3M"" General Purpose Adhesive Cleaner PN 08987

SECTION 2: Hazards identification

29 CFR 1910.1200) 3.1 EMERGENCY OVERVIEW Specific Physical Form: Aerosol Odor, Color, Grade: Clear spray with solvent odor General Physical Form: Liquid Immediate health, physical, and environmental hazards: Extremely flammable liquid and vapor. Aerosol container contains flammable material under pressure. Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel Page 1 of 10 A-5 F"729 03/01111 long distances along the ground or floor to an ignition source and flash back. May cause target organ effects. Contains a chemical or chemicals which can cause birth defects or other reproductive hann. Contains a chemical or chemicals which can cause cancer.

Potential health effects

Eye Contact: Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing. Skin Contact: Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Inhalation: Intentional concentration and inhalation may be harmful or fatal. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Single exposure, above recommended guidelines, may cause: Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be fatal. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Chemical (Aspiration) Pneumonitis: Signs/symptoms may include coughing, gasping, choking, burning of the mouth, difficulty breathing, bluish colored skin (cyanosis), and may be fatal. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness. and unconsciousness. Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Prolonged or repeated exposure may cause: Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Page 2 of 10 R 6 F 730 0.1/01/ 11 Contains a chemical or chemicals wruch can cause birth defects or other reproductive hann. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Jngredient C.A.S. No. Class Description Regulation BENZENE 71-43-2 Grp. 1: Carcinogenic to International Agency for Research on Cancer humans BENZENE 71-43-2 Known human carcinogen National Toxicology Program Carcinogens BENZENE 71-43-2 Cancer hazard

Storage

Store away from acids. Store away from heat. Store out of direct sunlight. Keep container in well-ventilated area. Keep container tightly closed. Do not store containers on their sides. Store away from oxidizing agents. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Page 4 of 10 R 8 F 732 03/01111 8.1 ENGINEERING CONTROLS Provide appropriate local exhaust ventilation on open containers. If exhaust ventilation is not available, use appropriate respiratory protection. Do not use in a confined area or arcas with little or no air movement. Do not remain in area where available oxygen may be reduced. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. Ifventilation is DOt adequate, use respiratory protection equipment. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection A void eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Safety Glasses with side shields Indirect Vented Goggles 8.2.2 Skin Protection A void skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Fluoroelastomer Polymer laminate 8.2.3 Respiratory Protection Avoid breathing of vapors, mists or spray. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with

Additional information

BENZENE ACGIH TWA 0.5 ppm Skin Notation* BENZENE ACGIH STEL 2.5 ppm Skin Notation* BENZENE

TOXICOLOGICAL INFORMATION

Please contact the address listed on the first page of the MSDS for Toxicologicallnfonnation on this material and/or its components. Not detennined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Incinerate in a pennitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility. Facility must be capable of handling aerosol cans. Dispose of empty product containers in a sanitary landfill. EPA Hazardons Waste Number (ReRA): DOOI (Ignitable), DOl8 (Benzene) I Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number(s): 60-4550-3068-8, 60-4550-4585-0, 60-9800-2679-7 Page 7 of 10 R.ll F:735 03/01111 I For Transport Information, please visit http://3M.comlTransportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 3111312 Hazard Categories: Fire Hazard - Ves Pressure Hazard - Ves Reactivity Hazard - No Immediate Hazard - Ves Delayed Hazard - Ves Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372

2.1 Classification of the substance or mixture

BENZENE 7 1-43-2 "'Male reproductive toxin BENZENE 71-43-2 '" ·Carcinogen BENZENE 71-43·2 *DevelopmentaI Toxin ETHYLBENZENE 100-41-4 *"'Carcinogen TOLUENE 108·88·3 *Female reproductive toxin TOLUENE 108-88-3 *Developmental Toxin * WARNING: contains a chemical or chemicals which can cause birth defects or other reproductive harm. ** WARNING: contains a chemical which can cause cancer. CHEMICAL INVENTORIES The components ofthis product are in compliance with the chemical notification requirements ofTSCA. All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. Contact 3M for more information. Page 8 of 10 A 12 F 736 03101111 INTERNATIONAL REGULATIONS Contact 3M for more information.

Further information

NFPA Hazard Classification Health: 2 Flammability: 4 Reactivity 0 Special None Aerosol Storage Code: 3 National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response persorUlel to address the hazards that are presented by short-tenn, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

HMIS® ratings

Health: 2 Flammability: 4 Reactivity: 0 Protection: X - See PPE section. Hazardous Material Identification System (HMIS(r» hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions ofnonnal use and are not intended for use in emergency situations. HMJS(r) ratings are to be used with a fully implemented HMIS(r) program. HM1S(r) is a registered mark of the National Paint and Coatings Association (NPCA). Revision Changes: Copyright was modified. Section 3: Potential effects from eye contact was modified. Section 3: Potential effects from inhalation infonnation was modified. Section 8: Eye/face protection information was modified. Section 8: Skin protection - recommended gloves inforrnation was modified. Section 8: Respiratory protection - recommended respirators infonnation was modified. Section 14: Transportation legal text was modified. Section 3: Other health effects information was modified. Section 15: Inventories infonnation was modified. Section 9: Density information was modified.