Vulcanizing Cement

Hazard statements (CLP)

H315, H317, H319, H336, H341, H344, H350

Code

Statements

H315

Causes skin irritation

2.2 Label elements

The product is classified and labeled according to the Globally Harmonized System (GHS).

Hazard pictograms

OS GHS07 GHS08

Signal word

Danger

Hazard statements

H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H341 Suspected of causing genetic defects. H350 May cause cancer. H336 May cause drowsiness or dizziness.

Precautionary statements

P2614 Avoid breathing mist, vapors, or spray. (Cont'd. on page 2} Trade name: Vulcanizing Cement {Cont'd. of page 1) P264 Wash thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing must not be allowed out of the workplace. P280 Wear protective gloves/protective clothing/eye protection/face protection. P302+P352 {F ON SKIN: Wash with plenty of water. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P 338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 + IF exposed or concerned: Get medical advice/attention. P312 ’ Calla POISON CENTER/doctor if you feel unwell. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P5014 Dispose of contents/container in accordance with locai/regional/national/international regulations. - Chemical chai racterization: Mixtures - Components: 79-01-6 [tric hloroethylene >70% ® Muta, 2, H344; Carc. 1B, H350 07 Skin Irrit, 2, H315; Eye Irrit. 2A, H319; Skin Sens. 1B, H317; STOT SE 3, H336 9006-04-6 | natural rubber latex 10-25%

Additional information

For the wording of the listed Hazard Statements refer to section 16 ‘Description of first aid measures ‘ General information: Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. After inhalation: Supply fresh air; consult doctor in case of complaints. Provide oxygen treatment if affected person has difficulty breathing. In case of irregular breathing or respiratory arrest provide artificial respiration. In case of unconsciousness place patient stably in side position for transportation. After skin contact: Take off contaminated clothing. Immediately wash with water and soap and rinse thoroughly. lf skin irritation or rash occurs: Get medical advice/attention. After eye contact: Remove conta ct lenses if worn. Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. (Cont'd. on page 3) Trade name: Vulcanizing Cement {Cont'd. of page 2) - After swallowing: Rinse out mouth and then drink plenty of water. Do not induce vomiting; immediately call for medical help. A person vorniting while lying on their back should be turned onto their side. ‘ Most important symptoms and effects, both acute and delayed: Headache Breathing difficulty Coughing, dizziness, if inhaled. Irritant to skin and mucous membranes. Allergic reactions Causes eye irritation. Gastric or intestinal disorders when ingested. Nausea in case of ingestion. Disorientation - Danger: Danger of disturbed cardiac rhythm. Danger of impaired breathing. Vapours may cause drowsiness and dizziness. May cause cancer. Suspected of causing genetic defects. ‘Indication of any immediate medical attention and special treatment needed: If necessary oxygen respiration treatment. Later observation for pneumonia and pulmonary edema. ‘ Extinguishing media ‘ Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water. - For safety reasons unsuitable extinguishing agents: Water - Special hazards arising from the substance or mixture During heating or in case of fire poisonous gases are produced. ‘ Advice for firefighters - Protective equipment: Wear self-contained respiratory protective device. Wear fully protective suit. Evacuate area and fight fire from from the upwind side - Personal precautions, protective equipment and emergency procedures Use respiratory protective device against the effects of fumes/dust/aerosol. Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation. Keep people at a distance and stay upwind. ‘ Environmental precautions Do not allow to enter sewers/ surface or ground water. Inform respective authorities in case of seepage into water course or sewage system. (Cont'd. on page 4) Trade name: Vulcanizing Cement (Cont'd. of page 3) ‘Methods and material for containment and cleaning up Allow to solidify. Pick up mechanically. Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Send for recovery or disposal in suitable receptacles. ‘Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. ‘Handling - Precautions for safe handling: Prevent formation of aerosols. Avoid splashes or spray in enclosed areas. Use only outdoors or in a well-ventilated area. - Information about protection against explosions and fires: Keep respiratory protective device available. ’ Conditions for safe storage, including any incompatibilities

