3M Adper Single Bond 2

3M

Revision date : 2023-11-05

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GHS02 GHS07 GHS08
Health risk rating 5
Safety risk rating 3
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

64-17-5

Name of the chemical

Ethanol

Concentration

25 - 35

EC/CAS

868-77-9

Name of the chemical

2-hydroxyethyl methacrylate

Concentration

5 - 15

EC/CAS

7732-18-5

Name of the chemical

Water, distilled, conductivity or of similar purity H2O

Concentration

< 10

EC/CAS

72869-86-4

Name of the chemical

11,14-Dioxa-2,9-diazaheptadec-16-enoic Acid, 4,4,6,16-tetramethyl-10,15-dioxo, 2-[(2-methyl-1-oxo-2-propenyl)oxy]ethyl ester (31)

Concentration

< 5

General Information

Version

13.00

Revision date

2023-11-05

Product name

3M Adper Single Bond 2

1.2.1 Relevant identified uses

Dental Product, Adhesive

1.2.2. Uses advised against

For use only by dental professionals

supplier name

3M

Manufacturer Name

3M

Emergency telephone

1-800-364-3577, (651) 737-6501

Icons in SDS

GHS02 GHS07 GHS08 M004

Company Information

company name

3M

Hazard Codes

Hazard statements (CLP)

H225, H317, H319, H360

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

Hazard pictograms

Flame | Exclamation mark | Health Hazard |

Hazard statements

Highly flammable liquid and vapor. Causes serious eye irritation. May cause an allergic skin reaction. May damage fertility or the unborn child.

Prevention

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Take precautionary measures against static discharge. Keep container tightly closed. Avoid breathing dust/fume/gas/mist/vapors/spray. Wear protective gloves and eye/face protection. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace.

Response

IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. IF exposed or concerned: Get medical advice/attention. In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish.

Storage

Store in a well-ventilated place. Keep cool.

Disposal

Dispose of contents/container in accordance with applicable local/regional/national/international regulations.

2.1 Classification of the substance or mixture

Flammable Liquid: Category 2. Serious Eye Damage/Irritation: Category 2A. Skin Sensitizer: Category 1. Reproductive Toxicity: Category 1B. 2.2. Label elements Signal word Danger Symbols Flame | Exclamation mark | Health Hazard | Pictograms Hazard Statements Highly flammable liquid and vapor. Causes serious eye irritation. May cause an allergic skin reaction. May damage fertility or the unborn child. Precautionary Statements Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Take precautionary measures against static discharge. Keep container tightly closed. Avoid breathing dust/fume/gas/mist/vapors/spray. Wear protective gloves and eye/face protection. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. IF exposed or concerned: Get medical advice/attention. In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. Storage: Store in a well-ventilated place. Keep cool. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Ethyl Alcohol 64-17-5 25 - 35 Trade Secret * Bisphenol A Diglycidyl Ether Dimethacrylate 1565-94-2 10 - 20 Trade Secret * (BISGMA) Silane Treated Silica None 10 - 20 Trade Secret * 2-Hydroxyethyl Methacrylate (HEMA) 868-77-9 5 - 15 Trade Secret * Glycerol 1,3 Dimethacrylate 1830-78-0 5 - 10 Trade Secret * Water 7732-18-5 < 10 Trade Secret * Copolymer Of Acrylic And Itaconic Acids 25948-33-8 < 5 Trade Secret * Diurethane Dimethacrylate (UDMA) 72869-86-4 < 5 Trade Secret * Diphenyliodonium Hexafluorophosphate 58109-40-3 < 1 Trade Secret * Ethyl 4-Dimethyl Aminobenzoate (EDMAB) 10287-53-3 < 0.3 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed Allergic skin reaction (redness, swelling, blistering, and itching). 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and

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