04747 Duramix(TM) Super Fast Adhesive, (10 Seconds) Part A

SECTION 2: Hazards identification

29 CFR 1910.1200) 3.1 EMERGENCY OVERVIEW Specific Physical Form: Viscous Odor, Color, Grade: Low or no detectable odor, clear. General Physical Form: Liquid Immediate health, physical, and environmental hazards: May cause severe eye irritation. May cause severe skin irritation. May cause allergic skin reaction. May cause allergic respiratory reaction. May cause target organ effects.

Potential health effects

Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Skin Contact: Severe Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Inhalation: May be harmful or fatal if inhaled. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Allergic Respiratory Reaction: Signs/symptoms may include difficulty breathing, wheezing, cough, and tightness of chest. Prolonged or repeated exposure may cause: Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate, bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Target Organ Effects: Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature Not Applicable Flash Point >=290 ºF [Test Method: Tagliabue Closed Cup] Flammable Limits - LEL Not Applicable Flammable Limits - UEL Not Applicable

Storage

Store away from acids. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use with appropriate local exhaust ventilation. Provide appropriate local exhaust for cutting, grinding, sanding or machining. Do not use in a confined area or areas with little or no air movement. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Indirect Vented Goggles. 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Butyl Rubber, Nitrile Rubber. 8.2.3 Respiratory Protection Avoid breathing of dust created by cutting, sanding, grinding or machining. Do not breathe vapors. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with

Additional information

3-(TRIMETHOXYSILYL)PROPYL CMRG TWA 5 ppm GLYCIDYL ETHER FREE ISOCYANATES 3M TWA 0.005 ppm FREE ISOCYANATES 3M STEL 0.02 ppm MERCURY, INORGANIC COMPOUNDS ACGIH TWA, as Hg 0.025 mg/m3 Skin Notation*; Table A4 4,4'-DIPHENYLMETHANE ACGIH TWA 0.005 ppm DIISOCYANATE 4,4'-DIPHENYLMETHANE

TOXICOLOGICAL INFORMATION

Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Cure (harden, set, or react) the product according to product instructions. Dispose of completely cured (or polymerized) wastes in a sanitary landfill. As a disposal alternative, incinerate uncured product in an industrial or commercial incinerator in the presence of a combustible material. EPA Hazardous Waste Number (RCRA): Not regulated Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION Not regulated per U.S. DOT, IATA or IMO. These transportation classifications are provided as a customer service. As the shipper YOU remain responsible for complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M's transportation classifications are based on product formulation, packaging, 3M policies and 3M's understanding of applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information applies only to transportation classification and not the packaging, labeling, or marking requirements. The original 3M package is certified for U.S. ground shipment only. If you are shipping by air or ocean, the package may not meet applicable regulatory requirements. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372

Further information

NFPA Hazard Classification Health 3 Flammability 1 Reactivity 1 Special None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

HMIS® ratings

Health 2 Flammability 1 Reactivity 1 Protection X - See PPE section Hazardous Material Identification System (HMIS(r)) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS(r) ratings are to be used with a fully implemented HMIS(r) program. HMIS(r) is a registered mark of the National Paint and Coatings Association (NPCA). Revision Changes: Section 16: NFPA hazard classification for health was modified. Copyright was modified. Section 4: First aid for eye contact - decontamination - was modified. Section 4: First aid for eye contact - medical assistance - was modified. Section 3: Immediate skin hazard(s) was modified. Section 3: Potential effects from eye contact was modified. Section 3: Potential effects from skin contact information was modified. Section 3: Potential effects from inhalation information was modified. Section 3: Potential effects from ingestion information was modified. Section 3: Other health effects information was modified. Section 3: Immediate eye hazard(s) was added. Section 2: Ingredient table was added. Section 15