3M Bathroom & Shower Cleaner Concentrate (Product No. 51, Twist "n Fill System)

SECTION 2: Hazards identification

29 CFR 1910.1200) 3.1 EMERGENCY OVERVIEW Specific Physical Form: Liquid Odor, Color, Grade: Clear, yellow liquid with pungent odor of hydrochloric acid General Physical Form: Liquid Immediate health, physical, and environmental hazards: May cause chemical eye burns. May cause chemical skin burns. May cause chemical gastrointestinal burns. May cause chemical respiratory tract burns.

Potential health effects

Eye Contact: Corrosive (Eye Burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing, ulcerations, significantly impaired vision or complete loss of vision. Skin Contact: Corrosive (Skin Burns): Signs/symptoms may include localized redness, swelling, itching, intense pain, blistering, ulceration, and tissue destruction. Inhalation: May be harmful if inhaled. Respiratory Tract Corrosion: Signs/symptoms may include nasal discharge, severe nose and throat pain, chest tightness and pain, coughing up blood, wheezing, and breathlessness, possibly progressing to respiratory failure. Ingestion: May be harmful if swallowed. Gastrointestinal Corrosion: Signs/symptoms may include severe mouth, throat and abdominal pain; nausea; vomiting; and diarrhea; blood in the feces and/or vomitus may also be seen.

Environmental effects

A 3M Product Environmental Data Sheet (PED) is available. A conservative assessment indicates this product presents a low

Environmental hazards

Components released to the environment through use and disposal are expected to have insignificant environmental impacts. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water for at least 15 minutes. Get immediate medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. Get immediate medical attention. If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get immediate medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature Not Applicable Flash Point No flash point Flammable Limits(LEL) Not Applicable Flammable Limits(UEL) Not Applicable

Storage

Keep container in well-ventilated area. Store away from areas where product may come into contact with food or pharmaceuticals. Store away from oxidizing agents. Store away from strong bases. Store away from strong bases. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use in a well-ventilated area. NOTE: When used as directed and diluted and dispensed with a TWIST 'n FILL(TM) Chemical Dispenser, special ventilation is not required. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Do not get in eyes. NOTE: When used as directed and diluted and dispensed with a TWIST 'n FILL(TM) Chemical Dispenser, eye contact with the concentrate is not expected to occur. If the product is not used with the Twist 'n Fill system or if there is an accidental release, the following eye protection is recommended: Full Face Shield, Indirect Vented Goggles. 8.2.2 Skin Protection Do not get on skin or on clothing. NOTE: When used as directed and diluted and dispensed with a TWIST 'n FILL(TM) Chemical Dispenser, skin contact with the concentrate is not expected to occur. If the product is not used with the Twist 'n Fill system or if there is an accidental release, select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material is recommended: Butyl Rubber, Neoprene. The following protective clothing material(s) are recommended: Apron - Neoprene; Boots - Neoprene. 8.2.3 Respiratory Protection Do not breathe vapors. NOTE: When used as directed and diluted and dispensed with a TWIST 'n FILL(TM) Chemical Dispenser, respiratory protection is not required. If the product is not used with the Twist 'n Fill system or if there is an accidental release, select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with

Additional information

HYDROCHLORIC ACID ACGIH CEIL 2 ppm HYDROCHLORIC ACID

TOXICOLOGICAL INFORMATION

Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. A 3M Product Environmental Data Sheet (PED) is available. CHEMICAL FATE INFORMATION A 3M Product Environmental Data Sheet (PED) is available. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Dispose of waste product in a permitted hazardous waste facility. EPA Hazardous Waste Number (RCRA): D002 (Corrosive) Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number UPC ID Number UPC 70-0710-0730-9 00-48011-26320-0 70-0710-0947-9 00-48011-26321-7 70-0716-5771-5 00-48011-26320-5 70-0716-5772-3 00-48011-26321-2 For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372

Further information

NFPA Hazard Classification Health 3 Flammability 0 Reactivity 0 Special None Corrosive: Yes National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

HMIS® ratings

Health 3 Flammability 0 Reactivity 0 Protection X - See PPE section Hazardous Material Identification System (HMIS®) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint and Coatings Association (NPCA). Revision Changes: Section 3: Potential effects from inhalation information information was modified. Section 7: Storage information information was modified. Section 14: ID Number(s) and/or UPC(s) Template 1 information was modified. Section 6: Environmental procedures information information was modified. Copyright information was modified. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. 3M USA MSDSs are available at www.3M.com