3M(TM) DOSE "n FILL CLEANING SYSTEM, ALL PURPOSE CLEANER &

SECTION 2: Hazards identification

29 CFR 1910.1200) 3.1 EMERGENCY OVERVIEW Specific Physical Form: Liquid Odor, Color, Grade: Clear, red concentrate with slight clean and fresh odor. General Physical Form: Liquid Immediate health, physical, and environmental hazards: May cause allergic skin reaction. May cause target organ effects.

Potential health effects

Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin Contact: Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Flash Point > 200 ºF [Test Method: Closed Cup]

Storage

Store away from acids. Keep container tightly closed. Store away from oxidizing agents. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use with appropriate local exhaust ventilation. NOTE: When used as directed and diluted and dispensed with a DOSE 'n FILL(TM) Chemical Dispenser, special ventilation is not required. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. NOTE: When used as directed and diluted and dispensed with a DOSE 'n FILL(TM) Chemical Dispenser, eye contact with the concentrate is not expected to occur. If the product is not used with the Dose 'n Fill system or if there is an accidental release, the following eye protection is recommended: Safety Glasses with side shields, Indirect Vented Goggles. 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. NOTE: When used as directed and diluted and dispensed with a DOSE 'n FILL(TM) Chemical Dispenser, skin contact with the concentrate is not expected to occur. If the product is not used with the Dose 'n Fill system or if there is an accidental release, select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material is recommended: Butyl Rubber 8.2.3 Respiratory Protection Avoid breathing of vapors, mists or spray. NOTE: When used as directed and diluted and dispensed with a DOSE 'n FILL(TM) Chemical Dispenser, respiratory protection is not required. If the product is not used with the Dose 'n Fill system or if there is an accidental release, select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with

Additional information

ISOPROPYL ALCOHOL ACGIH TWA 200 ppm Table A4 ISOPROPYL ALCOHOL ACGIH STEL 400 ppm Table A4 ISOPROPYL ALCOHOL

TOXICOLOGICAL INFORMATION

Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Incinerate in an industrial or commercial facility in the presence of a combustible material. As a disposal alternative, dispose of waste product in a facility permitted to accept chemical waste. EPA Hazardous Waste Number (RCRA): Not regulated Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number UPC ID Number UPC 70-0711-9717-5 00-48011-54110-0 Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372

Further information

NFPA Hazard Classification Health 2 Flammability 1 Reactivity 0 Special None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

HMIS® ratings

Health 2 Flammability 1 Reactivity 0 Protection X - See PPE section Hazardous Material Identification System (HMIS®) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint and Coatings Association (NPCA). Reason for Reissue: The MSDS has been revised because 3M has adopted the 16-section ANSI/ISO format. The potential hazards of the product have not changed. We encourage you to reread the MSDS and review the information. Revision Changes: Section 1: Product name was modified. Section 7: Handling information was modified. Section 7: Storage information was modified. Section 8: Skin protection phrase was modified. Section 14: ID Number(s) and/or UPC(s) was modified. Page Heading: Product name was modified. Section 16: Reason for reissue heading was added. Section 16: Reason for reissue phrase was added. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. 3M MSDSs are available at www.3M.com SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 3M(TM) DOSE 'n FILL CLEANING SYSTEM, ALL PURPOSE CLEANER & DEGREASER (Ready-to-Use) MANUFACTURER: 3M DIVISION: Commercial Care Division ADDRESS: 3M Center St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours) Issue date 10/20/2005 Supercedes Date: 08/10/2005 Document Group: 18-9289-2 SECTION 2: INGREDIENTS Ingredient C.A.S. No. % by Wt WATER 7732-18-5 > 99 POLYETHOXYLATED ALCOHOL - NJTSN #027586004-8002 Trade Secret < 1 2-AMINOISOBUTANOL 124-68-5 < 0.5 ETHYLENE GLYCOL ETHYLHEXYL ETHER 1559-35-9 < 0.1 TRIMETHYL OCTADECYL AMMONIUM CHLORIDE 112-03-8 < 0.05 D-LIMONENE 5989-27-5 < 0.01 SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW Specific Physical Form: Liquid Odor, Color, Grade: Clear, pink with mild clean and fresh fragrance. General Physical Form: Liquid Immediate health, physical, and environmental hazards: DEGREASER (Ready-to-Use) 10/20/2005 3.2 POTENTIAL HEALTH EFFECTS Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching. Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. 3.3 POTENTIAL ENVIRONMENTAL EFFECTS A 3M Product Environmental Data Sheet (PED) is available.