemical lists
EC/CAS
9016-87-9
Name of the chemical
4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)
Concentration
N/A
EC/CAS
5873-54-1
Name of the chemical
2,4’-Methylenediphenyl diisocyanate
Concentration
N/A
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
N/A
EC/CAS
227-534-9
Name of the chemical
4,4'-Methylendiphenyldiisocyanat 2,2'-Methylendiphenyldiisocyanat 2,4'-Methylendiphenyldiisocyanat Methylendiphenyldiisocyanat (790/2009)
Concentration
N/A
EC/CAS
202-966-0
Name of the chemical
4,4'-Methylendiphenyldiisocyanat 2,2'-Methylendiphenyldiisocyanat 2,4'-Methylendiphenyldiisocyanat Methylendiphenyldiisocyanat (790/2009)
Concentration
N/A
General Information
Revision date
2020-05-14
Product name
3M Flexible Foam/Part A, 08463
Emergency telephone
+44 (0)1344 858 000
Icons in SDS
Company Information
company name
3m company
e-mail address of the competent person responsible for the Safety Data Sheet
tox.uk@mmm.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H334, H335, H351, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
2.1 Classification of the substance or mixture
CLP REGULATION (EC) No 1272/2008 Serious Eye Damage/Eye Irritation, Category 2 - Eye Irrit. 2; H319 Skin Corrosion/Irritation, Category 2 - Skin Irrit. 2; H315 Respiratory Sensitization, Category 1 - Resp. Sens. 1; H334 Skin Sensitization, Category 1 - Skin Sens. 1; H317 Carcinogenicity, Category 2 - Carc. 2; H351 Specific Target Organ Toxicity-Single Exposure, Category 3 - STOT SE 3; H335 Specific Target Organ Toxicity-Repeated Exposure, Category 2 - STOT RE 2; H373 For full text of H phrases, see Section 16.
2.2 Label elements
CLP REGULATION (EC) No 1272/2008
Hazard pictograms
GHS07 (Exclamation mark) | GHS08 (Health Hazard) | Ingredients: Ingredient CAS Nbr EC No. % by Wt Formaldehyde, oligomeric reaction products with 32055-14-4 500-079-6 10 - 30 aniline and phosgene Polymethylene polyphenylene isocyanate 9016-87-9 10 - 30 o-(p-isocyanatobenzyl)phenyl isocyanate 5873-54-1 227-534-9 1 - 10 4,4'-methylenediphenyl diisocyanate 101-68-8 202-966-0 1 - 10
Hazard statements
H319 Causes serious eye irritation. H315 Causes skin irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure: respiratory system |
Prevention
P260A Do not breathe vapours. P280E Wear protective gloves.
Response
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTRE or doctor/physician. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. 38% of the mixture consists of components of unknown acute oral toxicity.
Contains
41% of components with unknown hazards to the aquatic environment
2.3 Other hazards
Persons previously sensitised to isocyanates may develop a cross-sensitisation reaction to other isocyanates.
