3M(TM) ES-2000 Edge Sealer (Part A)

SECTION 2: Hazards identification

29 CFR 1910.1200) 3.1 EMERGENCY OVERVIEW Specific Physical Form: Paste Odor, Color, Grade: pale yellow, odorless General Physical Form: Liquid Immediate health, physical, and environmental hazards: Reacts violently with water. Hazardous polymerization may occur. May cause severe eye irritation. May cause allergic skin reaction. May cause allergic respiratory reaction.

Potential health effects

Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Skin Contact: Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Inhalation: Allergic Respiratory Reaction: Signs/symptoms may include difficulty breathing, wheezing, cough, and tightness of chest. Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting. Target Organ Effects: Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get immediate medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point 237 ºC [Test Method: SETAFLASH] Flammable Limits - LEL No Data Available Flammable Limits - UEL No Data Available 5.2 EXTINGUISHING MEDIA DO NOT USE WATER Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: No unusual fire or explosion hazards are anticipated. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. Pour isocyanate decontaminant solution (90% water, 8% concentrated ammonia, 2% detergent) on spill and allow to react for 10 minutes. Or pour water on spill and allow to react for more than 30 minutes. Cover with absorbent material. Place in a container approved for transportation by appropriate authorities, but do not seal the container for 48 hours to avoid pressure build-up. Cover or dilute with water. Collect as much of the spilled material as possible. Flush area thoroughly with water. Dispose of collected material as soon as possible. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Avoid contact with water to prevent potentially violent reaction or fire. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Contents may be under pressure, open carefully. Avoid breathing of vapors, mists or spray. For industrial or professional use only. Avoid contact with oxidizing agents. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits. If ventilation is not adequate, use respiratory protection equipment.

Storage

Store away from acids. Store away from heat. Store out of direct sunlight. Keep container in well-ventilated area. Store away from oxidizing agents. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use with appropriate local exhaust ventilation. Do not use in a confined area or areas with little or no air movement. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact. Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Indirect Vented Goggles. 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Polyvinyl Alcohol (PVA). 8.2.3 Respiratory Protection Avoid breathing of vapors, mists or spray. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with

Additional information

FREE ISOCYANATES 3M TWA 0.005 ppm FREE ISOCYANATES 3M STEL 0.02 ppm HEXAMETHYLENE DIISOCYANATE ACGIH TWA 0.005 ppm HEXAMETHYLENE DIISOCYANATE CMRG TWA 0.5 mg/m3 POLYMER HEXAMETHYLENE DIISOCYANATE CMRG STEL 1 mg/m3 POLYMER SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline

TOXICOLOGICAL INFORMATION

Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Dispose of completely cured (or polymerized) wastes in a sanitary landfill. Incinerate uncured product in a permitted hazardous waste incinerator in the presence of a combustible material. EPA Hazardous Waste Number (RCRA): D003 (Reactive) Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - Yes Immediate Hazard - Yes Delayed Hazard - No STATE REGULATIONS Contact 3M for more information. CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information.

Further information

NFPA Hazard Classification Health 2 Flammability 1 Reactivity 1 Special Reacts with Water National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Revision Changes: Section 1: Product name was modified. Section 1: Division name was modified. Page Heading: Product name was modified. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 3M(TM) ES-2000 Edge Sealer, Part B MANUFACTURER: 3M DIVISION: Aerospace Aircraft Maintenance Division ADDRESS: 3M Center St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours) Issue date 09/24/2007 Supercedes Date: 08/13/2002 Document Group: 18-1571-1 Product Use: Intended Use: Edge Sealer for Applique SECTION 2: INGREDIENTS Ingredient C.A.S. No. % by Wt POLYESTER RESIN (NJ TS RN 31765300002-5730P) Trade Secret 40 - 70 POLYESTER POLYOL 37625-56-2 10 - 30 POLYESTER 27925-07-1 5 - 10 POLYESTER DIOL 31831-53-5 5 - 10 AMINE STABILIZER 41556-26-7 0.1 - 1 AMINE STABILIZER 82919-37-7 0.1 - 1 SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW Specific Physical Form: Viscous Odor, Color, Grade: CLEAR General Physical Form: Liquid Immediate health, physical, and environmental hazards: May cause allergic skin reaction. May cause target organ effects. 3.2 POTENTIAL HEALTH EFFECTS Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin Contact: Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching. Inhalation: Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting.