3M Scotch-Weld Epoxy Adhesive DP-190, Translucent (Part B)

SECTION 2: Hazards identification

29 CFR 1910.1200) 3.1 EMERGENCY OVERVIEW Specific Physical Form: Viscous Liquid Odor, Color, Grade: Clear, slight epoxy odor General Physical Form: Liquid Immediate health, physical, and environmental hazards: May cause allergic skin reaction.

Potential health effects

Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Vapors released during curing may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Dust created by cutting, grinding, sanding, or machining may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin Contact: Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Prolonged or repeated exposure may cause: Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Inhalation: Vapors released during curing may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Dust from cutting, grinding, sanding or machining may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: If signs/symptoms develop, remove person to fresh air. If signs/symptoms persist, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point >=200 ºF [Test Method: Pensky-Martens Closed Cup] Flammable Limits - LEL No Data Available Flammable Limits - UEL No Data Available 5.2 EXTINGUISHING MEDIA Ordinary combustible material. Use fire extinguishers with class A extinguishing agents (e.g., water, foam). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Water may be used to blanket the fire. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: No unusual fire or explosion hazards are anticipated. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Collect the resulting residue containing solution. Place in a closed container approved for transportation by appropriate authorities. Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING For industrial or professional use only. Keep out of the reach of children. Avoid eye contact with vapors, mists, or spray. Avoid breathing of vapors, mists or spray. Avoid skin contact with hot material. Avoid breathing of dust created by cutting, sanding, grinding or machining. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep container closed when not in use. Contents may be under pressure, open carefully.

Storage

Store away from acids. Keep container tightly closed. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Provide appropriate local exhaust for cutting, grinding, sanding or machining. Provide appropriate local exhaust when product is heated. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Safety Glasses with side shields Indirect Vented Goggles . 8.2.2 Skin Protection Avoid skin contact. Avoid skin contact with hot material. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Neoprene Nitrile Rubber Polyethylene/Ethylene Vinyl Alcohol . 8.2.3 Respiratory Protection Avoid breathing of dust created by cutting, sanding, grinding or machining. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with

TOXICOLOGICAL INFORMATION

Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Cure (harden, set, or react) the product according to product instructions. As a disposal alternative, incinerate in an industrial or commercial facility. Dispose of waste product in a facility permitted to accept chemical waste. Dispose of completely cured (or polymerized) wastes in a sanitary landfill. Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No STATE REGULATIONS Contact 3M for more information. CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. Contact 3M for more information.

Additional information

This Base to be used with Scotch-Weld DP-190 Part A Translucent Epoxy Adhesive INTERNATIONAL REGULATIONS Contact 3M for more information. This MSDS has been prepared to meet the U.S.

Further information

NFPA Hazard Classification Health 2 Flammability 1 Reactivity 0 Special None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Revision Changes: Section 1: Product name was modified. Copyright was modified. Section 8: Skin protection phrase was modified. Section 13: Waste disposal method information was modified. Section 8: Eye/face protection information was modified. Section 8: Skin protection - recommended gloves information was modified. Section 8: Respiratory protection - recommended respirators information was modified. Page Heading: Product name was modified. Section 9: Property description for optional properties was modified. Section 9: Specific gravity information was modified. Section 9: Vapor pressure text was added. Section 10.1 Conditions to avoid heading was added. Section 10.2 Materials to avoid heading was added. Section 6: Personal precautions information was added. Section 6: Environmental procedures information was added. Section 6: Methods for cleaning up information was added. Section 10: Materials to avoid physical property was added. Section 10: Conditions to avoid physical property was added. Section 6: Release measures information was deleted. Section 8: Skin protection - protective clothing recommendations was deleted. Section 8: Skin protection - protective clothing information was deleted. Section 10: Materials and conditions to avoid physical property was deleted. Section 9: Vapor pressure value was deleted. Section 8: Skin protection - protective clothing - punctuation was deleted. Section 14: ID Number(s) Template 1 was deleted. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: Scotch-Weld(TM) Epoxy Adhesive DP-190, Translucent (Part A) MANUFACTURER: 3M DIVISION: Industrial Adhesives and Tapes Division ADDRESS: 3M Center St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours) Issue date 04/23/10 Supercedes Date: 02/18/09 Document Group: 05-6839-4 Product Use: Intended Use: Adhesive Specific Use: Part A of 2-Component Epoxy Adhesive SECTION 2: INGREDIENTS Ingredient C.A.S. No. % by Wt ALIPHATIC POLYMER DIAMINE 68911-25-1 70 - 90 4,7,10-TRIOXATRIDECANE-1,13-DIAMINE 4246-51-9 10 - 30 CALCIUM SALT 55120-75-7 1 - 5 TOLUENE 108-88-3 <= 0.98 SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW Specific Physical Form: Viscous Liquid Odor, Color, Grade: Light amber, slight amine odor General Physical Form: Liquid Immediate health, physical, and environmental hazards: May cause chemical eye burns. May cause allergic skin reaction. May cause severe skin irritation. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. 3.2 POTENTIAL HEALTH EFFECTS Eye Contact: Corrosive (Eye Burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing, ulcerations, significantly impaired vision or complete loss of vision. Vapors released during curing may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Dust created by cutting, grinding, sanding, or machining may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin Contact: Severe Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Dust from cutting, grinding, sanding or machining may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Contains a chemical or chemicals which can cause birth defects or other reproductive harm.