3M ESPE KETAC-FIL PLUS APLICAP POWDER

SECTION 2: Hazards identification

29 CFR 1910.1200) 3.1 EMERGENCY OVERVIEW Specific Physical Form: Powder Odor, Color, Grade: Different colored, odorless powders General Physical Form: Solid Immediate health, physical, and environmental hazards: This document has been prepared in accordance with the U.S. OSHA Communication Standard, which requires the inclusion of all known hazards of the product or ingredients regardless of the potential risk. The risks of the hazards communicated in this document may vary depending on the potential for exposure.

Potential health effects

Eye Contact: Mechanical eye irritation: Signs/symptoms may include pain, redness, tearing and corneal abrasion. Skin Contact: Mechanical Skin irritation: Signs/symptoms may include abrasion, redness, pain, and itching. No health effects are expected. Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Wash affected area with soap and water. If signs/symptoms develop, get medical attention. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point No flash point Flammable Limits(LEL) Not Applicable Flammable Limits(UEL) Not Applicable 5.2 EXTINGUISHING MEDIA Non-combustible. Choose material suitable for surrounding fire. Material will not burn. 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: No unusual fire or explosion hazards are anticipated. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. 6.2. Environmental precautions Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. Clean-up methods Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more information on handling and managing the spill. Collect as much of the spilled material as possible. Use wet sweeping compound or water to avoid dusting. Sweep up. Clean up residue. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Avoid eye contact. Avoid prolonged or repeated skin contact.

Storage

Not applicable. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Not applicable. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact. The following eye protection(s) are recommended: Safety Glasses with side shields . 8.2.2 Skin Protection Avoid skin contact. Avoid prolonged or repeated skin contact. Gloves are not required. Gloves not normally required. 8.2.3 Respiratory Protection Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. 8.2.4 Prevention of Swallowing Not applicable. Do not ingest. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit

Additional information

GLASS POWDER Manufacturer TWA, as dust 10 mg/m3 determined SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Specific Physical Form: Powder Odor, Color, Grade: Different colored, odorless powders General Physical Form: Solid Autoignition temperature No Data Available Flash Point No flash point Flammable Limits(LEL) Not Applicable Flammable Limits(UEL) Not Applicable Boiling Point Not Applicable Vapor Density Not Applicable Vapor Pressure Not Applicable Specific Gravity >=1.0 [Ref Std: WATER=1] pH Not Applicable Melting point No Data Available Solubility in Water Moderate Evaporation rate Not Applicable Volatile Organic Compounds Not Applicable Kow - Oct/Water partition coef No Data Available Percent volatile Not Applicable VOC Less H2O & Exempt Solvents Not Applicable Viscosity Not Applicable SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: 10.1 Conditions to avoid None known 10.2 Materials to avoid None known Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Condition None known. During Combustion

TOXICOLOGICAL INFORMATION

Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Dispose of waste product in a facility permitted to accept chemical waste. As a disposal alternative, dispose of waste product in a facility permitted to accept chemical waste. EPA Hazardous Waste Number (RCRA): Not regulated Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION LE-FSFD-5501-1 For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No STATE REGULATIONS Contact 3M for more information. CHEMICAL INVENTORIES All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. This material contains one or more substances not listed on the TSCA Inventory. Commercial use of this material is regulated by the FDA. Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information. This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

Further information

NFPA Hazard Classification Health 1 Flammability 0 Reactivity 0 Special None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Revision Changes: Section 3: Potential effects from skin contact information information was modified. Section 8: Prevention of swallowing information information was modified. Sections 3 and 9: Specific physical form information information was modified. Section 14: ID Number(s) Template 1 information was modified. Section 2: Ingredient table information was modified. Section 8: Hand protection information information was modified. Copyright information was modified. Section 14: ID Number Heading Template 1 information was deleted. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M 3M USA MSDSs are available at www.3M.com SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 3M™ ESPE™ KETAC FIL PLUS APLICAP LIQUID MANUFACTURER: 3M DIVISION: 3M ESPE Dental Products ADDRESS: 3M Center, St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours) Issue date 07/27/12 Supercedes Date: Initial Issue Document Group: 30-7032-3 Product Use: Intended Use: Dental Product Limitations on Use: For use only by dental professionals Specific Use: Dental restorative SECTION 2: INGREDIENTS Ingredient C.A.S. No. % by Wt COPOLYMER OF ACRYLIC ACID-MALEIC ACID 29132-58-9 35 - 55 WATER 7732-18-5 40 - 55 TARTARIC ACID 87-69-4 5 - 10 SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW Specific Physical Form: Liquid Odor, Color, Grade: Slightly acidic odor, colorless General Physical Form: Liquid Immediate health, physical, and environmental hazards: This document has been prepared in accordance with the U.S. OSHA Hazard Communication Standard, which requires the inclusion of all known hazards of the product or ingredients regardless of the potential risk. The risks of the hazards communicated in this document may vary depending on the potential for exposure. 3.2 POTENTIAL HEALTH EFFECTS Eye Contact: Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing. Skin Contact: Contact with the skin during product use is not expected to result in significant irritation. Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.