Storage

Requirements to be met by storerooms and receptacles: Store in cool, dry conditions in well sealed receptacles. Store only in the original receptacle. ‘ Information about storage in one common storage facility: Store away from foodstuffs. Do not store together with oxidizing and acidic materials. ‘ Specific end use(s) No relevant information available. ‘ Control parameters * Components with limit values that require monitoring at the workplace: 79-01-6 trichloroethylene PEL (USA) Long-term value: 100 ppm Ceiling limit value: 200; 300* ppm *6-min peak in any 2 hrs REL (USA) See Pocket Guide Apps. A and C TLV (USA) Short-term value: 135 mg/m?, 25 ppm Long-term value: 54 mg/m?, 10 ppm BEI EL (Canada) | Short-term value: 25 ppm Long-term value: 10 ppm ACGIH A2, IARC 1 (Cont'd. en page 5) Trade name: Vulcanizing Cement (Cont'd. of page 4) EV (Canada) | Short-term value: 25 ppm Long-term value: 10 ppm LMPE (Mexico) | Short-term value: 25 ppm Long-term value: 10 ppm A2, IBE 9006-04-6 natural rubber latex TLV (USA) Long-term value: 0.0001* mg/m* Skin; DSEN, RSEN;* inh. fraction EL (Canada) / Long-term value: 0.001 mg/m? inhalable, Skin; S EV (Canada) {Long-term value: 0.001 mg/m? as total proteins, inhalable, Skin LMPE (Mexico) Long-term value: 0.0001* mg/m?* SEN, PIEL, *fraccién inhalable - Ingredients with biological limit values: 79-01-6 trichloroethylene BET (USA) 15 mg/L Medium: urine Time: end of shift at end of workweek Parameter: Trichloroacetic acid (nonspecific) 0.5 mg/L Medium: blood Time: end of shift at end of workweek Parameter: Trichloroethanol without hydrolysis (nonspecific) Medium: blood Time: end of shift at end of workweek Parameter: Trichloroethylene (semi-quantitative) Medium: end-exhaled air Time: end of shift at end of workweek Parameter: Trichioroethylene (semi-quantitative) ‘Exposure controls - Personal protective equipment: ‘ General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed. Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Do not inhale gases / fumes / aerosols. Avoid contact with the eyes and skin. - Engineering controls: Use only outdoors or in a well-ventilated area. (Cont'd. on page 6) Trade name: Vulcanizing Cement (Cont'd. of page 5) ‘ Breathing equipment: Wear appropriate NIOSH respirator when ventilation is inadequate and occupational exposure limits are exceeded. For large spills, respiratory protection may be advisable. ‘ Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. - Eye protection: Safety glasses Follow relevant national guidelines concerning the use of protective eyewear. ’ Body protection: Solvent resistant protective clothing ‘Limitation and supervision of exposure into the environment No relevant information available. ‘Risk management measures No relevant information available. ‘Information on basic physical and chemical properties - Appearance: Form: Liquid Color: Cloudy * Odor: Sweet ‘ Odor threshold: Not determined. - pH-value: Not determined. ‘ Meiting point/Melting range: Not determined. ‘ Boiling point/Boiling range: 87 °C (189 °F) * Flash point: Not applicable. * Flammability (solid, gaseous): Not applicable. Auto-ignition temperature: 410 °C (770 °F) ‘ Decomposition temperature: Not determined. - Danger of explosion: Product does not present an explosion hazard. - Explosion limits Lower: 8.0 Vol % Upper: 10.5 Vol % ‘ Vapor pressure at 20 °C (68 °F): 77 hPa (58 mm Hg) ‘ Density at 20 °C (68 °F): 1.45 glom? (12.1 Ibs/gal) {Cont'd. on page 7) Trade name: Vuleanizing Cement (Cont'd. of page 6} - Relative density: Not determined. ‘Vapor density at 20 °C (68 °F): 4.54 g/cm® (37.886 Ibs/gal) (air = 1) - Evaporation rate: Not determined. Solubility in / Miscibility with Water: Not miscible or difficult to mix. ' Partition coefficient (n-octanol/water): Not determined. Viscosity Dynamic: Not determined. Kinematic: Not determined.

