3M BONDO PROFESSIONAL GLAZING & SPOT PUTTY, 801

SECTION 2: Hazards identification

29 CFR 1910.1200) 3.1 EMERGENCY OVERVIEW Odor, Color, Grade: Strong Solvent Odor White paste General Physical Form: Liquid Immediate health, physical, and environmental hazards: Flammable liquid and vapor. Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. May cause target organ effects. Contains a chemical or chemicals which can cause cancer.

Potential health effects

Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin Contact: Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Inhalation: Intentional concentration and inhalation may be harmful or fatal. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Prolonged or repeated exposure may cause: Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and changes in lung function tests. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Prolonged or repeated exposure may cause: Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and jaundice. Immunological Effects: Signs/symptoms may include alterations in the number of circulating immune cells, allergic skin and /or respiratory reaction, and changes in immune function. Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Ocular Effects: Signs/symptoms may include blurred or significantly impaired vision. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient C.A.S. No. Class Description Regulation QUARTZ SILICA 14808-60-7 Grp. 1: Carcinogenic to International Agency for Research on Cancer humans SILICA, CRYSTALLINE (AIRBORNE SEQ677 Grp. 1: Carcinogenic to International Agency for Research on Cancer PARTICLES OF RESPIRABLE SIZE) humans SILICA, CRYSTALLINE (AIRBORNE SEQ677 Known human carcinogen National Toxicology Program Carcinogens PARTICLES OF RESPIRABLE SIZE) STYRENE 100-42-5 Grp. 2B: Possible human carc. International Agency for Research on Cancer SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point 88 ºF [Test Method: Closed Cup] Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available

Storage

Store away from acids. Store away from heat. Store out of direct sunlight. Keep container in well-ventilated area. Keep container tightly closed. Store away from oxidizing agents. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use with appropriate local exhaust ventilation. Use in an enclosed process area is recommended. Provide appropriate local exhaust for cutting, grinding, sanding or machining. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. To minimize the risk of injury to face and eyes, always wear eye and face protection when working at sanding or grinding operations or when near such operations. The following eye protection(s) are recommended: Indirect Vented Goggles . 8.2.2 Skin Protection Avoid prolonged or repeated skin contact. Wear appropriate gloves to minimize risk of injury to skin from contact with dust or physical abrasion from grinding or sanding. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Nitrile Rubber . 8.2.3 Respiratory Protection Avoid breathing of vapors, mists or spray. Avoid breathing of dust created by cutting, sanding, grinding or machining. Do not breathe vapors. Do not breathe dust. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with

Additional information

LIMESTONE

TOXICOLOGICAL INFORMATION

Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Dispose of waste product in a permitted hazardous waste facility. EPA Hazardous Waste Number (RCRA): D001 (Ignitable) Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number(s): LB-K100-0425-9, 41-0003-6689-2 For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372

2.1 Classification of the substance or mixture

SILICA, CRYSTALLINE (AIRBORNE SEQ677 **Carcinogen PARTICLES OF RESPIRABLE SIZE) ** WARNING: contains a chemical which can cause cancer. CHEMICAL INVENTORIES Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information. This MSDS has been prepared to meet the U.S.

Further information

NFPA Hazard Classification Health: 2 Flammability: 3 Reactivity: 1 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Revision Changes: Section 16: Disclaimer (second paragraph) was modified. Section 3: Potential effects from skin contact information was modified. Section 3: Potential effects from inhalation information was modified. Section 13: Waste disposal method information was modified. Section 3: Immediate other hazard(s) was modified. Section 14: Transportation legal text was modified. Section 3: Other health effects information was modified. Section 9: Boiling point information was modified.