Figure 4 Rigid 140C Black - Part A

3D Systems, Inc

Revision date : 2022-02-23

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GHS05 GHS07 GHS08
Health risk rating 4
Safety risk rating 1
Environmental risk rating 3

Note: Ingredients listed on restricted chemical lists

EC/CAS

418-140-1/5117-12-4

Name of the chemical

4-(1-oxo-2-propenyl)-morpholine

Concentration

418-140- 20-30 20-30

Listed in

EC/CAS

423-340-5/162881-26-7

Name of the chemical

Phenyl bis(2,4,6-trimethylbenzoyl)-phosphine oxide

Concentration

1-10

Listed in

EC/CAS

227-561-6/5888-33-5

Name of the chemical

Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate

Concentration

<5

Listed in

General Information

Revision date

2022-02-23

Product name

Figure 4 Rigid 140C Black - Part A

1.2.1 Relevant identified uses

For 3D printing use in Figure 4® systems

Emergency telephone

U.S.A

Icons in SDS

GHS05 GHS07 GHS08

Company Information

company name

3D Systems, Inc

e-mail address of the competent person responsible for the Safety Data Sheet

moreinfo@3dsystems.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H302, H315, H317, H318, H373, H412

Hazard statements

Code

Statements

H302

Harmful if swallowed

Section 2

2.1 Classification of the substance or mixture

GHS : Regulation (EC) No. 1272/2008, 29 CFR 1910:

Physical hazards

None

Health hazards

Acute Toxicity (oral) Category 4 H302 Skin Corrosion/Irritation Category 2 H315 Skin Sensitization Category 1 H317 Serious Eye Damage/Eye Irritation Category 1 H318 STOT repeated Exposure Category 2 H373

Environmental hazards

Aquatic environment – Chronic Category 3 H412

2.2 Label elements

Regulation (EC) No, 1272/2008: Hazard pictograms and signal word: GHS07 GHS05 GHS08

Signal word

Danger

Hazardous Ingredients

2-Propen-1-one, 1-(4-morpholinyl); Epoxy Resin; Oxirane, 2,2',2''- [ethylidynetris(4,1- phenyleneoxymethylene)]tris; Phenyl bis(2,4,6-trimethylbenzoyl)-phosphine oxide; Isobornylacrylate

Hazard statements

H302: Harmful if swallowed H315: Causes skin irritation H317: May cause an allergic skin reaction H318: Causes serious eye damage H373: May cause damage to organs through prolonged or repeated exposure H412: Toxic to aquatic life with long-lasting effect SDS • 420123-S12-03-A • Figure 4 Rigid 140C Black – Part A • US-English • GHS 1

Prevention

P260: Do not breathe dust/fume/gas/mist/vapours/spray. P264: Wash contaminated skin thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P272: Contaminated work clothing should not be allowed out of the workplace. P273: Avoid release to the environment. P280: Wear protective gloves/protective clothing/eye protection/face protection.

Response

P301 + P317 IF SWALLOWED Get medical help P302 + P352 IF ON SKIN Wash with plenty of water P305 + P354 + P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P319: Get medical help if you feel unwell. P321: Specific treatment (Wash contaminated skin with soap and water. Wash eyes with clean water for about 15 minutes). P330: Rinse mouth P332 + P317 If skin irritation occurs Get medical help P333 + P317 If skin irritation or rash occurs Get medical help P362+P364: Take off contaminated clothing and wash before reuse.

Storage

None Protect from sunlight. Store in a well-ventilated place

Disposal

P501: Dispose of contents/container in accordance with local/state/regional regulations.

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