Further information

No relevant information available. ‘Reactivity: No relevant information available. * Chemical stability: ‘ Thermal decomposition / conditions to be avoided: No decomposition if used and stored according to specifications. ‘Possibility of hazardous reactions Reacts with strong acids and oxidizing agents. Toxic fumes may be released if heated above the decomposition point. ‘Conditions to avoid Keep away from heat and direct sunlight. ‘Incompatible materials Oxidizing agents Strong acids ‘Hazardous decomposition products Carbon monoxide and carbon dioxide Chlorine compounds ‘Information on toxicological effects Acute toxicity: - LD/LC50 values that are relevant for classification: 79-01-6 trichloroethylene Oral LD50 | 2402 mg/kg (mouse) Dermal} LD50 | 8450 mg/kg (mouse) - Primary irritant effect: - On the skin: Irritant to skin and mucous membranes. * On the eye: Irritating effect. + Sensitization: Contains natural rubber latex. May produce an allergic reaction. Sensitization possible through skin contact. (Cont'd. on page 8) Trade name: Vulcanizing Cement (Cont'd. of page 7) IARC (International Agency for Research on Cancer): 79-01-6 | trichloroethylene 2A ‘NTP (National Toxicology Program): 79-01-6 |trichloroethylene | R * OSHA-Ca (Occupational Safety & Health Administration): None of the ingredients are listed. Probable route(s) of exposure: Ingestion. Inhalation. Eye contact. Skin contact. ‘Acute effects (acute toxicity, irritation and corrosivity): Causes skin and eye Irritation. Vapors have narcotic effect. May cause drowsiness or dizziness. Irritating to eyes and skin. ‘Repeated dose toxicity: Danger of very serious irreversible effects. * Germ cell mutagenicity: Suspected of causing genetic defects. - Carcinogenicity: May cause cancer. - Reproductive toxicity: Based on available data, the classification criteria are not met. ‘ STOT-single exposure: May cause drowsiness or dizziness. ‘ STOT-repeated exposure: Based on available data, the classification criteria are not met. ‘ Aspiration hazard: Based on available data, the classification criteria are not met. ‘Toxicity ‘ Aquatic toxicity The product contains materials that are harmful to the environment. ‘Persistence and degradability No relevant information available. - Bioaccumulative potential: No relevant information available. - Mobility in soil: No relevant information available. ‘ Additional ecological information - General notes: Due to available data on eliminability/decomposition and bioaccumulation potential prolonged term damage of the environment can not be excluded. Do not allow product to reach ground water, water course or sewage system, even in small quantities. ‘Results of PBT and vPvB assessment - PBT: Not applicable. + vPvB: Not applicable. ‘ Other adverse effects No relevant information available. (Cont'd. on page 9) Trade name: Vulcanizing Cement (Cont'd. of page 8) ‘Waste treatment methods - Recommendation: The user of this material has the responsibility to dispose of unused material, residues and containers in compliance with all relevant iocal, state and federal laws and regulations regarding treatment, storage and disposal for hazardous and nonhazardous wastes. ‘Uncleaned packagings * Recommendation: Disposal must be made according to official regulations. ‘ UN-Number - DOT, ADR, IMDG, IATA UN1710 ‘UN proper shipping name ‘ DOT, ADR, IMDG, IATA TRICHLOROETHYLENE Transport hazard class(es) DOT ‘Class 6.1 (T1) Toxic substances > Class 6.1 Toxic substances - Label 6.1 ‘Packing group - DOT, ADR, IMDG, IATA lil ‘ Environmental hazards - Marine pollutant: No ‘Special precautions for user Warning: Toxic substances (Cont'd. on page 10) Trade name: Vulcanizing Cement (Cont'd. of page 9} ‘ Danger code (Kemler): 60 - EMS Number: F-A,S-A * Segregation groups Liquid halogenated hydrocarbons ‘Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. ‘ Transport/Additional information: *DOT < » Limited Quantity for packages less than 30 kg gross and inner packagings less than 5 L each. .. Limited Quantity for packages less than 30 kg gross and inner packagings less than 0.5 L each Ye 2 L net. ‘Safety, health and environmental regulations/legislation specific for the substance or