3M(TM) Scotchcast(TM) Conformable Roll Splint 73002, 73003, 73004 & 73005

SECTION 2: Hazards identification

3.1 EMERGENCY OVERVIEW Specific Physical Form: Pliable solid. Odor, Color, Grade: Viscous resin impregnated on knit encased in off-white felt; slight odor. General Physical Form: Solid Immediate health, physical, and environmental hazards: May cause allergic skin reaction. May cause allergic respiratory reaction.

Potential health effects

Eye Contact: Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing. Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Allergic Respiratory Reaction: Signs/symptoms may include difficulty breathing, wheezing, cough, and tightness of chest. Ingestion: Physical Blockage: Signs/symptoms may include cramping, abdominal pain, and constipation. Target Organ Effects: Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point Not Applicable Flammable Limits - LEL Not Applicable Flammable Limits - UEL Not Applicable 5.2 EXTINGUISHING MEDIA DO NOT USE WATER Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: Not applicable. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. Collect as much of the spilled material as possible. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Place in a metal container approved for transportation by appropriate authorities. Cover, but do not seal for 48 hours. Dispose of collected material as soon as possible. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Avoid eye contact. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. For industrial or professional use only. Avoid contact with unprotected areas of the splint created by trimming or removal of the fabric or felt covering.

Storage

Store away from heat. Store out of direct sunlight. Keep container tightly closed. Keep container closed when not in use. For best performance store between 40-80 deg F. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use in a well-ventilated area. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact. 8.2.2 Skin Protection Gloves are not required. Protective gloves are not necessary while handling this product. Avoid contact with unprotected areas of the splint created by trimming or removal fo the fabric or felt covering. See product insert for additional precaution statements. 8.2.3 Respiratory Protection Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Not applicable. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit Additional Information 1,1'- ACGIH TWA 0.005 ppm METHYLENEBIS(ISOCYANATOBENZENE ) 1,1'- OSHA CEIL 0.02 ppm Table Z-1 METHYLENEBIS(ISOCYANATOBENZENE ) FREE ISOCYANATES 3M TWA 0.005 ppm FREE ISOCYANATES 3M STEL 0.02 ppm SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)