3M Citrus Base Cleaner (Aerosol)

SECTION 2: Hazards identification

3.1 EMERGENCY OVERVIEW Odor, Color, Grade: clear, pale yellow, sweet odor General Physical Form: Gas Aerosol Immediate health, physical, and environmental hazards: Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Aerosol container contains flammable material under pressure. May cause target organ effects.

Potential health effects

Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin Contact: Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Single exposure, above recommended guidelines, may cause: Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be fatal. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. Get immediate medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. 4.2 NOTE TO PHYSICIANS Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point -50.00 ºF Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available 5.2 EXTINGUISHING MEDIA Ordinary combustible material. Use fire extinguishers with class A extinguishing agents (e.g., water, foam). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Aerosol container contains flammable material under pressure. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. 6.2. Environmental precautions For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Collect the resulting residue containing solution. Place in a metal container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. Clean-up methods Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill. Contain spill. Cover spill area with a fire-extinguishing foam. An aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Seal the container. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. No smoking while handling this material. Avoid eye contact with vapors, mists, or spray. For industrial or professional use only. Avoid contact with oxidizing agents.

Storage

Store away from acids. Store away from heat. Store out of direct sunlight. Keep container in well-ventilated area. Store away from oxidizing agents. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use with appropriate local exhaust ventilation. Provide appropriate local exhaust ventilation on open containers. Use in an enclosed process area is recommended. Use with functioning spray booth or local exhaust. Do not use in a confined area or areas with little or no air movement. Do not remain in area where available oxygen may be reduced. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. Do not use in a confined area or areas with little or no air movement. If exhaust ventilation is not adequate, use appropriate respiratory protection. Provide ventilation adequate to control vapor concentrations below recommended exposure limits and/or control spray or mist. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Safety Glasses with side shields . 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Nitrile Rubber Polyvinyl Alcohol (PVA) . 8.2.3 Respiratory Protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors For questions about suitability for a specific application, consult with your respirator manufacturer. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Not applicable. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit Additional Information Propane OSHA TWA 1800 mg/m3 SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Odor, Color, Grade: clear, pale yellow, sweet odor General Physical Form: Gas Aerosol Autoignition temperature No Data Available Flash Point -50.00 ºF Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Boiling Point Not Applicable Density 0.784 g/ml Vapor Density Not Applicable Vapor Pressure 28 mmHg [@ 20 ºC] [Details: Composite Vapor Pressure (Calculated)] Specific Gravity 0.784 [Ref Std: WATER=1] pH Not Applicable Melting point No Data Available Solubility in Water Slight (less than 10%) Evaporation rate Not Applicable Hazardous Air Pollutants 0 % weight [Test Method: Calculated] Volatile Organic Compounds Approximately 91 % [Test Method: tested per EPA method 24] [Details: low solids less exempts] Volatile Organic Compounds 6.18 lb/gal [Test Method tested per EPA method 24] [Details low solids less exempts] Kow - Oct/Water partition coef No Data Available Percent volatile Approximately 91 % weight VOC Less H2O & Exempt Solvents 94.4 % [Test Method: tested per EPA method 24] Viscosity Not Applicable Solids Content 0 % SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: 10.1 Conditions to avoid Heat 10.2 Materials to avoid Strong oxidizing agents Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products