General Information
Revision date
2009-09-21
Product name
3M Super Weatherstrip and Gasket Adhesive - Black, P.N. 08008
Product Synonyms
METHYL ETHYL KETONE
CAS No.
9010-98-4
Manufacturer Name
3M
Emergency telephone
1-800-364-3577 or (651) 737-6501 (24 hours
Icons in SDS
Company Information
company name
3M
Section 2
SECTION 2: Hazards identification
29 CFR 1910.1200) 3.1 EMERGENCY OVERVIEW Odor, Color, Grade: Black. Solvent odor. General Physical Form: Liquid Immediate health, physical, and environmental hazards: Flammable liquid and vapor. Closed containers exposed to heat from fire may build pressure and explode. Dust clouds of this material in combination with an ignition source may be explosive. Vapors may travel long distances along the ground or floor to an ignition source and flash back. May cause allergic skin reaction. Contains a chemical or chemicals which can cause cancer. May cause target organ effects. Contains a chemical or chemicals which can cause birth defects or other reproductive harm.
Potential health effects
Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin Contact: Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Intentional concentration and inhalation may be harmful or fatal. Prolonged or repeated exposure may cause: Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate, bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Prolonged or repeated exposure may cause: Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Peripheral Neuropathy: Signs/symptoms may include tingling or numbness of the extremities, incoordination, weakness of the hands and feet, tremors and muscle atrophy. Ocular Effects: Signs/symptoms may include blurred or significantly impaired vision. Olfactory Effects: Signs/symptoms may include decreased ability to detect odors and/or complete loss of smell. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient C.A.S. No. Class Description Regulation CARBON BLACK 1333-86-4 Group 2B International Agency for Research on Cancer ETHYLBENZENE 100-41-4 Group 2B International Agency for Research on Cancer SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point -6.00 ºF [Test Method: Tagliabue Closed Cup] Flammable Limits - LEL 1.00 % volume Flammable Limits - UEL 11.50 % volume
Storage
Store away from acids. Store away from heat. Store out of direct sunlight. Keep container in well-ventilated area. Keep container tightly closed. Store away from oxidizing agents. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use with appropriate local exhaust ventilation. Provide appropriate local exhaust ventilation on open containers. Use in an enclosed process area is recommended. Do not use in a confined area or areas with little or no air movement. Provide ventilation adequate to maintain dust concentration below minimum explosive concentrations. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact. The following eye protection(s) are recommended: Safety Glasses with side shields, Indirect Vented Goggles. 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Fluoroelastomer (Viton), Nitrile Rubber, Polyvinyl Alcohol (PVA). 8.2.3 Respiratory Protection Do not breathe vapors. Consult the current 3M Respirator Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with
Additional information
CARBON BLACK ACGIH TWA 3.5 mg/m3 Table A4 CARBON BLACK CMRG TWA 0.5 mg/m3 CARBON BLACK
TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Dispose of waste product in a permitted hazardous waste facility. EPA Hazardous Waste Number (RCRA): D001 (Ignitable), D006 (Cadmium), D009 (Mercury), D010 (Selenium), D018 (Benzene), D035 (Methyl ethyl ketone) Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number(s): 41-3701-2175-2, 60-4550-2996-1, 60-9800-3122-7, LB-K000-1071-0 Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372
2.1 Classification of the substance or mixture
CARBON BLACK 1333-86-4 **Carcinogen ETHYLBENZENE 100-41-4 **Carcinogen TOLUENE 108-88-3 *Developmental Toxin * WARNING: contains a chemical or chemicals which can cause birth defects or other reproductive harm. ** WARNING: contains a chemical which can cause cancer. CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information.
Further information
NFPA Hazard Classification Health 2 Flammability 3 Reactivity 0 Special None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Revision Changes: Section 3: Potential effects from inhalation information was modified. Section 5: Unusual fire and explosion hazard information was modified. Section 7: Handling information was modified. Section 8: Respiratory protection information was modified. Section 3: Immediate other hazard(s) was modified. Section 3: Other health effects information was modified. Section 9: Property description for optional properties was modified. Section 2: Ingredient table was modified. Section 15: EPCRA 313 information was modified. Section 8: Exposure guidelines ingredient information was modified. Section 9: Property description for required properties was added. 10.1 Conditions to avoid was added. 10.2 Materials to avoid was added. Section 6: Release measures information was added. Section 10: Materials to avoid physical property was added. Section 10: Conditions to avoid physical property was added. Section 6: Release measures information was deleted. Section 10: Materials and conditions to avoid physical property was deleted. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. 3M MSDSs are available at www.3M.com