Note: Ingredients listed on restricted chemical lists
EC/CAS
418-140-1/5117-12-4
Name of the chemical
4-(1-oxo-2-propenyl)-morpholine
Concentration
418-140- 30-50
EC/CAS
423-340-5/162881-26-7
Name of the chemical
Phenyl bis(2,4,6-trimethylbenzoyl)-phosphine oxide
Concentration
1-10
General Information
Revision date
2021-03-01
Product name
Figure 4 PRO-BLK 10
1.2.1 Relevant identified uses
For 3D printing use in Figure 4 systems
Emergency telephone
U.S.A
Icons in SDS
Company Information
company name
3D Systems, Inc
e-mail address of the competent person responsible for the Safety Data Sheet
moreinfo@3dsystems.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H302, H317, H318, H373, H412
Hazard statements
Code
Statements
H302
Harmful if swallowed
Section 2
2.1 Classification of the substance or mixture
GHS : Regulation (EC) No. 1272/2008, 29 CFR 1910
Physical hazards
None
Health hazards
Acute Toxicity (oral) Category 4 H302 Serious Eye Damage/Eye Irritation Category 1 H318 STOT RE 2 (Oral) Category 2 H373 Skin Sensitization Category 1 H317
Environmental hazards
Chronic aquatic toxicity Category 3 H412
2.2 Label elements
Regulation (EC) No, 1272/2008: Hazard pictograms and signal word: GHS07 GHS05 GHS08
Signal word
Danger
Hazardous Ingredients
2-Propen-1-one, 1-(4-morpholinyl); 3,3,5-Trimethylcyclohexyl acrylate; 2-Propenoic acid, 2-methyl-, (1R,2R,4R)-1,7,7trimethylbicyclo[2.2.1]hept-2-yl ester, rel-; Phosphine oxide, phenylbis(2,4,6-trimethylbenzoyl)
Hazard statements
H302: Harmful if swallowed H317: May cause an allergic skin reaction H318: Causes serious eye damage H373: May cause damage to organs through prolonged or repeated exposure H412: Harmful to aquatic life with long-lasting effect SDS • Figure 4 PRO-BLK 10 • 420126-S12-08-A • International-English • GHS 1
Prevention
P260: Do not breathe dust/fume/gas/mist/vapors/spray. P264: Wash contaminated skin thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P272: Contaminated work clothing should not be allowed out of the workplace. P273: Avoid release to the environment. P280: Wear protective gloves/protective clothing/eye protection/face protection. P285: In case of inadequate ventilation wear respiratory protection.
Response
P314: Get medical advice/attention if you feel unwell. P302 + P352 IF ON SKIN Wash with plenty of soap and water P333 + P313 If skin irritation or rash occurs Get medical advice/attention P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P410 + P403: Protect from sunlight. Store in a well-ventilated place. P307 + P311 IF exposed Call a POISON CENTER or doctor/physician
Storage
P410 + P403: Protect from sunlight. Store in a well-ventilated place.
Disposal
P501 -Dispose of contents/container in accordance with local/state/regional regulations
Potential health effects
Effects due to processing releases or residual monomer: Irritating to eyes, respiratory system and skin. Prolonged or repeated exposure may cause: headache, drowsiness, nausea, weakness, (severity of effects depends on extent of exposure)
