3M Carburetor Cleaner, 08796

SECTION 2: Hazards identification

29 CFR 1910.1200) 3.1 EMERGENCY OVERVIEW Specific Physical Form: Aerosol Odor, Color, Grade: Clear spray with solvent odor General Physical Form: Liquid Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and explode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Aerosol container contains flammable material under pressure. May cause severe eye irritation. May cause severe skin irritation. May cause target organ effects. Contains a chemical or chemicals which can cause birth defects or other reproductive harm.

Potential health effects

Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Skin Contact: Severe Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. May be absorbed through skin and cause target organ effects. Inhalation: Intentional concentration and inhalation may be harmful or fatal. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Single exposure, above recommended guidelines, may cause: Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be fatal. Prolonged or repeated exposure may cause: Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate, bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Chemical (Aspiration) Pneumonitis: Signs/symptoms may include coughing, gasping, choking, burning of the mouth, difficulty breathing, bluish colored skin (cyanosis), and may be fatal. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: May cause blindness. Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Blood Effects: Signs/symptoms may include generalized weakness and fatigue, skin pallor, changes in blood clotting time, internal bleeding, and/or hemoglobinemia. Prolonged or repeated exposure may cause: Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Ocular Effects: Signs/symptoms may include blurred or significantly impaired vision. Olfactory Effects: Signs/symptoms may include decreased ability to detect odors and/or complete loss of smell. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. Get immediate medical attention. If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get immediate medical attention. 4.2 NOTE TO PHYSICIANS Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point -50.00 ºF Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available 5.2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: Closed containers exposed to heat from fire may build pressure and explode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Aerosol container contains flammable material under pressure. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. 6.2. Environmental precautions Place depressurized can and clean up wastes in a closed container approved for transportation by appropriate authorities. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Dispose of collected material as soon as possible. Clean-up methods Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill. Contain spill. Cover spill area with a fire-extinguishing foam. An aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with detergent and water. Seal the container. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Do not pierce or burn container, even after use. Do not spray near flames or sources of ignition. Avoid breathing of vapors, mists or spray. Aerosol container contains flammable gas under pressure. Avoid static discharge. Avoid eye contact with vapors, mists, or spray. Keep out of the reach of children. Avoid contact with oxidizing agents. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits. If ventilation is not adequate, use respiratory protection equipment. Avoid skin contact.

Storage

Store away from acids. Store away from heat. Store out of direct sunlight. Keep container tightly closed. Do not store containers on their sides. Store away from areas where product may come into contact with food or pharmaceuticals. Store away from oxidizing agents. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use in an enclosed process area is recommended. Use in a well-ventilated area. Do not use in a confined area or areas with little or no air movement. Do not remain in area where available oxygen may be reduced. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Safety Glasses with side shields Indirect Vented Goggles . 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Fluoroelastomer Polymer laminate . 8.2.3 Respiratory Protection Avoid breathing of vapors, mists or spray. Consult the current 3M Respirator Selection Guide for additional information or call 1- 800-243-4630 for 3M technical assistance. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors For questions about suitability for a specific application, consult with your respirator manufacturer. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit

Additional information

ACETONE ACGIH TWA 500 ppm ACETONE ACGIH STEL 750 ppm ACETONE OSHA TWA 2400 mg/m3 DIACETONE ALCOHOL ACGIH TWA 50 ppm DIACETONE ALCOHOL OSHA TWA 240 mg/m3 METHYL ALCOHOL ACGIH TWA 200 ppm Skin Notation* METHYL ALCOHOL ACGIH STEL 250 ppm Skin Notation* METHYL ALCOHOL OSHA TWA 260 mg/m3 PROPANE OSHA TWA 1800 mg/m3 TOLUENE ACGIH TWA 20 ppm TOLUENE CMRG STEL 75 ppm Skin Notation* TOLUENE OSHA TWA 200 ppm TOLUENE OSHA CEIL 300 ppm * Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Specific Physical Form: Aerosol Odor, Color, Grade: Clear spray with solvent odor General Physical Form: Liquid Autoignition temperature No Data Available Flash Point -50.00 ºF Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Boiling Point No Data Available Density 0.776 g/ml Vapor Density >=1 [Ref Std: AIR=1] Vapor Pressure No Data Available Specific Gravity 0.776 [Ref Std: WATER=1] pH Not Applicable Melting point No Data Available Solubility in Water Slight (less than 10%) Evaporation rate No Data Available Hazardous Air Pollutants 53.0 % weight [Test Method: Calculated] Volatile Organic Compounds 580 g/l [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 74.8 % weight [Test Method: calculated per CARB title 2] Kow - Oct/Water partition coef No Data Available Percent volatile 100 % weight VOC Less H2O & Exempt Solvents 771 g/l [Test Method: calculated SCAQMD rule 443.1] Viscosity Not Applicable SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: 10.1 Conditions to avoid Heat 10.2 Materials to avoid None known Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide Not Specified Carbon dioxide Not Specified

TOXICOLOGICAL INFORMATION

Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. Facility must be capable of handling aerosol cans. Dispose of empty product containers in a sanitary landfill. EPA Hazardous Waste Number (RCRA): D001 (Ignitable) Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number(s): 60-4550-3013-4, 60-4550-6902-5 For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt TOLUENE 108-88-3 35 - 45 METHYL ALCOHOL 67-56-1 10 - 15 STATE REGULATIONS Contact 3M for more information. CALIFORNIA PROPOSITION 65 Ingredient C.A.S. No.

2.1 Classification of the substance or mixture

METHYL ALCOHOL 67-56-1 *Developmental Toxin TOLUENE 108-88-3 *Female reproductive toxin TOLUENE 108-88-3 *Developmental Toxin * WARNING: contains a chemical or chemicals which can cause birth defects or other reproductive harm. CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information. This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

Further information

NFPA Hazard Classification Health 2 Flammability 4 Reactivity 0 Special None Aerosol Storage Code: 2 National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Revision Changes: Section 1: Product name was modified. Section 1: Product use information was modified. Section 4: First aid for eye contact - decontamination - was modified. Section 4: First aid for eye contact - medical assistance - was modified. Section 3: Potential effects from eye contact was modified. Section 3: Potential effects from ingestion information was modified. Section 7: Handling information was modified. Section 7: Storage information was modified. Section 8: Respiratory protection information was modified. Section 8: Prevention of swallowing information was modified. Section 10: Hazardous decomposition or by-products table was modified. Section 13: Waste disposal method information was modified. Section 8: Respiratory protection - recommended respirators information was modified. Section 4: First aid for ingestion (swallowing) - decontamination - was modified. Section 4: First aid for ingestion (swallowing) - medical assistance - was modified. Section 8: Respiratory protection - recommended respirators was modified. Section 3: Other health effects information was modified. Page Heading: Product name was modified. Section 15: Inventories information was modified. Section 9: Density information was modified. Section 9: Vapor density value was modified. Section 9: Vapor pressure value was modified. Section 9: Boiling point information was modified. Section 5: Flammable limits (UE) information was modified. Section 5: Flammable limits (LEL) information was modified. Section 5: Autoignition temperature information was modified. Section 5: Flash point information was modified. Section 9: Property description for optional properties was modified. Section 9: Specific gravity information was modified. Section 9: pH information was modified. Section 9: Melting point information was modified. Section 9: Solubility in water text was modified. Section 8: Respiratory protection - recommended respirators guide was modified. Section 9: Flash point information was modified.