3M Panel Bonding Adhesive PN 38315, 58115 - Part A

SECTION 2: Hazards identification

29 CFR 1910.1200) 3.1 EMERGENCY OVERVIEW Specific Physical Form: Viscous liquid Odor, Color, Grade: Tan liquid, slight amine odor. General Physical Form: Liquid Immediate health, physical, and environmental hazards: May cause chemical eye burns. May cause allergic skin reaction. May cause chemical skin burns. May cause chemical gastrointestinal burns. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Contains a chemical or chemicals which can cause cancer.

Potential health effects

Eye Contact: Corrosive (Eye Burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing, ulcerations, significantly impaired vision or complete loss of vision. Skin Contact: Corrosive (Skin Burns): Signs/symptoms may include localized redness, swelling, itching, intense pain, blistering, ulceration, and tissue destruction. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Ingestion: Gastrointestinal Corrosion: Signs/symptoms may include severe mouth, throat and abdominal pain; nausea; vomiting; and diarrhea; blood in the feces and/or vomitus may also be seen. Target Organ Effects: Persons previously sensitized to amines may develop a cross-sensitization reaction to certain other amines. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient C.A.S. No. Class Description Regulation QUARTZ SILICA 14808-60-7 Grp. 1: Carcinogenic to International Agency for Research on Cancer humans QUARTZ SILICA 14808-60-7 Known human carcinogen National Toxicology Program Carcinogens SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water for at least 15 minutes. Get immediate medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get immediate medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point 110 ºC [Test Method: Closed Cup] Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available

Storage

Store away from acids. Store away from heat. Store out of direct sunlight. Keep container in well-ventilated area. Store away from oxidizing agents. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use with appropriate local exhaust ventilation. Provide appropriate local exhaust for cutting, grinding, sanding or machining. Use in a well-ventilated area. If exhaust ventilation is not available, use appropriate respiratory protection. For additional health and precautionary information, including air monitoring methodology, contact 3M. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. Avoid eye contact. The following eye protection(s) are recommended: Safety Glasses with side shields Indirect Vented Goggles . 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Polyethylene/Ethylene Vinyl Alcohol . 8.2.3 Respiratory Protection Avoid breathing of vapors, mists or spray. Avoid breathing of vapors. Avoid breathing of dust created by cutting, sanding, grinding or machining. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with

Additional information

DIMETHYL SILOXANE, REACTION CMRG CEIL 5 mg/m3 PRODUCT WITH SILICA QUARTZ SILICA ACGIH TWA, respirable 0.025 mg/m3 fraction QUARTZ SILICA

TOXICOLOGICAL INFORMATION

Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Incinerate uncured product in a permitted hazardous waste incinerator in the presence of a combustible material. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility. EPA Hazardous Waste Number (RCRA): D018 (Benzene) Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes STATE REGULATIONS Contact 3M for more information.

2.1 Classification of the substance or mixture

SILICA, CRYSTALLINE (AIRBORNE SEQ677 **Carcinogen PARTICLES OF RESPIRABLE SIZE) TOLUENE 108-88-3 *Developmental Toxin * WARNING: contains a chemical or chemicals which can cause birth defects or other reproductive harm. ** WARNING: contains a chemical which can cause cancer. CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. The components of this product are listed on the Canadian Domestic Substances List. The components of this product are listed on the Australian Inventory of Chemical Substances. All the components of this product are listed on China's Inventory of Chemical Substances. Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information.

Further information

NFPA Hazard Classification Health 3 Flammability 1 Reactivity 0 Special None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Revision Changes: Section 1: Product name was modified. Page Heading: Product name was modified. Section 15: Inventories information was modified. Section 9: Vapor pressure value was modified. Section 9: Boiling point information was modified. Section 5: Flammable limits (UE) information was modified. Section 5: Flammable limits (LEL) information was modified. Section 9: Property description for optional properties was modified. Section 1: Initial issue message was modified. Section 9: Flammable limits (LEL) information was modified. Section 9: Flammable limits (UEL) information was modified. Section 6: 6.2. Environmental precautions heading was modified. Section 6: 6.1. Personal precautions, protective equipment and emergency procedures heading was modified. Section 9: Density information was added. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 3M™ Panel Bonding Adhesive PN 38315, 58115 - Part B MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours) Issue date 12/28/10 Supercedes Date: 08/04/10 Document Group: 28-6996-4 Product Use: Intended Use: Automotive Specific Use: Panel Repair SECTION 2: INGREDIENTS Ingredient C.A.S. No. % by Wt 4,4'-ISOPROPYLIDENEDIPHENOL-EPICHLOROHYDRIN POLYMER 25068-38-6 30 - 60 GLASS BEADS 65997-17-3 10 - 30 FUSED SILICA 60676-86-0 7 - 13 1,4-BIS[(2,3-EPOXYPROPOXY)METHYL]CYCLOHEXANE 14228-73-0 7 - 13 METHYL METHACRYLATE-BUTADIENE-STYRENE POLYMER 25053-09-2 5 - 10 SILICA 7631-86-9 1 - 5 DIMETHYL SILOXANE, REACTION PRODUCT WITH SILICA 67762-90-7 0.5 - 1.5 3-(TRIMETHOXYSILYL)PROPYL GLYCIDYL ETHER 2530-83-8 0.5 - 1.5 CARBON BLACK 1333-86-4 <= 0.47 2,6-DI-TERT-BUTYL-P-CRESOL 128-37-0 <= 0.1786 QUARTZ SILICA 14808-60-7 <= 0.01 SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW Specific Physical Form: Viscous Odor, Color, Grade: Black, Viscous liquid. General Physical Form: Liquid Immediate health, physical, and environmental hazards: May cause allergic skin reaction. Contains a chemical or chemicals which can cause cancer. May cause target organ effects. 3.2 POTENTIAL HEALTH EFFECTS Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin Contact: Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient C.A.S. No. Class Description Regulation CARBON BLACK 1333-86-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer QUARTZ SILICA 14808-60-7 Grp. 1: Carcinogenic to International Agency for Research on Cancer humans QUARTZ SILICA 14808-60-7 Known human carcinogen National Toxicology Program Carcinogens