04240 DURAMix 4040 Plastic Repair, Semi-Rigid (Part A)

SECTION 2: Hazards identification

29 CFR 1910.1200) 3.1 EMERGENCY OVERVIEW Specific Physical Form: Viscous Odor, Color, Grade: Low or no detectable odor, weakly aromatic, black. General Physical Form: Liquid Immediate health, physical, and environmental hazards: May cause severe eye irritation. May cause severe skin irritation. May cause allergic skin reaction. May cause allergic respiratory reaction. May cause target organ effects. Contains a chemical or chemicals which can cause cancer.

Potential health effects

Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Skin Contact: Severe Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Inhalation: May be harmful or fatal if inhaled. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Allergic Respiratory Reaction: Signs/symptoms may include difficulty breathing, wheezing, cough, and tightness of chest. Prolonged or repeated exposure may cause: Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate, bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Target Organ Effects: Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient C.A.S. No. Class Description Regulation CARBON BLACK 1333-86-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature Not Applicable Flash Point >=290 ºF [Test Method: Tagliabue Closed Cup] Flammable Limits - LEL Not Applicable Flammable Limits - UEL Not Applicable 5.2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Water may be used to blanket the fire. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards Not applicable. Non-flammable ordinary combustible material Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Dispose of collected material as soon as possible. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Avoid eye contact with vapors, mists, or spray. Avoid breathing of dust created by cutting, sanding, grinding or machining. Do not breathe vapors.

Storage

Store away from acids. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use with appropriate local exhaust ventilation. Provide appropriate local exhaust for cutting, grinding, sanding or machining. Do not use in a confined area or areas with little or no air movement. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Indirect Vented Goggles. 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Butyl Rubber, Nitrile Rubber. 8.2.3 Respiratory Protection Avoid breathing of dust created by cutting, sanding, grinding or machining. Do not breathe vapors. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with

Additional information

CARBON BLACK ACGIH TWA 3.5 mg/m3 CARBON BLACK CMRG TWA 0.5 mg/m3 CARBON BLACK

TOXICOLOGICAL INFORMATION

Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Dispose of completely cured (or polymerized) wastes in a sanitary landfill. As a disposal alternative, incinerate uncured product in an industrial or commercial incinerator in the presence of a combustible material. EPA Hazardous Waste Number (RCRA): Not regulated Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION LB-K100-0780-9, LB-K100-0104-8 Not regulated per U.S. DOT, IATA or IMO. These transportation classifications are provided as a customer service. As the shipper YOU remain responsible for complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M’s transportation classifications are based on product formulation, packaging, 3M policies and 3M’s understanding of applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information applies only to transportation classification and not the packaging, labeling, or marking requirements. The original 3M package is certified for U.S. ground shipment only. If you are shipping by air or ocean, the package may not meet applicable regulatory requirements. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes STATE REGULATIONS Contact 3M for more information.

2.1 Classification of the substance or mixture

CARBON BLACK 1333-86-4 **Carcinogen ** WARNING: contains a chemical which can cause cancer. CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. The components of this product are listed on the Canadian Domestic Substances List. Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information. This MSDS has been prepared to meet the U.S.

HMIS® ratings

Health 2 Flammability 1 Reactivity 1 Protection X - See PPE section Hazardous Material Identification System (HMIS(r)) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS(r) ratings are to be used with a fully implemented HMIS(r) program. HMIS(r) is a registered mark of the National Paint and Coatings Association (NPCA). Revision Changes: Section 1: Product name was modified. Copyright was modified. Section 14: Transportation legal text was modified. Page Heading: Product name was modified. Section 8: Exposure guidelines ingredient information was modified. Section 3: Carcinogenicity table was modified. Section 14: ID Number(s) Template 1 was added. Section 10.1 Conditions to avoid was added. Section 10.2 Materials to avoid was added. Section 6: Release measures information was added. Section 10: Materials to avoid physical property was added. Section 10: Conditions to avoid physical property was added. Section 6: Release measures information was deleted. Section 10: Materials and conditions to avoid physical property was deleted. Section 15