3M Polyurethane Foam Insulation Adhesive CR-20, Part A

SECTION 2: Hazards identification

GHS Classification FiberTite® FTR-601A Adhesive, Part A

2.1 Classification of the substance or mixture

Acute Toxicity (inhalation): Category 4. Serious Eye Damage/Irritation: Category 2A. Rev. Date 23 Dec 2014 Skin Corrosion/Irritation: Category 2. PRODUCT & COMPANY INFORMATION PRODUCT & COMPANY INFORMATION Respiratory Sensitizer: Category 1. Product Name: Skin Sensitizer: Category 1. FTR-601A Adhesive, Part A Product Name: FTR-601A Adhesive, Part A Specific Target Organ Toxicity (single exposure): Category 2. Specific Target Organ Toxicity (respiratory irritation): Category 3. Recommended Use: Foamable adhesive Recommended Use: Foamable adhesive Specific Target Organ Toxicity (repeated exposure): Category 1. Manufacturer: SEAMAN CORPORATION PHONE: (330) 262-1111 May cause an allergic skin reaction. Acute Toxicity - Inhalation - Category 4 Harmful if inhaled. Acute Toxicity - Inhalation - Category 4 Skin Irritation – Category 2 May cause respiratory irritation. Skin Irritation – Category 2 Eye Irritation – Category 2A Respiratory Sensitization - Category 1 May cause damage to organs: Respiratory Sensitization - Category 1 Skin Sensitization - Category 1 cardiovascular system | Skin Sensitization - Category 1 Carcinogenicity - Category 2 Specific Target Organ Toxicity (Single Exposure) – Category 3 (Respiratory irritation) Causes damage to organs through prolonged or repeated exposure: Specific Target Organ Toxicity (Single Exposure) – Category 3 (Respiratory irritation) Specific Target Organ Toxicity (Repeated Exposure) – Category 2 respiratory system | Specific Target Organ Toxicity (Repeated Exposure) – Category 2

2.2 Label elements

Manufacturer SEAMAN CORPORATION PHONE: (330) 262-1111 1000 Venture Blvd. INTERNET: www.seamancorp.com

Signal word

INTERNET: www.seamancorp.com Wooster, OH 44691 USA Danger 3M™ Polyurethane Foam Insulation Adhesive CR-20, Part A Wooster, OH 44691 USA 24-HR EMERGENCY: (800) 424-9300 (Chemtrec) 08/21/15 24-HR EMERGENCY: (800) 424-9300 (Chemtrec) DANGER Causes skin irritation. DANGER Jump Back To Index May cause allergy or asthma symptoms or breathing difficulties if inhaled. Page 58

Hazard pictograms

Exclamation mark | Health Hazard | __________________________________________________________________________________________ __________________________________________________________________________________________ Page 1 of 12 Foam Insulation Adhesive Notebook

Hazard statements

Causes serious eye irritation. Harmful if inhaled Causes skin irritation Causes serious eye irritation. Causes skin irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Harmful if inhaled. May cause respiratory irritation. Section IX - Physical and Chemical Properties Odor, Color, Grade: Light brown color, slight musty odor General Physical Form: May cause damage to organs: Gas Autoignition Temperature cardiovascular system | >=600 ºF Flash Point >=200 ºF Flammable Limits - LEL Causes damage to organs through prolonged or repeated exposure: No Data Available Flammable Limits - UEL respiratory system | No Data Available Boiling point <=0 ºF Density 1.23 g/ml Vapor Density

Prevention

Causes skin irritation Causes serious eye irritation Do not breathe dust/fume/gas/mist/vapors/spray. Causes serious eye irritation May cause allergy or asthma symptoms or breathing difficulties if inhaled Use only outdoors or in a well-ventilated area. May cause allergy or asthma symptoms or breathing difficulties if inhaled May cause an allergic skin reaction In case of inadequate ventilation wear respiratory protection. Suspected of causing cancer May cause respiratory irritation Wear protective gloves and eye/face protection. May cause respiratory irritation May cause damage to organs (respiratory system, eyes, skin) through prolonged or repeated exposure Do not eat, drink or smoke when using this product. May cause damage to organs (respiratory system, eyes, skin) through prolonged or repeated exposure Wash thoroughly after handling. 1.23 [Ref Std: WATER=1] pH Do not breathe dust/fume/gas/mist/vapors/spray. No Data Available Melting Point Use only outdoors or in a well-ventilated area. No Data Available Solubility in Water In case of inadequate ventilation wear respiratory protection. Nil VOC Less H2O & Exempt Solvents Wear protective gloves and eye/face protection. 0 g/l Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Section X - Stability and Reactivity Contaminated work clothing must not be allowed out of the workplace. Stability: Stable.

Precautionary statements

Contaminated work clothing must not be allowed out of the workplace. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. 3.6 [Ref Std: AIR=1] Vapor Pressure 85.7 psi Specific Gravity

Response

Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapors/spray. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Do not breathe dust/fume/gas/mist/vapors/spray. Wash face, hands and any exposed skin thoroughly after handling. If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. Wash face, hands and any exposed skin thoroughly after handling. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Page 1 of 5 If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. IF exposed or concerned: Call a POISON CENTER or doctor/physician. Specific treatment (see Notes to Physician on this label). Materials and Conditions to Avoid: Heat; Sparks and/or flames IF INHALED: Remove person to fresh air and keep comfortable for breathing. Hazardous Polymerization: Hazardous polymerization will not occur. If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Hazardous Decomposition or By-Products Continue rinsing. Substance Condition If eye irritation persists: Get medical advice/attention. Carbon monoxide During Combustion Carbon dioxide During Combustion IF ON SKIN: Wash with plenty of soap and water. Hydrogen Cyanide During Combustion If skin irritation or rash occurs: Get medical advice/attention. Oxides of Nitrogen During Combustion Take off contaminated clothing and wash it before reuse. IF exposed or concerned: Call a POISON CENTER or doctor/physician. Specific treatment (see Notes to Physician on this label). Section XI - Toxicological Information Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or

Storage

Store in a well-ventilated place. Keep container tightly closed. Store locked up. its components. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Section XII - Ecological Information

Disposal

Dispose of contents/container in accordance with applicable local/regional/national/international regulations. Notes to Physician: Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. 3M™ Polyurethane Foam Insulation Adhesive CR-20, Part A 08/21/15 FiberTite® FTR-CR20 Exclamation mark | Health Hazard |

TOXICOLOGICAL INFORMATION

Dispose of contents/container in accordance with applicable local/regional/national/international regulations. Not determined. CHEMICAL FATE INFORMATION Notes to Physician: Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. Not determined. 3M™ Polyurethane Foam Insulation Adhesive CR-20, Part A 08/21/15 Section XIII - Disposal Considerations __________________________________________________________________________________________

2.3 Other hazards

Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator in the presence of a combustible Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates. material. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility.The facility should be Page 2 of 12 equipped to handle gaseous waste. 10% of the mixture consists of ingredients of unknown acute inhalation toxicity. EPA Hazardous Waste Number (RCRA): D003 (Reactive) Since regulations vary, consult applicable regulations or authorities before disposal.