3M(TM) HB QUAT DISINFECTANT CLEANER CONCENTRATE

SECTION 2: Hazards identification

29 CFR 1910.1200) 3.1 EMERGENCY OVERVIEW Specific Physical Form: Liquid Odor, Color, Grade: Clear, light amber color, mild odor. General Physical Form: Liquid Immediate health, physical, and environmental hazards: Combustible liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back. May cause chemical eye burns. May cause chemical skin burns. May cause chemical gastrointestinal burns. Contains a chemical or chemicals which can cause cancer. May cause target organ effects. Contains a chemical or chemicals which can cause birth defects or other reproductive harm.

Potential health effects

Eye Contact: Corrosive (Eye Burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing, ulcerations, significantly impaired vision or complete loss of vision. Skin Contact: Corrosive (Skin Burns): Signs/symptoms may include localized redness, swelling, itching, intense pain, blistering, ulceration, and tissue destruction. Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Corrosion: Signs/symptoms may include severe mouth, throat and abdominal pain; nausea; vomiting; and diarrhea; blood in the feces and/or vomitus may also be seen. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Prolonged or repeated exposure may cause: Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and jaundice. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Carcinogenicity: NOTE: This product contains ethanol. In IARC published Monograph No. 44, entitled, "Alcohol Drinking", the carcinogenicity of ethanol was determined based on chronic exposure to ethanol through human consumption of alcoholic beverages. This is not an expected effect during the foreseeable use of this product. Ingredient C.A.S. No. Class Description Regulation ETHYL ALCOHOL 64-17-5 Group 1 International Agency for Research on Cancer

Environmental effects

A 3M Product Environmental Data Sheet (PED) is available. This product is a disinfectant; it is toxic to microorganisms. Care must be taken to avoid improper disposal or release to the environment. When properly handled, use of this product is expected to have minimal environmental impact. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water for at least 15 minutes. Get immediate medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get immediate medical attention. 4.2 NOTE TO PHYSICIANS Probable mucosal damage may contraindicate the use of gastric lavage. Measures against circulatory shock, respiratory depression, and convulsion may be needed. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Flash Point Approximately 133 ºF [Test Method: Tagliabue Closed Cup]

Storage

Store away from acids. Store away from heat. Store out of direct sunlight. Keep container in well-ventilated area. Store away from oxidizing agents. Do not store containers on their sides. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use with appropriate local exhaust ventilation. NOTE: When used as directed and diluted and dispensed with a TWIST 'n FILL(TM) Chemical Dispenser, special ventilation is not required. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. NOTE: When used as directed and diluted and dispensed with a TWIST 'n FILL(TM) Chemical Dispenser, eye contact with the concentrate is not expected to occur. If the product is not used with the Twist 'n Fill system or if there is an accidental release, the following eye protection is recommended: Indirect Vented Goggles, Full Face Shield. 8.2.2 Skin Protection Avoid skin contact. NOTE: When used as directed and diluted and dispensed with a TWIST 'n FILL(TM) Chemical Dispenser, skin contact with the concentrate is not expected to occur. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. If the product is not used with the Twist 'n Fill system or if there is an accidental release, select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material is recommended: Butyl Rubber, Neoprene. The following protective clothing material(s) are recommended: Apron - Neoprene. 8.2.3 Respiratory Protection Avoid breathing of vapors, mists or spray. NOTE: When used as directed and diluted and dispensed with a TWIST 'n FILL(TM) Chemical Dispenser, respiratory protection is not required. If the product is not used with the Twist 'n Fill system or if there is an accidental release, select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with

Additional information

ETHYL ALCOHOL ACGIH TWA 1000 ppm Table A4 ETHYL ALCOHOL

TOXICOLOGICAL INFORMATION

Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. A 3M Product Environmental Data Sheet (PED) is available. Not determined. CHEMICAL FATE INFORMATION A 3M Product Environmental Data Sheet (PED) is available. Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility. EPA Hazardous Waste Number (RCRA): D001 (Ignitable), D002 (Corrosive) Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number UPC ID Number UPC 70-0711-6224-5 00-48011-23556-6 70-0711-6229-4 00-48011-23557-3 70-0711-6230-2 00-48011-23578-8 Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes FIFRA Status Registration Number Registered 61178-5-10350 STATE REGULATIONS CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. The components of this material are in compliance with the new chemical notification requirements for the Korean Existing Chemicals Inventory. The components of this product are listed on the Australian Inventory of Chemical Substances. All the components of this product are listed on China's Inventory of Chemical Substances. The components of this product are in compliance with notification requirements in the Philippines. The components of this product are listed on the Canadian Domestic Substances List. INTERNATIONAL REGULATIONS This MSDS has been prepared to meet the U.S.

Further information

NFPA Hazard Classification Health 3 Flammability 2 Reactivity 0 Special None Acid/Base Alkaline Corrosive Yes National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

HMIS® ratings

Health 3 Flammability 2 Reactivity 0 Protection X - See PPE section Hazardous Material Identification System (HMIS®) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint and Coatings Association (NPCA). Reason for Reissue: The MSDS has been revised because 3M has adopted the 16-section ANSI/ISO format. The potential hazards of the product have not changed. We encourage you to reread the MSDS and review the information. Revision Changes: Section 3: Potential effects from ingestion information was modified. Section 7: Handling information was modified. Section 7: Storage information was modified. Section 8: Skin protection phrase was modified. Section 4: First aid for ingestion (swallowing) - decontamination - was modified. Section 4: First aid for ingestion (swallowing) - medical assistance - was modified. Section 3: Immediate ingestion hazard(s) was added. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. 3M MSDSs are available at www.3M.com